Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants
A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, w...
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Veröffentlicht in: | Journal of environmental sciences (China) 2011-01, Vol.23 (6), p.1027-1032 |
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container_title | Journal of environmental sciences (China) |
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creator | Takahashi, Shigehiro Abiko, Naoyuki Haraguchi, Nobuhiro Fujita, Hiroyuki Seki, Eriko Ono, Tetsuya Yoshida, Kentaro Anzai, Jun-ichi |
description | A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water. |
doi_str_mv | 10.1016/S1001-0742(10)60509-8 |
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A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.</description><identifier>ISSN: 1001-0742</identifier><identifier>EISSN: 1878-7320</identifier><identifier>DOI: 10.1016/S1001-0742(10)60509-8</identifier><identifier>PMID: 22066227</identifier><language>eng</language><publisher>Netherlands: Elsevier B.V</publisher><subject>additives ; Boronic Acids - chemistry ; cyclic voltammetry ; electrochemical determination ; electrochemistry ; Electrochemistry - methods ; esters ; ferroceneboronic acid ; Ferrous Compounds - chemistry ; Metallocenes ; Molecular Structure ; oxidation ; Oxidation-Reduction ; phenolic compound ; phenolic compounds ; Phenols - chemistry ; pollutants ; pollutants in water ; sugar ; Water Pollutants - chemistry ; 二醇 ; 伏安法 ; 循环伏安 ; 有机污染物 ; 氧化还原活性 ; 电化学测定 ; 还原峰 ; 酚类化合物</subject><ispartof>Journal of environmental sciences (China), 2011-01, Vol.23 (6), p.1027-1032</ispartof><rights>2011 The Research Centre for Eco-Environmental Sciences, Chinese Academy of Sciences</rights><rights>Copyright © Wanfang Data Co. 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All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c477t-9cf0d9b3a64ea45d8f59746e8385435f8eeadf5dd10e4fcd20333ea0fc267fba3</citedby><cites>FETCH-LOGICAL-c477t-9cf0d9b3a64ea45d8f59746e8385435f8eeadf5dd10e4fcd20333ea0fc267fba3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/85265X/85265X.jpg</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S1001074210605098$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3537,27901,27902,65306</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/22066227$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Takahashi, Shigehiro</creatorcontrib><creatorcontrib>Abiko, Naoyuki</creatorcontrib><creatorcontrib>Haraguchi, Nobuhiro</creatorcontrib><creatorcontrib>Fujita, Hiroyuki</creatorcontrib><creatorcontrib>Seki, Eriko</creatorcontrib><creatorcontrib>Ono, Tetsuya</creatorcontrib><creatorcontrib>Yoshida, Kentaro</creatorcontrib><creatorcontrib>Anzai, Jun-ichi</creatorcontrib><title>Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants</title><title>Journal of environmental sciences (China)</title><addtitle>Journal of Environmental Sciences</addtitle><description>A voltammetric determination of possible organic pollutants such as diol and phenolic compounds in water was studied using ferroceneboronic acid (FBA) as a redox-active marker. A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.</description><subject>additives</subject><subject>Boronic Acids - chemistry</subject><subject>cyclic voltammetry</subject><subject>electrochemical determination</subject><subject>electrochemistry</subject><subject>Electrochemistry - methods</subject><subject>esters</subject><subject>ferroceneboronic acid</subject><subject>Ferrous Compounds - chemistry</subject><subject>Metallocenes</subject><subject>Molecular Structure</subject><subject>oxidation</subject><subject>Oxidation-Reduction</subject><subject>phenolic compound</subject><subject>phenolic compounds</subject><subject>Phenols - chemistry</subject><subject>pollutants</subject><subject>pollutants in water</subject><subject>sugar</subject><subject>Water Pollutants - chemistry</subject><subject>二醇</subject><subject>伏安法</subject><subject>循环伏安</subject><subject>有机污染物</subject><subject>氧化还原活性</subject><subject>电化学测定</subject><subject>还原峰</subject><subject>酚类化合物</subject><issn>1001-0742</issn><issn>1878-7320</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>EIF</sourceid><recordid>eNqFkUtv1DAUhSMEomXgJwBhw2MRuH4lzgqhipdUiUUpW8tjX089SuzUTkD8ezzNDNuufOX7Xd_jc6rqOYH3BEj74YoAkAY6Tt8SeNeCgL6RD6pzIjvZdIzCw1KfkLPqSc57AOACxOPqjFJoW0q788r-isOsxxHn5E2dME8xZKyjqx2mFA0G3MYUQ2lq4209x9r6ONQ62Hq6wRCH0jFxnOISbK51rqeYs98OWIphWGYd5vy0euT0kPHZ8dxU118-_7z41lz--Pr94tNlY3jXzU1vHNh-y3TLUXNhpRN9x1uUTArOhJOI2jphLQHkzlgKjDHU4AxtO7fVbFO9Xt_9o4PTYaf2cUmhbFR7zAopEAItlLFN9WYFpxRvF8yzGn02OAw6YFyy6oERLono7iVl11IGktNCipU0qTiQ0Kkp-VGnv4qAOkSm7iJThzwOV3eRKVnmXhw3LNsR7f-pU0YFeLkCTkeld8lndX1V_iIAKJGEHIiPK4HF3N8ek8rGYzBofUIzKxv9vSJeHcXfxLC79cW7kw4mCedAJPsHl2C7NQ</recordid><startdate>20110101</startdate><enddate>20110101</enddate><creator>Takahashi, Shigehiro</creator><creator>Abiko, Naoyuki</creator><creator>Haraguchi, Nobuhiro</creator><creator>Fujita, Hiroyuki</creator><creator>Seki, Eriko</creator><creator>Ono, Tetsuya</creator><creator>Yoshida, Kentaro</creator><creator>Anzai, Jun-ichi</creator><general>Elsevier B.V</general><general>School of Pharmaceutical Sciences, Ohu University, 31-1 Misumido, Tomita-machi, Koriyama, Fukushima 963-8611, Japan</general><general>Graduate School of Pharmaceutical Sciences, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan%Graduate School of Pharmaceutical Sciences, Tohoku University, Aramaki, Aoba-ku, Sendai 980-8578, Japan</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W92</scope><scope>~WA</scope><scope>FBQ</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7QH</scope><scope>7ST</scope><scope>7TV</scope><scope>7UA</scope><scope>C1K</scope><scope>F1W</scope><scope>H97</scope><scope>L.G</scope><scope>SOI</scope><scope>7X8</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20110101</creationdate><title>Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants</title><author>Takahashi, Shigehiro ; 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A cyclic voltammogram of FBA exhibited a pair of oxidation and reduction peaks at 230 and 170 mV at pH 7.0, respectively, while another pair of redox peaks was observed in the presence of diol or phenolic compounds tested. The results were rationalized based on the formation of boronate esters of FBA with the added compounds. The changes in the redox peak currents were dependent on the concentration of the additives, suggesting a usefulness of FBA in the electrochemical determination of these compounds in water.</abstract><cop>Netherlands</cop><pub>Elsevier B.V</pub><pmid>22066227</pmid><doi>10.1016/S1001-0742(10)60509-8</doi><tpages>6</tpages></addata></record> |
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subjects | additives Boronic Acids - chemistry cyclic voltammetry electrochemical determination electrochemistry Electrochemistry - methods esters ferroceneboronic acid Ferrous Compounds - chemistry Metallocenes Molecular Structure oxidation Oxidation-Reduction phenolic compound phenolic compounds Phenols - chemistry pollutants pollutants in water sugar Water Pollutants - chemistry 二醇 伏安法 循环伏安 有机污染物 氧化还原活性 电化学测定 还原峰 酚类化合物 |
title | Voltammetric response of ferroceneboronic acid to diol and phenolic compounds as possible pollutants |
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