M(OTf)3催化N-烷氧羰基吡咯或噻吩与甲醛和盐酸伯胺的新颖Mannich反应
O6; 三氟甲磺酸盐M(OTf)3(M=Sc,Y,Ln)在水相中能较好地催化N-烷氧羰基吡咯或噻吩与甲醛和盐酸伯胺的新颖的Mannich反应,其中Y(OTf)3催化效果最佳.该反应具有条件温和,收率较高和原子经济性等优点,为N-烷氧羰基吡咯和噻吩类Mannich碱的合成提供了一种新方法,同时该反应以水为主要溶剂,符合当今绿色化学的发展趋势....
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| Veröffentlicht in: | 化学学报 2002, Vol.60 (3), p.481-486 |
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| container_end_page | 486 |
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| container_issue | 3 |
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| container_title | 化学学报 |
| container_volume | 60 |
| creator | 张传新 程铁明 李润涛 |
| description | O6; 三氟甲磺酸盐M(OTf)3(M=Sc,Y,Ln)在水相中能较好地催化N-烷氧羰基吡咯或噻吩与甲醛和盐酸伯胺的新颖的Mannich反应,其中Y(OTf)3催化效果最佳.该反应具有条件温和,收率较高和原子经济性等优点,为N-烷氧羰基吡咯和噻吩类Mannich碱的合成提供了一种新方法,同时该反应以水为主要溶剂,符合当今绿色化学的发展趋势. |
| doi_str_mv | 10.3321/j.issn:0567-7351.2002.03.018 |
| format | Article |
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| fulltext | fulltext |
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| source | Wiley Journals |
| title | M(OTf)3催化N-烷氧羰基吡咯或噻吩与甲醛和盐酸伯胺的新颖Mannich反应 |
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