Synthesis and optical activity of isosorbide chiral derivative containing fluorocarbon group as chiral dopant in liquid crystal materials
Novel isosorbide derivative containing perfluorocarbon group,bi（perfluorooctanesulfonyl）isosorbide ester as chiral dopant in liquid crystal,was synthesized.Chemical structure was characterized by elemental analysis,FT-IR,~1H NMR and ~（19）F NMR.The optical texture of the mixture was observed by polar...
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| Veröffentlicht in: | Chinese chemical letters 2011-12, Vol.22 (12), p.1447-1450 |
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| creator | Xie, Kong Liang Su, Yin He Zhang, Chun Xiang |
| description | Novel isosorbide derivative containing perfluorocarbon group,bi（perfluorooctanesulfonyl）isosorbide ester as chiral dopant in liquid crystal,was synthesized.Chemical structure was characterized by elemental analysis,FT-IR,~1H NMR and ~（19）F NMR.The optical texture of the mixture was observed by polarized optical microscopy（POM）.Novel chiral dopant containing perfluorocarbon group had excellent optical activity.Its specific rotation and molar rotation were noticeable higher than those of bi（4-chloromethylbenzenecarbonic）isosorbide ester.The fluorocarbon group improved the molar rotation of chiral compound and did not affect optical rotation direction.The texture of the mixture added isosorbide derivative with fluorocarbon group showed the oily streak texture. |
| doi_str_mv | 10.1016/j.cclet.2011.07.021 |
| format | Article |
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All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c361t-5a5401ac1b5dbe198873fa477eab69371f1de405e65a5ca032c09939aaa3f3da3</citedby><cites>FETCH-LOGICAL-c361t-5a5401ac1b5dbe198873fa477eab69371f1de405e65a5ca032c09939aaa3f3da3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/84039X/84039X.jpg</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.cclet.2011.07.021$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Xie, Kong Liang</creatorcontrib><creatorcontrib>Su, Yin He</creatorcontrib><creatorcontrib>Zhang, Chun Xiang</creatorcontrib><title>Synthesis and optical activity of isosorbide chiral derivative containing fluorocarbon group as chiral dopant in liquid crystal materials</title><title>Chinese chemical letters</title><addtitle>Chinese Chemical Letters</addtitle><description>Novel isosorbide derivative containing perfluorocarbon group,bi（perfluorooctanesulfonyl）isosorbide ester as chiral dopant in liquid crystal,was synthesized.Chemical structure was characterized by elemental analysis,FT-IR,~1H NMR and ~（19）F NMR.The optical texture of the mixture was observed by polarized optical microscopy（POM）.Novel chiral dopant containing perfluorocarbon group had excellent optical activity.Its specific rotation and molar rotation were noticeable higher than those of bi（4-chloromethylbenzenecarbonic）isosorbide ester.The fluorocarbon group improved the molar rotation of chiral compound and did not affect optical rotation direction.The texture of the mixture added isosorbide derivative with fluorocarbon group showed the oily streak texture.</description><subject>Fluorocarbon</subject><subject>Liquid crystal</subject><subject>Optical properties</subject><subject>Surfaces</subject><subject>Texture</subject><subject>光学活性</subject><subject>单硝酸异山梨酯</subject><subject>异山梨醇</subject><subject>手性化合物</subject><subject>掺杂</subject><subject>氟碳</subject><subject>液晶材料</subject><subject>衍生物</subject><issn>1001-8417</issn><issn>1878-5964</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqFkM9OGzEQxldVkZoCT9CLOfW0i2e9fw8cKlTaSpF6AM7WrO3dTLrYwXYC6Rvw1jgN4trLzMjz_eaTvyz7ArwADs3lulBqNrEoOUDB24KX8CFbQNd2ed031cc0cw55V0H7KfscwprzsutEs8hebvc2rkygwNBq5jaRFM4MVaQdxT1zI6PggvMDacPUinzaauNph0mRXpyNSJbsxMZ567xT6Adn2eTddsMwvCNugzYysmymxy1ppvw-xLR4wJiu4RzOspMxNXP-1k-z-5vvd9c_8-XvH7-uvy1zJRqIeY11xQEVDLUeDPRd14oRq7Y1ODS9aGEEbSpemyYpFXJRKt73okdEMQqN4jT7erz7hHZEO8m123qbHOXfafX8ZzhkCKk0SSmOSuVdCN6McuPpAf1eApeH3OVa_stdHhjJW5lyT9TVkTLpEzsyXgZFxiqjyRsVpXb0H_7izXXl7PSYkn23rXhTQVlX4hXNHpv5</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Xie, Kong Liang</creator><creator>Su, Yin He</creator><creator>Zhang, Chun Xiang</creator><general>Elsevier B.V</general><general>College of Chemistry, Chemical Engineering and Biotechnology, Donghua University, Shanghai 201620, China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20111201</creationdate><title>Synthesis and optical activity of isosorbide chiral derivative containing fluorocarbon group as chiral dopant in liquid crystal materials</title><author>Xie, Kong Liang ; Su, Yin He ; Zhang, Chun Xiang</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c361t-5a5401ac1b5dbe198873fa477eab69371f1de405e65a5ca032c09939aaa3f3da3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Fluorocarbon</topic><topic>Liquid crystal</topic><topic>Optical properties</topic><topic>Surfaces</topic><topic>Texture</topic><topic>光学活性</topic><topic>单硝酸异山梨酯</topic><topic>异山梨醇</topic><topic>手性化合物</topic><topic>掺杂</topic><topic>氟碳</topic><topic>液晶材料</topic><topic>衍生物</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Xie, Kong Liang</creatorcontrib><creatorcontrib>Su, Yin He</creatorcontrib><creatorcontrib>Zhang, Chun Xiang</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Chinese chemical letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Xie, Kong Liang</au><au>Su, Yin He</au><au>Zhang, Chun Xiang</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis and optical activity of isosorbide chiral derivative containing fluorocarbon group as chiral dopant in liquid crystal materials</atitle><jtitle>Chinese chemical letters</jtitle><addtitle>Chinese Chemical Letters</addtitle><date>2011-12-01</date><risdate>2011</risdate><volume>22</volume><issue>12</issue><spage>1447</spage><epage>1450</epage><pages>1447-1450</pages><issn>1001-8417</issn><eissn>1878-5964</eissn><abstract>Novel isosorbide derivative containing perfluorocarbon group,bi（perfluorooctanesulfonyl）isosorbide ester as chiral dopant in liquid crystal,was synthesized.Chemical structure was characterized by elemental analysis,FT-IR,~1H NMR and ~（19）F NMR.The optical texture of the mixture was observed by polarized optical microscopy（POM）.Novel chiral dopant containing perfluorocarbon group had excellent optical activity.Its specific rotation and molar rotation were noticeable higher than those of bi（4-chloromethylbenzenecarbonic）isosorbide ester.The fluorocarbon group improved the molar rotation of chiral compound and did not affect optical rotation direction.The texture of the mixture added isosorbide derivative with fluorocarbon group showed the oily streak texture.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.cclet.2011.07.021</doi><tpages>4</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1001-8417 |
| ispartof | Chinese chemical letters, 2011-12, Vol.22 (12), p.1447-1450 |
| issn | 1001-8417 1878-5964 |
| language | eng |
| recordid | cdi_wanfang_journals_zghxkb201112016 |
| source | Elsevier ScienceDirect Journals Complete; Alma/SFX Local Collection |
| subjects | Fluorocarbon Liquid crystal Optical properties Surfaces Texture 光学活性 单硝酸异山梨酯 异山梨醇 手性化合物 掺杂 氟碳 液晶材料 衍生物 |
| title | Synthesis and optical activity of isosorbide chiral derivative containing fluorocarbon group as chiral dopant in liquid crystal materials |
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