Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants

A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, w...

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Veröffentlicht in:Journal of environmental sciences (China) 2011-01, Vol.23 (6), p.1027-1032
Hauptverfasser: Takahashi, Shigehiro, Abiko, Naoyuki, Haraguchi, Nobuhiro, Fujita, Hiroyuki, Seki, Eriko, Ono, Tetsuya, Yoshida, Kentaro, Anzai, Jun-ichi
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container_issue 6
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container_title Journal of environmental sciences (China)
container_volume 23
creator Takahashi, Shigehiro
Abiko, Naoyuki
Haraguchi, Nobuhiro
Fujita, Hiroyuki
Seki, Eriko
Ono, Tetsuya
Yoshida, Kentaro
Anzai, Jun-ichi
description A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.
doi_str_mv 10.1016/S1001-0742(10)60509-8
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subjects additives
Boronic Acids - chemistry
cyclic voltammetry
electrochemical determination
electrochemistry
Electrochemistry - methods
esters
ferroceneboronic acid
Ferrous Compounds - chemistry
Metallocenes
Molecular Structure
oxidation
Oxidation-Reduction
phenolic compound
phenolic compounds
Phenols - chemistry
pollutants
pollutants in water
sugar
Water Pollutants - chemistry
二醇
伏安法
循环伏安
有机污染物
氧化还原活性
电化学测定
还原峰
酚类化合物
title Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants
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