Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters

An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical condi...

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Veröffentlicht in:Chinese chemical letters 2022-03, Vol.33 (3), p.1555-1558
Hauptverfasser: Dai, Jian-Jun, Teng, Xin-Xin, Fang, Wen, Xu, Jun, Xu, Hua-Jian
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container_issue 3
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container_title Chinese chemical letters
container_volume 33
creator Dai, Jian-Jun
Teng, Xin-Xin
Fang, Wen
Xu, Jun
Xu, Hua-Jian
description An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical conditions. This reaction exhibits broad substrate scope, good functional group tolerability, and easy scalability. An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. [Display omitted]
doi_str_mv 10.1016/j.cclet.2021.09.011
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source Elsevier ScienceDirect Journals Complete; Alma/SFX Local Collection
subjects Alkyl boronic esters
Borylation
Decarboxylation
Electrochemical
Redox active esters
title Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters
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