New Chiral Calixarene Derivatives： Syntheses and Their Chiral Recognition Toward Amino Acids by UV-Vis Spectroscopy

Three novel types of chiral calixarene derivatives 5, 8, and 10 were designed and synthesized by introducing chiral units to parent calixarenes. Their chiralities were confirmed by rotational analysis. Chiral recognition properties of these host compounds towards L- and D-threonine were studied by U...

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Veröffentlicht in:	Chemical research in Chinese universities 2008, Vol.24 (1), p.106-109
Hauptverfasser:	GU, Jin-ying, HE, Wan-ping, SHI, Xian-fa, JI, Liang-nian
Format:	Artikel
Sprache:	eng
Schlagworte:	Amino acid Chiral calixarene Chiral recognition Synthesis 光谱学分析方法化合物氨基酸
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creator	GU, Jin-ying HE, Wan-ping SHI, Xian-fa JI, Liang-nian
description	Three novel types of chiral calixarene derivatives 5, 8, and 10 were designed and synthesized by introducing chiral units to parent calixarenes. Their chiralities were confirmed by rotational analysis. Chiral recognition properties of these host compounds towards L- and D-threonine were studied by UV-Vis spectroscopy. The results indicated that calixarene derivatives 5 and 8 exhibited good chiral recognition capabilities toward L- or D-threonine. Although calixarene derivative 10 had no evident chiral recognition ability, the supramolecules of calixarene derivative 10 with L- or D-threonine showed a hypochromic effect or hyperchromic effect respectively. Therefore, calixarene derivative 10 might serve as a good chiral UV-indicator.
doi_str_mv	10.1016/S1005-9040(08)60022-7
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Their chiralities were confirmed by rotational analysis. Chiral recognition properties of these host compounds towards L- and D-threonine were studied by UV-Vis spectroscopy. The results indicated that calixarene derivatives 5 and 8 exhibited good chiral recognition capabilities toward L- or D-threonine. Although calixarene derivative 10 had no evident chiral recognition ability, the supramolecules of calixarene derivative 10 with L- or D-threonine showed a hypochromic effect or hyperchromic effect respectively. 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Their chiralities were confirmed by rotational analysis. Chiral recognition properties of these host compounds towards L- and D-threonine were studied by UV-Vis spectroscopy. The results indicated that calixarene derivatives 5 and 8 exhibited good chiral recognition capabilities toward L- or D-threonine. Although calixarene derivative 10 had no evident chiral recognition ability, the supramolecules of calixarene derivative 10 with L- or D-threonine showed a hypochromic effect or hyperchromic effect respectively. Therefore, calixarene derivative 10 might serve as a good chiral UV-indicator.</description><subject>Amino acid</subject><subject>Chiral calixarene</subject><subject>Chiral recognition</subject><subject>Synthesis</subject><subject>光谱学</subject><subject>分析方法</subject><subject>化合物</subject><subject>氨基酸</subject><issn>1005-9040</issn><issn>2210-3171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2008</creationdate><recordtype>article</recordtype><recordid>eNqFkE1uEzEUxy0EEqFwBCSLFV0MPHtm7JkVilK-pAokknZreew3GYfUDvY0yVyFs3AnroDbFLas3ub_9X6EvGTwhgETb5cMoC5aqOA1NOcCgPNCPiIzzhkUJZPsMZn9kzwlz1LaAJStENWM3H7BA10MLuotXeitO-qIHukFRrfXo9tj-v3rJ11OfhwwYaLaW7oa0MW_pm9owtq70QVPV-Ggo6XzG-cDnRtnE-0menVdXLtElzs0YwzJhN30nDzp9Tbhi4d7Rq4-vF8tPhWXXz9-XswvC1NKGAvJTc-ZNKbVHWt5I4UxHWiOeX1bdx3wtoS6KRtEK_uqaVppZcnrvupEaytRnpHzU-5B-177tdqE2-hzo1rb43E4ThsO0ADLxLK2PmlNHpki9moX3Y2Ok2Kg7jire87qDqKCRt1zVjL73p18mB_ZO4wqGYfeoHUxf6xscP9NePXQPAS__uHyzk6b773bouKiFkxWsvwD-MeRnQ</recordid><startdate>2008</startdate><enddate>2008</enddate><creator>GU, Jin-ying</creator><creator>HE, Wan-ping</creator><creator>SHI, Xian-fa</creator><creator>JI, Liang-nian</creator><general>Elsevier Ltd</general><general>Department of Chemistry, Sun Yat-sen University, Guangzhou 510275, P. R. China</general><general>Department of Chemistry, Tongji University, Shanghai 200092, P. R. China%Department of Chemistry, Tongji University, Shanghai 200092, P. R. 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subjects	Amino acid Chiral calixarene Chiral recognition Synthesis 光谱学分析方法化合物氨基酸
title	New Chiral Calixarene Derivatives： Syntheses and Their Chiral Recognition Toward Amino Acids by UV-Vis Spectroscopy
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