Study on Preparation and Application of Ti/Si Complex Zeolite
A Ti/Si complex zeolite has been prepared. X-ray diffraction and infrared spectrometry study has shown that two structures, namely the ZSM-5 and MCM-41, exist in the sample. BET tests have revealed that the complex zeolite contains regular mesopores of 2.6 nm. Ultraviolet spectrometry analysis has s...
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Veröffentlicht in: | 中国石油加工与石油化工技术(英文版) 2003-09 (3), p.49-52 |
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description | A Ti/Si complex zeolite has been prepared. X-ray diffraction and infrared spectrometry study has shown that two structures, namely the ZSM-5 and MCM-41, exist in the sample. BET tests have revealed that the complex zeolite contains regular mesopores of 2.6 nm. Ultraviolet spectrometry analysis has shown that the Ti species exist in the zeolite skeleton in the form of tetra-coordinate valence. The Ti/Si complex zeolite (TS-1/Ti-MCM-41) has apparently improved catalytic activity with respect to the macromolecular organic compound oxidation as compared to individual components of either Ti or Si containing zeolites (TS- 1 and Ti-MCM-41). |
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The Ti/Si complex zeolite (TS-1/Ti-MCM-41) has apparently improved catalytic activity with respect to the macromolecular organic compound oxidation as compared to individual components of either Ti or Si containing zeolites (TS- 1 and Ti-MCM-41).</description><issn>1008-6234</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><recordid>eNotjUtOwzAYhL0Aiar0Dr5AwI_YjhcsqoiXVAmklg2byrF_B0fBjuJUEE5PpHZmMd9sZq7QihJSFZLx8gZtcu7IIsmkouUKPeynk5txivh9hMGMZgoLm-jwdhj6YM89eXwI9_uA6_Q99PCLPyH1YYJbdO1Nn2FzyTX6eHo81C_F7u35td7uikyJqgrulLOCEtlwob1WRhuvdCmFaqhgwK0DoxtacS9d47wDDsxoK6wqJUgAvkZ3590fE72J7bFLpzEuj8e_Ns9dO-f5q-0yI4QvJhX_B538SNc</recordid><startdate>200309</startdate><enddate>200309</enddate><creator>Zhang Baoji</creator><creator>Wang Xieqing</creator><general>SINOPEC Research Institute of Petroleum Processing, Beijing 100083</general><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>200309</creationdate><title>Study on Preparation and Application of Ti/Si Complex Zeolite</title><author>Zhang Baoji ; Wang Xieqing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-s1078-3d7dc5106b359f97a9af794657b152e3cdea9b183f6dbdfde3e2a9c5c746e6ee3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Zhang Baoji</creatorcontrib><creatorcontrib>Wang Xieqing</creatorcontrib><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>中国石油加工与石油化工技术(英文版)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang Baoji</au><au>Wang Xieqing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Study on Preparation and Application of Ti/Si Complex Zeolite</atitle><jtitle>中国石油加工与石油化工技术(英文版)</jtitle><date>2003-09</date><risdate>2003</risdate><issue>3</issue><spage>49</spage><epage>52</epage><pages>49-52</pages><issn>1008-6234</issn><abstract>A Ti/Si complex zeolite has been prepared. X-ray diffraction and infrared spectrometry study has shown that two structures, namely the ZSM-5 and MCM-41, exist in the sample. BET tests have revealed that the complex zeolite contains regular mesopores of 2.6 nm. Ultraviolet spectrometry analysis has shown that the Ti species exist in the zeolite skeleton in the form of tetra-coordinate valence. The Ti/Si complex zeolite (TS-1/Ti-MCM-41) has apparently improved catalytic activity with respect to the macromolecular organic compound oxidation as compared to individual components of either Ti or Si containing zeolites (TS- 1 and Ti-MCM-41).</abstract><pub>SINOPEC Research Institute of Petroleum Processing, Beijing 100083</pub><tpages>4</tpages></addata></record> |
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title | Study on Preparation and Application of Ti/Si Complex Zeolite |
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