A highly selective solid-contact electrode for Ag+ based on a monoazathiacrown ether ionophore

A new solid-contact Ag~+-selective electrode was prepared with 9,10,12,13,24,25-hexahydro-5H,15H,23H-dibenzo [b,q][1,7,10,13,19,4,16]-entathiadiazacyclodocosine-6,16(7H,17H)-dione as ionophore,and cc,a-dihexylsexithiophene(DH- 6T) ion-to-electron transducer.The sensor exhibited a working concentrati...

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Veröffentlicht in:Chinese chemical letters 2012-04, Vol.23 (4), p.488-491
Hauptverfasser: Yu, Shun Yang, Ju, Lan, Li, Fu Hai, Liu, Yong Ming, Fang, Jun Feng
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container_end_page 491
container_issue 4
container_start_page 488
container_title Chinese chemical letters
container_volume 23
creator Yu, Shun Yang
Ju, Lan
Li, Fu Hai
Liu, Yong Ming
Fang, Jun Feng
description A new solid-contact Ag~+-selective electrode was prepared with 9,10,12,13,24,25-hexahydro-5H,15H,23H-dibenzo [b,q][1,7,10,13,19,4,16]-entathiadiazacyclodocosine-6,16(7H,17H)-dione as ionophore,and cc,a-dihexylsexithiophene(DH- 6T) ion-to-electron transducer.The sensor exhibited a working concentration range of 10~8 to 10~(-3) mol/L,with a near-Nernstian slope of 55.1±0.2 mV/dec and detection limit of 1.7×10~(-9) mol/L.The fabricated electrodes demonstrated excellent selectivity over the most common monovalent and divalent cations.
doi_str_mv 10.1016/j.cclet.2011.12.016
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source ScienceDirect Journals (5 years ago - present); Alma/SFX Local Collection
subjects Ion-selective electrodes
Low detection limit
Silver
Solid contact
二价阳离子
固体接触
接触电极
浓度范围
电子传感器
载体
选择性电极

title A highly selective solid-contact electrode for Ag+ based on a monoazathiacrown ether ionophore
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