The distribution of iodine and effects of phosphatization on it in the ferromanganese crusts from the Mid-Pacific Ocean

In the present paper, iodine (I), iron (Fe), manganese (Mn), cobalt (Co), phosphorus (P) and calcium (Ca) contents in three ferromanganese crusts from the Pacific Ocean are measured by spectrophotometric method and inductively coupled plasma atomic emission spectrometers (ICP-AES) to investigate the...

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Veröffentlicht in:Acta oceanologica Sinica 2015-08, Vol.34 (8), p.13-19
Hauptverfasser: Ji, Lihong, Liu, Guangshan, Huang, Yipu, Xing, Na, Chen, Zhigang
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creator Ji, Lihong
Liu, Guangshan
Huang, Yipu
Xing, Na
Chen, Zhigang
description In the present paper, iodine (I), iron (Fe), manganese (Mn), cobalt (Co), phosphorus (P) and calcium (Ca) contents in three ferromanganese crusts from the Pacific Ocean are measured by spectrophotometric method and inductively coupled plasma atomic emission spectrometers (ICP-AES) to investigate the contents and distribution of iodine in ferromanganese crusts. The results show that iodine contents in three crusts vary between 27.1 and 836 mg/kg, with an average of 172 mg/kg, and the profile of iodine in the three crusts all exhibits a two-stage distribution zone: a young non-phosphatized zone and an old phosphatized zone that is rich in I, P and Ca. The iodine content ratios of old to young zone in MP5D44, CXD62-1 and CXD08-1 are 2.3, 3.4 and 13.7, respectively. The boundary depths of two-stage zone in MP5D44, CXD62-1 and CXD08-1 locate at 4.0 cm, 2.5 cm and 3.75 cm, respectively, and the time of iodine mutation in three crusts ranges from 17-37 Ma derived from 129I dating and Co empirical formula, which is consistent with the times of Cenozoic phosphatization events. The present study shows that the intensity of phosphatization is the main responsible for the distribution pattern of iodine in the crusts on the basis of the correlation analysis. Consequently, iodine is a sensitive indicator for phosphatization.
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The results show that iodine contents in three crusts vary between 27.1 and 836 mg/kg, with an average of 172 mg/kg, and the profile of iodine in the three crusts all exhibits a two-stage distribution zone: a young non-phosphatized zone and an old phosphatized zone that is rich in I, P and Ca. The iodine content ratios of old to young zone in MP5D44, CXD62-1 and CXD08-1 are 2.3, 3.4 and 13.7, respectively. The boundary depths of two-stage zone in MP5D44, CXD62-1 and CXD08-1 locate at 4.0 cm, 2.5 cm and 3.75 cm, respectively, and the time of iodine mutation in three crusts ranges from 17-37 Ma derived from 129I dating and Co empirical formula, which is consistent with the times of Cenozoic phosphatization events. The present study shows that the intensity of phosphatization is the main responsible for the distribution pattern of iodine in the crusts on the basis of the correlation analysis. 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Sin</addtitle><addtitle>Acta Oceanologica Sinica</addtitle><description>In the present paper, iodine (I), iron (Fe), manganese (Mn), cobalt (Co), phosphorus (P) and calcium (Ca) contents in three ferromanganese crusts from the Pacific Ocean are measured by spectrophotometric method and inductively coupled plasma atomic emission spectrometers (ICP-AES) to investigate the contents and distribution of iodine in ferromanganese crusts. The results show that iodine contents in three crusts vary between 27.1 and 836 mg/kg, with an average of 172 mg/kg, and the profile of iodine in the three crusts all exhibits a two-stage distribution zone: a young non-phosphatized zone and an old phosphatized zone that is rich in I, P and Ca. The iodine content ratios of old to young zone in MP5D44, CXD62-1 and CXD08-1 are 2.3, 3.4 and 13.7, respectively. 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Sin</stitle><addtitle>Acta Oceanologica Sinica</addtitle><date>2015-08-01</date><risdate>2015</risdate><volume>34</volume><issue>8</issue><spage>13</spage><epage>19</epage><pages>13-19</pages><issn>0253-505X</issn><eissn>1869-1099</eissn><abstract>In the present paper, iodine (I), iron (Fe), manganese (Mn), cobalt (Co), phosphorus (P) and calcium (Ca) contents in three ferromanganese crusts from the Pacific Ocean are measured by spectrophotometric method and inductively coupled plasma atomic emission spectrometers (ICP-AES) to investigate the contents and distribution of iodine in ferromanganese crusts. The results show that iodine contents in three crusts vary between 27.1 and 836 mg/kg, with an average of 172 mg/kg, and the profile of iodine in the three crusts all exhibits a two-stage distribution zone: a young non-phosphatized zone and an old phosphatized zone that is rich in I, P and Ca. The iodine content ratios of old to young zone in MP5D44, CXD62-1 and CXD08-1 are 2.3, 3.4 and 13.7, respectively. The boundary depths of two-stage zone in MP5D44, CXD62-1 and CXD08-1 locate at 4.0 cm, 2.5 cm and 3.75 cm, respectively, and the time of iodine mutation in three crusts ranges from 17-37 Ma derived from 129I dating and Co empirical formula, which is consistent with the times of Cenozoic phosphatization events. The present study shows that the intensity of phosphatization is the main responsible for the distribution pattern of iodine in the crusts on the basis of the correlation analysis. Consequently, iodine is a sensitive indicator for phosphatization.</abstract><cop>Beijing</cop><pub>The Chinese Society of Oceanography</pub><doi>10.1007/s13131-015-0704-x</doi><tpages>7</tpages></addata></record>
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issn 0253-505X
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language eng
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source SpringerLink (Online service); Alma/SFX Local Collection; ProQuest Central
subjects Calcium
Cenozoic
Climatology
Cobalt
Concretions
Correlation analysis
Crusts
Distribution
Earth and Environmental Science
Earth Sciences
Ecology
Emission analysis
Empirical analysis
Engineering Fluid Dynamics
Environmental Chemistry
Ferromanganese
Ferromanganese nodules
ICP-AES
Inductively coupled plasma
Iodine
Iron
Manganese
Marine & Freshwater Sciences
Metal oxides
Mountains
Oceanography
Phosphating (coating)
Phosphatization
Phosphorus
Sediments
Spectrometers
Spectrophotometry
中太平洋
分光光度法测定
富钴结壳
电感耦合等离子体原子发射光谱仪

磷化
经验公式
title The distribution of iodine and effects of phosphatization on it in the ferromanganese crusts from the Mid-Pacific Ocean
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