Synthesis of polystyrene-styrene/butadiene diblock copolymers via reversible addition-fragmentation chain transfer miniemulsion polymerization
Polystyrene-styrene/butadiene diblock copolymers were synthesized via reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization.During the polymerization process,the molecular weight distribution was narrow and the numerical molecular weight of the copolymers increased with...
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Veröffentlicht in: | Chinese chemical letters 2010-12, Vol.21 (12), p.1497-1500 |
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creator | Wang, Zhen Xi Zhang, Qing Hua Yu, Yi Tao Zhan, Xiao Li Chen, Feng Qiu Xiong, Ji Hai |
description | Polystyrene-styrene/butadiene diblock copolymers were synthesized via reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization.During the polymerization process,the molecular weight distribution was narrow and the numerical molecular weight of the copolymers increased with increasing conversion of monomers,which was close to the theoretical.FT-IR and ^1H NMR results indicated that the microstructure of the polymer was mainly 1,4-trans-butadiene with small amount of 1,2-units,and composition in the copolymers was obtained. |
doi_str_mv | 10.1016/j.cclet.2010.06.001 |
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All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c362t-d60c5d61c0fe5e82f69d7a9e11c7c3858614a3e061ee981fb911b4cb2f2dcea03</citedby><cites>FETCH-LOGICAL-c362t-d60c5d61c0fe5e82f69d7a9e11c7c3858614a3e061ee981fb911b4cb2f2dcea03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/84039X/84039X.jpg</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.cclet.2010.06.001$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3548,27923,27924,45994</link.rule.ids></links><search><creatorcontrib>Wang, Zhen Xi</creatorcontrib><creatorcontrib>Zhang, Qing Hua</creatorcontrib><creatorcontrib>Yu, Yi Tao</creatorcontrib><creatorcontrib>Zhan, Xiao Li</creatorcontrib><creatorcontrib>Chen, Feng Qiu</creatorcontrib><creatorcontrib>Xiong, Ji Hai</creatorcontrib><title>Synthesis of polystyrene-styrene/butadiene diblock copolymers via reversible addition-fragmentation chain transfer miniemulsion polymerization</title><title>Chinese chemical letters</title><addtitle>Chinese Chemical Letters</addtitle><description>Polystyrene-styrene/butadiene diblock copolymers were synthesized via reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization.During the polymerization process,the molecular weight distribution was narrow and the numerical molecular weight of the copolymers increased with increasing conversion of monomers,which was close to the theoretical.FT-IR and ^1H NMR results indicated that the microstructure of the polymer was mainly 1,4-trans-butadiene with small amount of 1,2-units,and composition in the copolymers was obtained.</description><subject>Miniemulsion polymerization</subject><subject>Polystyrene–styrene/butadiene diblock copolymers</subject><subject>Reversible addition-fragmentation chain transfer</subject><subject>分子量分布</subject><subject>嵌段共聚物</subject><subject>细乳液聚合</subject><subject>链转移</subject><issn>1001-8417</issn><issn>1878-5964</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNqFkM9u2zAMxo1hBda1e4JdhF12cipZtiwfdhiK_QMK7LD1LMgUlSixpU5S0qUP0Wee3OS-Eyny-0jqV1XvGV0xysTNdgUwYV41tFSoWFHKXlWXTPay7gbRvi55KdWyZf2b6m1KW0obKbm4rJ5_HX3eYHKJBEsewnRM-RjRY32ON-M-a-NKRowbpwA7AmHRzRgTOThNIh5KWnpItDEuu-BrG_V6Rp_18iKw0c6THLVPFiOZnXc476e09M6j3NOL9Lq6sHpK-O4cr6r7r19-336v735--3H7-a4GLppcG0GhM4IBtdihbKwYTK8HZAx64LKTgrWaIxUMcZDMjgNjYwtjYxsDqCm_qj6e5j5qb7Vfq23YR182qqf15u9uXECypkAqSn5SQgwpRbTqIbpZx6NiVC3w1Va9wFeLR1GhCuni-nRyYfnEwWFUCQpDQOMiQlYmuP_4P5y3boJf_3HlwlHDzroJVSHAu7bn_B9Z75_c</recordid><startdate>20101201</startdate><enddate>20101201</enddate><creator>Wang, Zhen Xi</creator><creator>Zhang, Qing Hua</creator><creator>Yu, Yi Tao</creator><creator>Zhan, Xiao Li</creator><creator>Chen, Feng Qiu</creator><creator>Xiong, Ji Hai</creator><general>Elsevier B.V</general><general>Department of Chemical and Biological Engineering,Zhejiang University,Hangzhou 310027,China%Institute of Energy Conversion,Jiangxi Academy of Sciences,Nanchang 330029,China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W94</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20101201</creationdate><title>Synthesis of polystyrene-styrene/butadiene diblock copolymers via reversible addition-fragmentation chain transfer miniemulsion polymerization</title><author>Wang, Zhen Xi ; Zhang, Qing Hua ; Yu, Yi Tao ; Zhan, Xiao Li ; Chen, Feng Qiu ; Xiong, Ji Hai</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c362t-d60c5d61c0fe5e82f69d7a9e11c7c3858614a3e061ee981fb911b4cb2f2dcea03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Miniemulsion polymerization</topic><topic>Polystyrene–styrene/butadiene diblock copolymers</topic><topic>Reversible addition-fragmentation chain transfer</topic><topic>分子量分布</topic><topic>嵌段共聚物</topic><topic>细乳液聚合</topic><topic>链转移</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Zhen Xi</creatorcontrib><creatorcontrib>Zhang, Qing Hua</creatorcontrib><creatorcontrib>Yu, Yi Tao</creatorcontrib><creatorcontrib>Zhan, Xiao Li</creatorcontrib><creatorcontrib>Chen, Feng Qiu</creatorcontrib><creatorcontrib>Xiong, Ji Hai</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-自然科学</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Chinese chemical letters</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Zhen Xi</au><au>Zhang, Qing Hua</au><au>Yu, Yi Tao</au><au>Zhan, Xiao Li</au><au>Chen, Feng Qiu</au><au>Xiong, Ji Hai</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis of polystyrene-styrene/butadiene diblock copolymers via reversible addition-fragmentation chain transfer miniemulsion polymerization</atitle><jtitle>Chinese chemical letters</jtitle><addtitle>Chinese Chemical Letters</addtitle><date>2010-12-01</date><risdate>2010</risdate><volume>21</volume><issue>12</issue><spage>1497</spage><epage>1500</epage><pages>1497-1500</pages><issn>1001-8417</issn><eissn>1878-5964</eissn><abstract>Polystyrene-styrene/butadiene diblock copolymers were synthesized via reversible addition-fragmentation chain transfer (RAFT) miniemulsion polymerization.During the polymerization process,the molecular weight distribution was narrow and the numerical molecular weight of the copolymers increased with increasing conversion of monomers,which was close to the theoretical.FT-IR and ^1H NMR results indicated that the microstructure of the polymer was mainly 1,4-trans-butadiene with small amount of 1,2-units,and composition in the copolymers was obtained.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.cclet.2010.06.001</doi><tpages>4</tpages></addata></record> |
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source | ScienceDirect Journals (5 years ago - present); Alma/SFX Local Collection |
subjects | Miniemulsion polymerization Polystyrene–styrene/butadiene diblock copolymers Reversible addition-fragmentation chain transfer 分子量分布 嵌段共聚物 细乳液聚合 链转移 |
title | Synthesis of polystyrene-styrene/butadiene diblock copolymers via reversible addition-fragmentation chain transfer miniemulsion polymerization |
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