Synthesis and Photoluminescence Properties of Rare Earth Complexes with 3-Allyl-2, 4-Pentanedione
In order to combine the merits of rare earth organic complexes with excellent material performances of polymers,a polymerizable chelating agent, 3-allyl-2, 4-pentane dione (APD), was synthesized by phase transfer catalysis and its rare earth complexes were prepared. The compounds were characterized...
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| Veröffentlicht in: | Journal of rare earths 2004-04, Vol.22 (2), p.201-205 |
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| container_title | Journal of rare earths |
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| creator | 邹应萍 谭松庭 肖尊宏 王霞瑜 |
| description | In order to combine the merits of rare earth organic complexes with excellent material performances of polymers,a polymerizable chelating agent, 3-allyl-2, 4-pentane dione (APD), was synthesized by phase transfer catalysis and its rare earth complexes were prepared. The compounds were characterized by EA, IR and ^1H NMR. Their UV spectra and fluorescence spectra were investigated. The effects of allyl on the luminescence properties of the complexes were studied.The results show that the sensitization of APD is changed by allyl in comparison with that of acetyl acetone (acac), and it becomes an ideal novel ligand of Eu. In addition, intramolecular energy transfer mechanism in the luminescence process in the complexes was also discussed in detail. |
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The compounds were characterized by EA, IR and ^1H NMR. Their UV spectra and fluorescence spectra were investigated. The effects of allyl on the luminescence properties of the complexes were studied.The results show that the sensitization of APD is changed by allyl in comparison with that of acetyl acetone (acac), and it becomes an ideal novel ligand of Eu. In addition, intramolecular energy transfer mechanism in the luminescence process in the complexes was also discussed in detail.</description><identifier>ISSN: 1002-0721</identifier><identifier>EISSN: 2509-4963</identifier><language>eng</language><publisher>Institute of Polymer Material Science,Xiangtan University,Xiangtan 411105,China</publisher><subject>APD ; NMR ; 发光性能 ; 发光材料 ; 烯丙基戊二酮</subject><ispartof>Journal of rare earths, 2004-04, Vol.22 (2), p.201-205</ispartof><rights>Copyright © Wanfang Data Co. Ltd. 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Their UV spectra and fluorescence spectra were investigated. The effects of allyl on the luminescence properties of the complexes were studied.The results show that the sensitization of APD is changed by allyl in comparison with that of acetyl acetone (acac), and it becomes an ideal novel ligand of Eu. In addition, intramolecular energy transfer mechanism in the luminescence process in the complexes was also discussed in detail.</description><subject>APD</subject><subject>NMR</subject><subject>发光性能</subject><subject>发光材料</subject><subject>烯丙基戊二酮</subject><issn>1002-0721</issn><issn>2509-4963</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2004</creationdate><recordtype>article</recordtype><recordid>eNotj91LwzAUxYsoOKf_Q30RBAP5aps-jjE_YODw47mk6c2amSVbk-LmX29kvpzLPfw4956zbEILXCNel-w8mxCMKcIVJZfZVQgbjFlV1HiSyfejiz0EE3LpunzV--jtuDUOggKnIF8NfgdDNBByr_M3OUC-kEPs87nf7iwckv9t0srQzNqjRfQh52gFLkoHnfEOrrMLLW2Am_85zT4fFx_zZ7R8fXqZz5ZIUc4jIhK0pKqkAljLucJcYMo70ioBpC47gnWnKlpUkouCMNySrtWS11jWZcm1ZtPs_pT7LZ2Wbt1s_Di4dLH5WR_ioW2AYszxnyT27sTuBr8fIcRma1Jfa9PTfgwNFZyRqhIJvD2BqvduvTcptpXqSxsLTS0oFQyzXyMQbJQ</recordid><startdate>20040401</startdate><enddate>20040401</enddate><creator>邹应萍 谭松庭 肖尊宏 王霞瑜</creator><general>Institute of Polymer Material Science,Xiangtan University,Xiangtan 411105,China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W92</scope><scope>~WA</scope><scope>7SR</scope><scope>7U5</scope><scope>8FD</scope><scope>H8D</scope><scope>JG9</scope><scope>L7M</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20040401</creationdate><title>Synthesis and Photoluminescence Properties of Rare Earth Complexes with 3-Allyl-2, 4-Pentanedione</title><author>邹应萍 谭松庭 肖尊宏 王霞瑜</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c244t-1aefa2c628e3b44c048024d1bc8e196d10fdc7257a485130b1dbfa490a9664ff3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2004</creationdate><topic>APD</topic><topic>NMR</topic><topic>发光性能</topic><topic>发光材料</topic><topic>烯丙基戊二酮</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>邹应萍 谭松庭 肖尊宏 王霞瑜</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-工程技术</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>Engineered Materials Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Aerospace Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Journal of rare earths</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>邹应萍 谭松庭 肖尊宏 王霞瑜</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and Photoluminescence Properties of Rare Earth Complexes with 3-Allyl-2, 4-Pentanedione</atitle><jtitle>Journal of rare earths</jtitle><addtitle>Journal of Rare Earths</addtitle><date>2004-04-01</date><risdate>2004</risdate><volume>22</volume><issue>2</issue><spage>201</spage><epage>205</epage><pages>201-205</pages><issn>1002-0721</issn><eissn>2509-4963</eissn><abstract>In order to combine the merits of rare earth organic complexes with excellent material performances of polymers,a polymerizable chelating agent, 3-allyl-2, 4-pentane dione (APD), was synthesized by phase transfer catalysis and its rare earth complexes were prepared. The compounds were characterized by EA, IR and ^1H NMR. Their UV spectra and fluorescence spectra were investigated. The effects of allyl on the luminescence properties of the complexes were studied.The results show that the sensitization of APD is changed by allyl in comparison with that of acetyl acetone (acac), and it becomes an ideal novel ligand of Eu. In addition, intramolecular energy transfer mechanism in the luminescence process in the complexes was also discussed in detail.</abstract><pub>Institute of Polymer Material Science,Xiangtan University,Xiangtan 411105,China</pub><tpages>5</tpages></addata></record> |
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| identifier | ISSN: 1002-0721 |
| ispartof | Journal of rare earths, 2004-04, Vol.22 (2), p.201-205 |
| issn | 1002-0721 2509-4963 |
| language | eng |
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| source | Alma/SFX Local Collection |
| subjects | APD NMR 发光性能 发光材料 烯丙基戊二酮 |
| title | Synthesis and Photoluminescence Properties of Rare Earth Complexes with 3-Allyl-2, 4-Pentanedione |
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