Synthesis and Structure of an Organo-templated Oxouranium Phosphite
A novel layered oxouranium phosphite open-structure [（C10H24N2）（H2O）][（UO2）2（HPO3）3]（denoted as TJPU-8,TJPU=Tianjin Polytechnic University） was hydrothermally synthesized with isophorondiamine（IPDA） as the template.Single crystal structure refinement disclosed that TJPU-8 crystallized in the monocli...
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| Veröffentlicht in: | 高等学校化学研究（英文版） 2011-07, Vol.27 (4), p.536-539 |
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| creator | YU Jian-guo ZHAO Yong-nan |
| description | A novel layered oxouranium phosphite open-structure [（C10H24N2）（H2O）][（UO2）2（HPO3）3]（denoted as TJPU-8,TJPU=Tianjin Polytechnic University） was hydrothermally synthesized with isophorondiamine（IPDA） as the template.Single crystal structure refinement disclosed that TJPU-8 crystallized in the monoclinic space group P21c with cell parameters a=1.8346（9） nm,b=0.6734（1） nm,c=2.0639（0） nm,β=114.61（5）°,V=2.3182（8） nm3,Z=2.TJPU-8 was constructed by UO7 monomer,U2O12 dimer and HPO3 groups.The monomeric UO7 or dimeric U2O12 was connected by HPO3 groups to form two types of 4-ring chains.An undulating sheet was then generated by connecting these two types of chains via HPO3 bridges.The layer structure formed by stacking the sheets along the a direction via the strong H-bonds of organoamine cations and water molecules intercalated in the interlayer spaces with the framework oxygen atoms.Although a mixture of cis-and trans-IPDA was used,only cis-IPDA served as the template.A typical green light emission of TJPU-8 is observed when excited by 266 nm laser. |
| format | Article |
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| ispartof | 高等学校化学研究（英文版）, 2011-07, Vol.27 (4), p.536-539 |
| issn | 1005-9040 2210-3171 |
| language | eng |
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| source | Alma/SFX Local Collection |
| subjects | 二聚体 合成 有机模板 氧原子 水分子 磷酸 结构连接 阳离子 |
| title | Synthesis and Structure of an Organo-templated Oxouranium Phosphite |
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