Electrocatalytic Synthesis of Propylene Carbonate from CO2 and Propylene Oxide
O611; The electrocatalytic synthesis ofpropylene carbonate(PC) from CO2 and propylene oxide(PO) was studied under mild conditions(Pco2=1.01×105 Pa, t=25℃). Influences of solvents, supporting electrolytes, the passed charge,the nature of electrodes and the current density(j) on the yield of PC were i...
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| Veröffentlicht in: | 高等学校化学研究（英文版） 2011-03, Vol.27 (2), p.300-303 |
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| container_title | 高等学校化学研究（英文版） |
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| creator | ZHANG Li WANG Huan LI Rui-na CHEN Bao-li LU Jia-xing |
| description | O611; The electrocatalytic synthesis ofpropylene carbonate(PC) from CO2 and propylene oxide(PO) was studied under mild conditions(Pco2=1.01×105 Pa, t=25℃). Influences of solvents, supporting electrolytes, the passed charge,the nature of electrodes and the current density(j) on the yield of PC were investigated to optimize the electrolytic conditions, with the maximal yield to be 46.2%, the selectivity of propylene carbonate is 100%. The reduction of propylene oxide in the absence and presence of CO2 was examined by cyclic voltammetry. The mechanism of the reaction initiated by the synergistic effect of halides ions of supporting electrolytes with nucleophilicity and the metal ions from scarification anode with Lewis acid acidity was proposed on the basis of our results. |
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Influences of solvents, supporting electrolytes, the passed charge,the nature of electrodes and the current density(j) on the yield of PC were investigated to optimize the electrolytic conditions, with the maximal yield to be 46.2%, the selectivity of propylene carbonate is 100%. The reduction of propylene oxide in the absence and presence of CO2 was examined by cyclic voltammetry. The mechanism of the reaction initiated by the synergistic effect of halides ions of supporting electrolytes with nucleophilicity and the metal ions from scarification anode with Lewis acid acidity was proposed on the basis of our results.</description><identifier>ISSN: 1005-9040</identifier><language>eng</language><publisher>Advanced Analysis and Measurement Center, Anhui University of Technology, Ma'anshan 230042, P. R. China%Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry,East China Normal University, Shanghai 200062, P. R. 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Influences of solvents, supporting electrolytes, the passed charge,the nature of electrodes and the current density(j) on the yield of PC were investigated to optimize the electrolytic conditions, with the maximal yield to be 46.2%, the selectivity of propylene carbonate is 100%. The reduction of propylene oxide in the absence and presence of CO2 was examined by cyclic voltammetry. 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Influences of solvents, supporting electrolytes, the passed charge,the nature of electrodes and the current density(j) on the yield of PC were investigated to optimize the electrolytic conditions, with the maximal yield to be 46.2%, the selectivity of propylene carbonate is 100%. The reduction of propylene oxide in the absence and presence of CO2 was examined by cyclic voltammetry. The mechanism of the reaction initiated by the synergistic effect of halides ions of supporting electrolytes with nucleophilicity and the metal ions from scarification anode with Lewis acid acidity was proposed on the basis of our results.</abstract><pub>Advanced Analysis and Measurement Center, Anhui University of Technology, Ma'anshan 230042, P. R. China%Shanghai Key Laboratory of Green Chemistry and Chemical Process, Department of Chemistry,East China Normal University, Shanghai 200062, P. R. China</pub><tpages>4</tpages></addata></record> |
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| title | Electrocatalytic Synthesis of Propylene Carbonate from CO2 and Propylene Oxide |
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