Laser Light Scattering Study on Aggregation of Cellulose Diacetate in Acetone
We have investigated the properties of cellulose diacetate in solution by using laser light scattering. The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chains. As the concentration increases, the average hydrodynamic radius (Rh) linearly in...
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Veröffentlicht in: | Chinese journal of chemical physics 2014-06, Vol.27 (3), p.256-258 |
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creator | Xie, Ding-hai Li, Xu-hua Fang, Xi-ling Ma, Chun-feng |
description | We have investigated the properties of cellulose diacetate in solution by using laser light scattering. The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chains. As the concentration increases, the average hydrodynamic radius (Rh) linearly increases, whereas the ratio of gyration radius to hydrodynamic radins 〈Rg〉/〈Rh〉 linearly decreases. It indicates that the micelles associate and form micellar clusters due to the intermolecular interactions. |
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The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chains. As the concentration increases, the average hydrodynamic radius (Rh) linearly increases, whereas the ratio of gyration radius to hydrodynamic radins 〈Rg〉/〈Rh〉 linearly decreases. 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The cellulose diacetate molecules can form micelles and micellar clusters in acetone besides the individual chains. As the concentration increases, the average hydrodynamic radius (Rh) linearly increases, whereas the ratio of gyration radius to hydrodynamic radins 〈Rg〉/〈Rh〉 linearly decreases. It indicates that the micelles associate and form micellar clusters due to the intermolecular interactions.</abstract><pub>Technology Center, China Tobacco Guangdong Industrial Co., Ltd., Guangzhou 510385, China%Faculty of Materials Science and Engineering, South China University of Technology, Guangzhou 510640, China</pub><doi>10.1063/1674-0068/27/03/256-258</doi><tpages>3</tpages></addata></record> |
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subjects | 丙酮 二乙酸酯 二醋酸纤维素 分子间相互作用 回转半径 流体动力学 激光光散射 聚集 |
title | Laser Light Scattering Study on Aggregation of Cellulose Diacetate in Acetone |
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