Synthesis of polystyrene-styrene/butadiene diblock copolymers via reversible addition-fragmentation chain transfer miniemulsion polymerization

Polystyrene-styrene/butadiene diblock copolymers were synthesized via reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization.During the polymerization process,the molecular weight distribution was narrow and the numerical molecular weight of the copolymers increased with...

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Veröffentlicht in:Chinese chemical letters 2010-12, Vol.21 (12), p.1497-1500
Hauptverfasser: Wang, Zhen Xi, Zhang, Qing Hua, Yu, Yi Tao, Zhan, Xiao Li, Chen, Feng Qiu, Xiong, Ji Hai
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container_issue 12
container_start_page 1497
container_title Chinese chemical letters
container_volume 21
creator Wang, Zhen Xi
Zhang, Qing Hua
Yu, Yi Tao
Zhan, Xiao Li
Chen, Feng Qiu
Xiong, Ji Hai
description Polystyrene-styrene/butadiene diblock copolymers were synthesized via reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization.During the polymerization process,the molecular weight distribution was narrow and the numerical molecular weight of the copolymers increased with increasing conversion of monomers,which was close to the theoretical.FT-IR and ^1H NMR results indicated that the microstructure of the polymer was mainly 1,4-trans-butadiene with small amount of 1,2-units,and composition in the copolymers was obtained.
doi_str_mv 10.1016/j.cclet.2010.06.001
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subjects Miniemulsion polymerization
Polystyrene–styrene/butadiene diblock copolymers
Reversible addition-fragmentation chain transfer
分子量分布
嵌段共聚物
细乳液聚合
链转移
title Synthesis of polystyrene-styrene/butadiene diblock copolymers via reversible addition-fragmentation chain transfer miniemulsion polymerization
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