Laser Light Scattering Study on Aggregation of Cellulose Diacetate in Acetone

We have investigated the properties of cellulose diacetate in solution by using laser light scattering. The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chains. As the concentration increases, the average hydrodynamic radius (Rh) linearly in...

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Veröffentlicht in:Chinese journal of chemical physics 2014-06, Vol.27 (3), p.256-258
Hauptverfasser: Xie, Ding-hai, Li, Xu-hua, Fang, Xi-ling, Ma, Chun-feng
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Li, Xu-hua
Fang, Xi-ling
Ma, Chun-feng
description We have investigated the properties of cellulose diacetate in solution by using laser light scattering. The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chains. As the concentration increases, the average hydrodynamic radius (Rh) linearly increases, whereas the ratio of gyration radius to hydrodynamic radins 〈Rg〉/〈Rh〉 linearly decreases. It indicates that the micelles associate and form micellar clusters due to the intermolecular interactions.
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subjects 丙酮
二乙酸酯
二醋酸纤维素
分子间相互作用
回转半径
流体动力学
激光光散射
聚集
title Laser Light Scattering Study on Aggregation of Cellulose Diacetate in Acetone
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