Strontium Isotope Compositions of Hydrothermal Barite from the Yonaguni IV: Insight into Fluid/Sediment Interaction and Barite Crystallization Condition

Hydrothermal barite is a typical low-temperature mineral formed during the mixing of hydrothermal fluid and seawater. Because of its extremely low solubility, barite behaves as a close system after crystallization and preserves the geochemical fingerprint of hydrothermal fluid. In this study, the el...

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Veröffentlicht in:Journal of Ocean University of China 2020-04, Vol.19 (2), p.377-385
Hauptverfasser: Zhang, Xia, Zhai, Shikui, Yu, Zenghui
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description Hydrothermal barite is a typical low-temperature mineral formed during the mixing of hydrothermal fluid and seawater. Because of its extremely low solubility, barite behaves as a close system after crystallization and preserves the geochemical fingerprint of hydrothermal fluid. In this study, the elemental contents and Sr isotope compositions of hydrothermal barites from the Yonaguni IV were determined using electron microprobe and LA-MC-ICP-MS respectively. On these bases, the fluid/sediment interaction during the hydrothermal circulation and physicochemical condition of barite crystallization were discussed. Results show that the 87Sr/86Sr values of hydrothermal barites from the Yonaguni IV are apparently higher than those of the seawater and associated volcanic rocks, indicating the sufficient interaction between the hydrothermal fluid and overlying sediment. Monomineral Sr abundance shows large variations, reflecting the changes in barite growth rate during the fluid mixing. The mineralization condition in the Yonaguni IV was unstable. During the crystallization of barite, hydrothermal fluid and seawater mixed in varying degrees, with the proportions of hydrothermal fluid varied from 36% to 72%. The calculated crystallization temperatures range from 109 to 220°C. Sediment plays a critical role during the mineralization process in the Yonaguni IV and incorporation of sediment component into hydrothermal system was prior to barite crystallization and sulfide mineralization.
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During the crystallization of barite, hydrothermal fluid and seawater mixed in varying degrees, with the proportions of hydrothermal fluid varied from 36% to 72%. The calculated crystallization temperatures range from 109 to 220°C. 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Ocean Univ. China</addtitle><description>Hydrothermal barite is a typical low-temperature mineral formed during the mixing of hydrothermal fluid and seawater. Because of its extremely low solubility, barite behaves as a close system after crystallization and preserves the geochemical fingerprint of hydrothermal fluid. In this study, the elemental contents and Sr isotope compositions of hydrothermal barites from the Yonaguni IV were determined using electron microprobe and LA-MC-ICP-MS respectively. On these bases, the fluid/sediment interaction during the hydrothermal circulation and physicochemical condition of barite crystallization were discussed. Results show that the 87Sr/86Sr values of hydrothermal barites from the Yonaguni IV are apparently higher than those of the seawater and associated volcanic rocks, indicating the sufficient interaction between the hydrothermal fluid and overlying sediment. 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1993-5021
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source Springer Nature - Complete Springer Journals; Alma/SFX Local Collection
subjects Barite
Chemical fingerprinting
Composition
Crystallization
Earth and Environmental Science
Earth Sciences
Electron microprobe
Electron probes
Growth rate
Hydrothermal systems
Isotopes
Low temperature
Meteorology
Mineralization
Oceanography
Seawater
Sediment
Sediments
Strontium
Strontium 87
Strontium isotopes
Sulfides
Sulphides
Volcanic rocks
title Strontium Isotope Compositions of Hydrothermal Barite from the Yonaguni IV: Insight into Fluid/Sediment Interaction and Barite Crystallization Condition
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