Solvothermal Synthesis and Characterization of Sheet Structure Containing Adamantane [Hg_2Sn_2S_（10）]~（8-） Anions
Sheet Rb2HgSnS4 was synthesized solvothermally and characterized by X-ray single crystal diffraction. The compound is comprised of sheets with admantane-like [Hg2Sn2S10]8– units. The crystals belong to the space group C2/c, with the unit cell parameters a=1.1063（2） nm, b=1.1071（2） nm, c=1.5741（3） nm...
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| Veröffentlicht in: | 高等学校化学研究（英文版） 2011, Vol.27 (6), p.915-918 |
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| container_title | 高等学校化学研究（英文版） |
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| creator | BAIYIN Meng-he LIANG Feng-ying XU Xiao-qing TA Na NA Mi-la BAI Wu-yun BAO Yong-sheng |
| description | Sheet Rb2HgSnS4 was synthesized solvothermally and characterized by X-ray single crystal diffraction. The compound is comprised of sheets with admantane-like [Hg2Sn2S10]8– units. The crystals belong to the space group C2/c, with the unit cell parameters a=1.1063（2） nm, b=1.1071（2） nm, c=1.5741（3） nm, a=90o, β=100.13（3）o, γ=90o. A reflectance spectroscopy study reveals the nature of the semiconductor with an energy of 2.1 eV for the compound. |
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The compound is comprised of sheets with admantane-like [Hg2Sn2S10]8– units. The crystals belong to the space group C2/c, with the unit cell parameters a=1.1063（2） nm, b=1.1071（2） nm, c=1.5741（3） nm, a=90o, β=100.13（3）o, γ=90o. A reflectance spectroscopy study reveals the nature of the semiconductor with an energy of 2.1 eV for the compound.</abstract><pub>Inner Mongolian Key Laboratory for Physics and Chemistry of Functional Materials,Inner Mongolia Normal University, Huhhot 010022, P.R.China%College of Chemistry and Environmental Science</pub><tpages>4</tpages></addata></record> |
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| ispartof | 高等学校化学研究（英文版）, 2011, Vol.27 (6), p.915-918 |
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| language | eng |
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| source | Alma/SFX Local Collection |
| subjects | 单晶衍射 反射光谱 晶胞参数 溶剂热合成 结构 表征 负债 阴离子 |
| title | Solvothermal Synthesis and Characterization of Sheet Structure Containing Adamantane [Hg_2Sn_2S_（10）]~（8-） Anions |
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