Effect of tin addition on microstructure and electrochemical properties of rolled AZ61-Sn magnesium anodic materials
Microstructure characterization, corrosion behavior, and electrochemical properties of magnesium anode materials containing 1-3 wt.% Sn in AZ61 alloy were studied by optical microscopy, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, and energy-dispersive spec- troscopy （EDS）, constant...
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| Veröffentlicht in: | Rare metals 2011-12, Vol.30 (6), p.639-643 |
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| creator | Wang, Ping Li, Jianping Guo, Yongchun Yang, Zhong Xia, Feng Wang, Jianli |
| description | Microstructure characterization, corrosion behavior, and electrochemical properties of magnesium anode materials containing 1-3 wt.% Sn in AZ61 alloy were studied by optical microscopy, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, and energy-dispersive spec- troscopy （EDS）, constant current method, potential polarization, and drainage. The results showed that amount of Mg2Sn phase increased, and recrystallization ratio of Sn-contained Mg alloys during rolling process was improved with increasing of Sn content. This resulted in uniform and refined gains. The results also demonstrated that discharge potential was improved and hydrogen release rate was reduced with the addition of Sn. As the current density increased, the release hydrogen rate was rising, owing to negative variance effect of magnesium alloys. The current efficiency gets to 87% at 20 mA/cm2. The main components of the corrosion products are easy-to-peel-off MgO and Al2O3 that can lead to more negative and stable work potential and accelerate battery reaction continuously. |
| doi_str_mv | 10.1007/s12598-011-0442-y |
| format | Article |
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The results showed that amount of Mg2Sn phase increased, and recrystallization ratio of Sn-contained Mg alloys during rolling process was improved with increasing of Sn content. This resulted in uniform and refined gains. The results also demonstrated that discharge potential was improved and hydrogen release rate was reduced with the addition of Sn. As the current density increased, the release hydrogen rate was rising, owing to negative variance effect of magnesium alloys. The current efficiency gets to 87% at 20 mA/cm2. The main components of the corrosion products are easy-to-peel-off MgO and Al2O3 that can lead to more negative and stable work potential and accelerate battery reaction continuously.</description><identifier>ISSN: 1001-0521</identifier><identifier>EISSN: 1867-7185</identifier><identifier>DOI: 10.1007/s12598-011-0442-y</identifier><language>eng</language><publisher>Springer Berlin Heidelberg: Nonferrous Metals Society of China</publisher><subject>AZ61镁合金 ; Biomaterials ; Chemistry and Materials Science ; Current density ; Energy ; Hydrogen storage ; Magnesium ; Magnesium base alloys ; Materials Engineering ; Materials Science ; Metallic Materials ; Microstructure ; Nanoscale Science and Technology ; Physical Chemistry ; Scanning electron microscopy ; Tin ; Tin base alloys ; 光学显微镜 ; 微观结构表征 ; 扫描电子显微镜 ; 热轧 ; 电化学性能 ; 锡含量 ; 阳极材料</subject><ispartof>Rare metals, 2011-12, Vol.30 (6), p.639-643</ispartof><rights>The Nonferrous Metals Society of China and Springer-Verlag Berlin Heidelberg 2011</rights><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-9c97476a1b000f3ab876cb6f51f9ccededf4da6caa3dac69f83fc88cdd40f4ac3</citedby><cites>FETCH-LOGICAL-c406t-9c97476a1b000f3ab876cb6f51f9ccededf4da6caa3dac69f83fc88cdd40f4ac3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/85314X/85314X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12598-011-0442-y$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12598-011-0442-y$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27923,27924,41487,42556,51318</link.rule.ids></links><search><creatorcontrib>Wang, Ping</creatorcontrib><creatorcontrib>Li, Jianping</creatorcontrib><creatorcontrib>Guo, Yongchun</creatorcontrib><creatorcontrib>Yang, Zhong</creatorcontrib><creatorcontrib>Xia, Feng</creatorcontrib><creatorcontrib>Wang, Jianli</creatorcontrib><title>Effect of tin addition on microstructure and electrochemical properties of rolled AZ61-Sn magnesium anodic materials</title><title>Rare metals</title><addtitle>Rare Metals</addtitle><addtitle>Rare Metals</addtitle><description>Microstructure characterization, corrosion behavior, and electrochemical properties of magnesium anode materials containing 1-3 wt.% Sn in AZ61 alloy were studied by optical microscopy, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, and energy-dispersive spec- troscopy （EDS）, constant current method, potential polarization, and drainage. The results showed that amount of Mg2Sn phase increased, and recrystallization ratio of Sn-contained Mg alloys during rolling process was improved with increasing of Sn content. This resulted in uniform and refined gains. The results also demonstrated that discharge potential was improved and hydrogen release rate was reduced with the addition of Sn. As the current density increased, the release hydrogen rate was rising, owing to negative variance effect of magnesium alloys. The current efficiency gets to 87% at 20 mA/cm2. The main components of the corrosion products are easy-to-peel-off MgO and Al2O3 that can lead to more negative and stable work potential and accelerate battery reaction continuously.</description><subject>AZ61镁合金</subject><subject>Biomaterials</subject><subject>Chemistry and Materials Science</subject><subject>Current density</subject><subject>Energy</subject><subject>Hydrogen storage</subject><subject>Magnesium</subject><subject>Magnesium base alloys</subject><subject>Materials Engineering</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Microstructure</subject><subject>Nanoscale Science and Technology</subject><subject>Physical Chemistry</subject><subject>Scanning electron microscopy</subject><subject>Tin</subject><subject>Tin base alloys</subject><subject>光学显微镜</subject><subject>微观结构表征</subject><subject>扫描电子显微镜</subject><subject>热轧</subject><subject>电化学性能</subject><subject>锡含量</subject><subject>阳极材料</subject><issn>1001-0521</issn><issn>1867-7185</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp9kcFrHCEUxofSQtO0f0Bv017ay7TP0XXGYwhpGwjkkOTSi7j63LjM6kYdkv3v-5YJKfRQEJ74ft_31K9pPjL4xgCG74X1KzV2wFgHQvTd4VVzwkY5dAMbV69pD0CdVc_eNu9K2QJBUsJJUy-8R1vb5NsaYmucCzWk2NLaBZtTqXm2dc7YmuhanIjNyd4jNc3U7nPaY64By9Egp2lC1579lqy7Ib3ZRCxh3pE0uWDpoGIOZirvmzeeCn54rqfN3Y-L2_Nf3dX1z8vzs6vOCpC1U1YNYpCGrQHAc7MeB2nX0q-YV9aiQ-eFM9Iaw52xUvmRezuO1jkBXhjLT5svi--jid7Ejd6mOUeaqJ8O26Kxp-8CCUwQ-XUh6UUPM5aqd6FYnCYTMc1FM2BKct6rkdDP_6AvropC4P3AFUFsgY5fWDJ6vc9hZ_KBnPQxML0EpukG-hiYPpCmXzSF2LjB_Nf4f6JPz4PuU9w8kO5lkgDBFGc9_wNxbqZS</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Wang, Ping</creator><creator>Li, Jianping</creator><creator>Guo, Yongchun</creator><creator>Yang, Zhong</creator><creator>Xia, Feng</creator><creator>Wang, Jianli</creator><general>Nonferrous Metals Society of China</general><general>Springer Nature B.V</general><general>School of Materials and Chemical Engineering, Xi'an Technological University, Xi'an 710032, China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W92</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7QF</scope><scope>7SE</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20111201</creationdate><title>Effect of tin addition on microstructure and electrochemical properties of rolled AZ61-Sn magnesium anodic materials</title><author>Wang, Ping ; Li, Jianping ; Guo, Yongchun ; Yang, Zhong ; Xia, Feng ; Wang, Jianli</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-9c97476a1b000f3ab876cb6f51f9ccededf4da6caa3dac69f83fc88cdd40f4ac3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>AZ61镁合金</topic><topic>Biomaterials</topic><topic>Chemistry and Materials Science</topic><topic>Current density</topic><topic>Energy</topic><topic>Hydrogen storage</topic><topic>Magnesium</topic><topic>Magnesium base alloys</topic><topic>Materials Engineering</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Microstructure</topic><topic>Nanoscale Science and Technology</topic><topic>Physical Chemistry</topic><topic>Scanning electron microscopy</topic><topic>Tin</topic><topic>Tin base alloys</topic><topic>光学显微镜</topic><topic>微观结构表征</topic><topic>扫描电子显微镜</topic><topic>热轧</topic><topic>电化学性能</topic><topic>锡含量</topic><topic>阳极材料</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Ping</creatorcontrib><creatorcontrib>Li, Jianping</creatorcontrib><creatorcontrib>Guo, Yongchun</creatorcontrib><creatorcontrib>Yang, Zhong</creatorcontrib><creatorcontrib>Xia, Feng</creatorcontrib><creatorcontrib>Wang, Jianli</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-工程技术</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>Aluminium Industry Abstracts</collection><collection>Corrosion Abstracts</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Rare metals</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Ping</au><au>Li, Jianping</au><au>Guo, Yongchun</au><au>Yang, Zhong</au><au>Xia, Feng</au><au>Wang, Jianli</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Effect of tin addition on microstructure and electrochemical properties of rolled AZ61-Sn magnesium anodic materials</atitle><jtitle>Rare metals</jtitle><stitle>Rare Metals</stitle><addtitle>Rare Metals</addtitle><date>2011-12-01</date><risdate>2011</risdate><volume>30</volume><issue>6</issue><spage>639</spage><epage>643</epage><pages>639-643</pages><issn>1001-0521</issn><eissn>1867-7185</eissn><abstract>Microstructure characterization, corrosion behavior, and electrochemical properties of magnesium anode materials containing 1-3 wt.% Sn in AZ61 alloy were studied by optical microscopy, X-ray diffraction （XRD）, scanning electron microscopy （SEM）, and energy-dispersive spec- troscopy （EDS）, constant current method, potential polarization, and drainage. The results showed that amount of Mg2Sn phase increased, and recrystallization ratio of Sn-contained Mg alloys during rolling process was improved with increasing of Sn content. This resulted in uniform and refined gains. The results also demonstrated that discharge potential was improved and hydrogen release rate was reduced with the addition of Sn. As the current density increased, the release hydrogen rate was rising, owing to negative variance effect of magnesium alloys. The current efficiency gets to 87% at 20 mA/cm2. The main components of the corrosion products are easy-to-peel-off MgO and Al2O3 that can lead to more negative and stable work potential and accelerate battery reaction continuously.</abstract><cop>Springer Berlin Heidelberg</cop><pub>Nonferrous Metals Society of China</pub><doi>10.1007/s12598-011-0442-y</doi><tpages>5</tpages></addata></record> |
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| subjects | AZ61镁合金 Biomaterials Chemistry and Materials Science Current density Energy Hydrogen storage Magnesium Magnesium base alloys Materials Engineering Materials Science Metallic Materials Microstructure Nanoscale Science and Technology Physical Chemistry Scanning electron microscopy Tin Tin base alloys 光学显微镜 微观结构表征 扫描电子显微镜 热轧 电化学性能 锡含量 阳极材料 |
| title | Effect of tin addition on microstructure and electrochemical properties of rolled AZ61-Sn magnesium anodic materials |
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