Promoting effect of ethanol on the synthesis of N-(2-methylphenyl) hydroxylamine from o-nitrotoluene in Zn/H2O/CO2 system
O621.2; The promoting effect of ethanol on the synthesis of N-(2-methylphenyl)hydroxylamine from o-nitrotoluene in Zn/H2O/CO2 system was observed. By adding appropriate amount of ethanol, the selectivity of N-(2-methylphenyl)hydroxylamine increased from 71 % to 90% when the reduction was carried out...
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Veröffentlicht in: | Chinese chemical letters 2011-02, Vol.22 (2), p.221-224 |
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creator | Liu, Shi Juan Wang, Yan Hua Hao, Yuan Ping Jiang, Jing Yang |
description | O621.2; The promoting effect of ethanol on the synthesis of N-(2-methylphenyl)hydroxylamine from o-nitrotoluene in Zn/H2O/CO2 system was observed. By adding appropriate amount of ethanol, the selectivity of N-(2-methylphenyl)hydroxylamine increased from 71 % to 90% when the reduction was carried out at 25 ℃ under normal pressure of CO2. |
doi_str_mv | 10.1016/j.cclet.2010.09.024 |
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title | Promoting effect of ethanol on the synthesis of N-(2-methylphenyl) hydroxylamine from o-nitrotoluene in Zn/H2O/CO2 system |
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