Catalytic perfomance of rhodium chalcogen halides and rhodium chalcogenides over silica supports in methane oxidative carbonylation

The gas phase methane oxidative carbonylation was studied in the presence of molecular oxygen over silica materials including their mechanical mixtures with rhodium chalcogen chlorides obtained in non-aqueous inorganic media. The formation of Rh4SCl7, Rh4S9Cl2, Rh4SesCl3 and Rh3Se3Cl solids was conf...

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Veröffentlicht in:Journal of natural gas chemistry 2009-12, Vol.18 (4), p.399-406
Hauptverfasser: Volkov, S.V., Kosmambetova, G.R., Kharkova, L.B., Shvets, O.V., Yanko, O.G., Gritsenko, V.I., Strizhak, P.E.
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Sprache:eng
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