Red Mechanoluminescence and Photoluminescence from Novel Europium Complexes

O6; Two new binuclear (europium and lanthanum) b -diketone complexes Eu0.9La0.1(TTA)3Phen and Eu0.5La0.5(TTA)3Phen in which Phen is 1,10-phenanthroline, TTA is an anion of thenoyltrifluoroacetone (HTTA) were synthesized for the first time. They showed intense photoluminescence (PL) and mechanolumine...

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Veröffentlicht in:中国化学快报(英文版) 2000-07, Vol.11 (7), p.635-638
Hauptverfasser: Wei Guo ZHU, Tong Suo YUAN, Xiao Qiang WEI, Zhi Yun LU, Yan HUANG, Yu LIU, Qiang PENG, Ming Gui XIE
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container_end_page 638
container_issue 7
container_start_page 635
container_title 中国化学快报(英文版)
container_volume 11
creator Wei Guo ZHU
Tong Suo YUAN
Xiao Qiang WEI
Zhi Yun LU
Yan HUANG
Yu LIU
Qiang PENG
Ming Gui XIE
description O6; Two new binuclear (europium and lanthanum) b -diketone complexes Eu0.9La0.1(TTA)3Phen and Eu0.5La0.5(TTA)3Phen in which Phen is 1,10-phenanthroline, TTA is an anion of thenoyltrifluoroacetone (HTTA) were synthesized for the first time. They showed intense photoluminescence (PL) and mechanoluminescence (ML), and had their maximum PL and ML spectra peaked at 613.5 nm with half bandwidth of 10 nm respectively. Their PL and ML intensity were obviously stronger than these from Eu(TTA)3Phen. It is considered that binuclear (europium and lanthanum) b -diketones complexes are promising ML and PL materials.
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They showed intense photoluminescence (PL) and mechanoluminescence (ML), and had their maximum PL and ML spectra peaked at 613.5 nm with half bandwidth of 10 nm respectively. Their PL and ML intensity were obviously stronger than these from Eu(TTA)3Phen. It is considered that binuclear (europium and lanthanum) b -diketones complexes are promising ML and PL materials.</description><identifier>ISSN: 1001-8417</identifier><language>eng</language><publisher>Department of Biochemistry, Qiongzhou University, Tongshi 572200</publisher><ispartof>中国化学快报(英文版), 2000-07, Vol.11 (7), p.635-638</ispartof><rights>Copyright © Wanfang Data Co. Ltd. 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title Red Mechanoluminescence and Photoluminescence from Novel Europium Complexes
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