Oil-soluble Ni-Mo sulfide nanoparticles and their hydrogenation catalytic properties
Oil-soluble bimetallic Ni-Mo sulfide nanoparticles（NiMoS） with narrow size distribution were successfully synthesized through a composite-surfactants-assisted-solvothermal process.The surface functionality and lipophilicity of the Ni-Mo sulfides were shown by transmission electronic microscopy,Fouri...
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| Veröffentlicht in: | Petroleum science 2013-12, Vol.10 (4), p.571-576 |
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| creator | Liu, Chenguang Wang, Shutao An, Changhua Yan, Fang He, Jie Wang, Zongxian Zhang, Qin-Hui |
| description | Oil-soluble bimetallic Ni-Mo sulfide nanoparticles（NiMoS） with narrow size distribution were successfully synthesized through a composite-surfactants-assisted-solvothermal process.The surface functionality and lipophilicity of the Ni-Mo sulfides were shown by transmission electronic microscopy,Fourier transform infrared and ultraviolet spectroscopy.The as-prepared Ni-Mo sulfides supported on activated carbon（NiMoS/AC） exhibited enhanced catalytic activity towards naphthalene hydrogenation instead of cracking.For comparison,CoMoS/AC and MoS2/AC catalysts were also prepared through similar procedures,and it was found that their catalytic performance decreased in the order of NiMoS/AC〉CoMoS/AC〉MoS2/AC.Furthermore,the activity of the bimetallic NiMoS nanocatalyst can be effectively tuned via variation of the atomic ratio of Ni/（Ni＋Mo）. |
| doi_str_mv | 10.1007/s12182-013-0308-z |
| format | Article |
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All Rights Reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c389t-8e28b0ddfd726bf098f30bd0ad13c053dc0c4ec6ce8486d92dea2f56b1f465693</citedby><cites>FETCH-LOGICAL-c389t-8e28b0ddfd726bf098f30bd0ad13c053dc0c4ec6ce8486d92dea2f56b1f465693</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/87756X/87756X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12182-013-0308-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://doi.org/10.1007/s12182-013-0308-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41120,42189,51576</link.rule.ids><linktorsrc>$$Uhttps://doi.org/10.1007/s12182-013-0308-z$$EView_record_in_Springer_Nature$$FView_record_in_$$GSpringer_Nature</linktorsrc></links><search><creatorcontrib>Liu, Chenguang</creatorcontrib><creatorcontrib>Wang, Shutao</creatorcontrib><creatorcontrib>An, Changhua</creatorcontrib><creatorcontrib>Yan, Fang</creatorcontrib><creatorcontrib>He, Jie</creatorcontrib><creatorcontrib>Wang, Zongxian</creatorcontrib><creatorcontrib>Zhang, Qin-Hui</creatorcontrib><title>Oil-soluble Ni-Mo sulfide nanoparticles and their hydrogenation catalytic properties</title><title>Petroleum science</title><addtitle>Pet. 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| subjects | Earth and Environmental Science Earth Sciences Economics and Management Energy Policy Industrial and Production Engineering Industrial Chemistry/Chemical Engineering Mineral Resources 催化性能 加氢 复合表面活性剂 油溶性 硫化物 纳米粒子 透射电子显微镜 镍钼 |
| title | Oil-soluble Ni-Mo sulfide nanoparticles and their hydrogenation catalytic properties |
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