Metal-free C(sp2)-H perfluoroalkylsulfonylation and configuration inversion: Stereoselective synthesis of α-perfluoroalkylsulfonyl E-enaminones

The perfluoroalkylsulfonylation (CF3SO2, C2F5SO2 and CHF2SO2) in the enaminone CH bonds has been developed simply via the promotion of molecular iodine by using stable and cheap sodium perfluoroalkyl sulfinates as coupling partners. The stereoselective synthesis of E-configurated α-perfluoroalkylsul...

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Veröffentlicht in:	Chinese chemical letters 2021-11, Vol.32 (11), p.3514-3517
Hauptverfasser:	Yu, Qing, Liu, Yunyun, Wan, Jie-Ping
Format:	Artikel
Sprache:	eng
Schlagworte:	Configuration inversion C–H Functionalization Enaminone Metal-free Perfluoroalkyl sulfonylation
Online-Zugang:	Volltext
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