Thermochemical studies on complex of [Sm(o-NBA)_3phen]_2
A ternary complex [Sm(o-NBA)3phen]2 (o-NBA: o-Nitrobenzoate; phen: 1,10-phenanthroline) was synthesized and characterized by elemental analysis, IR, molar conductance, and thermogravimetric analysis. The dissolution enthalpies of SmCl3·6H2O(s), o-HNBA(s) and phen·H2O(s) in mixed solvent (VHCl :VDMF...
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| Veröffentlicht in: | Journal of rare earths 2010, Vol.28 (1), p.12-15 |
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| creator | 肖圣雄 张建军 李旭 李强国 任宁 李环 |
| description | A ternary complex [Sm(o-NBA)3phen]2 (o-NBA: o-Nitrobenzoate; phen: 1,10-phenanthroline) was synthesized and characterized by elemental analysis, IR, molar conductance, and thermogravimetric analysis. The dissolution enthalpies of SmCl3·6H2O(s), o-HNBA(s) and phen·H2O(s) in mixed solvent (VHCl :VDMF :VDMSO=2:2:1) were determined by calorimetry at 298.15 K. The enthalpy change of the reaction was determined to be rHmΔθ=252.49±1.60 kJ/mol. Using the relevant data in the literature and a thermochemical recycle ... |
| doi_str_mv | 10.1016/S1002-0721(09)60040-5 |
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The dissolution enthalpies of SmCl3·6H2O(s), o-HNBA(s) and phen·H2O(s) in mixed solvent (VHCl :VDMF :VDMSO=2:2:1) were determined by calorimetry at 298.15 K. The enthalpy change of the reaction was determined to be rHmΔθ=252.49±1.60 kJ/mol. Using the relevant data in the literature and a thermochemical recycle ...</description><identifier>ISSN: 1002-0721</identifier><identifier>EISSN: 2509-4963</identifier><identifier>DOI: 10.1016/S1002-0721(09)60040-5</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>1,10-phenanthroline ; o-nitrobenzoic acid ; rare earth complex ; samarium chloride hexahydrate ; thermochemical</subject><ispartof>Journal of rare earths, 2010, Vol.28 (1), p.12-15</ispartof><rights>2010 The Chinese Society of Rare Earths</rights><rights>Copyright © Wanfang Data Co. Ltd. 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The dissolution enthalpies of SmCl3·6H2O(s), o-HNBA(s) and phen·H2O(s) in mixed solvent (VHCl :VDMF :VDMSO=2:2:1) were determined by calorimetry at 298.15 K. The enthalpy change of the reaction was determined to be rHmΔθ=252.49±1.60 kJ/mol. Using the relevant data in the literature and a thermochemical recycle ...</description><subject>1,10-phenanthroline</subject><subject>o-nitrobenzoic acid</subject><subject>rare earth complex</subject><subject>samarium chloride hexahydrate</subject><subject>thermochemical</subject><issn>1002-0721</issn><issn>2509-4963</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFUM1LwzAUD6LgnP4JQg8etkP1NWnS9iRz-AVDD5snkZCmL2vm2sx00-lfb_eBV-HBu_y-CTmP4DKCSFyNIwAaQkKjHmR9ARBDyA9Ih3LIwjgT7JB0_iDH5KRpZgAs4Rl0SDop0VdOl1hZreZBs1wVFpvA1YF21WKO68CZ4HVc9Vz4dDPoS7YosX6T9JQcGTVv8Gz_u-Tl7nYyfAhHz_ePw8Eo1DRNWJiowjDgLI5jwyOtY0gpKFBCFTqjWZpyTBk3JmXCFFhgAkZQ4IblCc1RIeuS_k73S9VG1VM5cytft47yZ7pernOJFNpy7bEWy3dY7V3TeDRy4W2l_LeMQG6mktup5GYHCZncTiV5y7ve8bAt8mnRy0ZbrDUW1qNeysLZfxUu9s6lq6cfts2ZK_1u7BzlJh0FJkTEfgEf93oT</recordid><startdate>2010</startdate><enddate>2010</enddate><creator>肖圣雄 张建军 李旭 李强国 任宁 李环</creator><general>Elsevier B.V</general><general>Department of Chemistry and Life Science,Xiangnan University,Chenzhou 423000,China%Experimental Center,Hebei Normal University,Shijiazhuang 050016,China%Department of Chemistry,Handan College,Handan 056005,China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W94</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>2010</creationdate><title>Thermochemical studies on complex of [Sm(o-NBA)_3phen]_2</title><author>肖圣雄 张建军 李旭 李强国 任宁 李环</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2873-7adf3053444f51cc40820a0a6adc929885e835ff836fdede70f6205f3b72beae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>1,10-phenanthroline</topic><topic>o-nitrobenzoic acid</topic><topic>rare earth complex</topic><topic>samarium chloride hexahydrate</topic><topic>thermochemical</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>肖圣雄 张建军 李旭 李强国 任宁 李环</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-自然科学</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Journal of rare earths</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>肖圣雄 张建军 李旭 李强国 任宁 李环</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Thermochemical studies on complex of [Sm(o-NBA)_3phen]_2</atitle><jtitle>Journal of rare earths</jtitle><addtitle>Journal of Rare Earths</addtitle><date>2010</date><risdate>2010</risdate><volume>28</volume><issue>1</issue><spage>12</spage><epage>15</epage><pages>12-15</pages><issn>1002-0721</issn><eissn>2509-4963</eissn><abstract>A ternary complex [Sm(o-NBA)3phen]2 (o-NBA: o-Nitrobenzoate; phen: 1,10-phenanthroline) was synthesized and characterized by elemental analysis, IR, molar conductance, and thermogravimetric analysis. The dissolution enthalpies of SmCl3·6H2O(s), o-HNBA(s) and phen·H2O(s) in mixed solvent (VHCl :VDMF :VDMSO=2:2:1) were determined by calorimetry at 298.15 K. The enthalpy change of the reaction was determined to be rHmΔθ=252.49±1.60 kJ/mol. Using the relevant data in the literature and a thermochemical recycle ...</abstract><pub>Elsevier B.V</pub><doi>10.1016/S1002-0721(09)60040-5</doi><tpages>4</tpages></addata></record> |
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| ispartof | Journal of rare earths, 2010, Vol.28 (1), p.12-15 |
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| language | eng |
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| source | Elsevier ScienceDirect Journals Complete; Alma/SFX Local Collection |
| subjects | 1,10-phenanthroline o-nitrobenzoic acid rare earth complex samarium chloride hexahydrate thermochemical |
| title | Thermochemical studies on complex of [Sm(o-NBA)_3phen]_2 |
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