Re-Os Dating of Bitumen from Paleo-Oil Reservoir in the Qinglong Antimony Deposit, Guizhou Province, China and Its Geological Significance
Abundant organic inclusions are present in the Qinglong antimony deposit. However, the source rocks of these organic matters have not been reliably identified. Recently, a paleo--oil reservoir was found in the Qinglong antimony deposit. In view of similar components of gaseous hydrocarbon, we propos...
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description | Abundant organic inclusions are present in the Qinglong antimony deposit. However, the source rocks of these organic matters have not been reliably identified. Recently, a paleo--oil reservoir was found in the Qinglong antimony deposit. In view of similar components of gaseous hydrocarbon, we propose that the organic matters observed in inclusions in Qinglong antimony deposit would come from this paleo-oil reservoir. We used the Re-Os dating method to determine the age of the bitumen from this paleo-oil reservoir, and obtained an isochron age of 254.3~2.8 Ma. The age indicates that the oil- generation from source rock occurred in the early Late Permian, earlier than the Sb mineralization age (-148~8.5 Ma) in the Qinglong antimony deposit area. After oil generation from Devonian source rock, first and secondary migration, the crude oil have probably entered into the fractures and pores of volcanic rocks and limestone and formed a paleo-oil reservoir in the western wing of Dachang anticline. As burial process deepened, the crude oil has turned into natural gas, migrates into the core of Dachang anticline and formed a paleo-gas reservoir. The hydrocarbons (including CH4) in the reservoirs can serve as reducing agent to provide the sulfur required for Sb mineralization through thermal chemical reduction of sulfates. Therefore, the formation of oil-gas in the area is a prerequisite for the Sb mineralization in the Qinglong antimony deposit. |
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However, the source rocks of these organic matters have not been reliably identified. Recently, a paleo--oil reservoir was found in the Qinglong antimony deposit. In view of similar components of gaseous hydrocarbon, we propose that the organic matters observed in inclusions in Qinglong antimony deposit would come from this paleo-oil reservoir. We used the Re-Os dating method to determine the age of the bitumen from this paleo-oil reservoir, and obtained an isochron age of 254.3~2.8 Ma. The age indicates that the oil- generation from source rock occurred in the early Late Permian, earlier than the Sb mineralization age (-148~8.5 Ma) in the Qinglong antimony deposit area. After oil generation from Devonian source rock, first and secondary migration, the crude oil have probably entered into the fractures and pores of volcanic rocks and limestone and formed a paleo-oil reservoir in the western wing of Dachang anticline. As burial process deepened, the crude oil has turned into natural gas, migrates into the core of Dachang anticline and formed a paleo-gas reservoir. The hydrocarbons (including CH4) in the reservoirs can serve as reducing agent to provide the sulfur required for Sb mineralization through thermal chemical reduction of sulfates. Therefore, the formation of oil-gas in the area is a prerequisite for the Sb mineralization in the Qinglong antimony deposit.</description><edition>English ed.</edition><identifier>ISSN: 1000-9515</identifier><identifier>EISSN: 1755-6724</identifier><identifier>DOI: 10.1111/1755-6724.13455</identifier><language>eng</language><publisher>Richmond: Wiley Subscription Services, Inc</publisher><subject>Age ; Anticlines ; Antimony ; bitumen ; Bitumens ; Chemical reduction ; Crude oil ; Dating ; Dating techniques ; Devonian ; Fractures ; Hydrocarbons ; Inclusions ; Limestone ; Migration ; Mineralization ; Natural gas ; Oil reservoirs ; paleo–oil reservoir ; Permian ; relationship between hydrocarbon accumulation and mineralization ; Re–Os isotopic dating ; Sulfur ; Sulphur ; the Qinglong antimony deposit ; Volcanic rocks</subject><ispartof>Acta geologica Sinica (Beijing), 2017-12, Vol.91 (6), p.2153-2163</ispartof><rights>2017 Geological Society of China</rights><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c4455-1f906cc4bafba1bcf4b58db94e30a8d1d9b5e57333843e8aeb2cab844c5070be3</citedby><cites>FETCH-LOGICAL-c4455-1f906cc4bafba1bcf4b58db94e30a8d1d9b5e57333843e8aeb2cab844c5070be3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/86253X/86253X.jpg</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1111%2F1755-6724.13455$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1111%2F1755-6724.13455$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,777,781,1412,27905,27906,45555,45556</link.rule.ids></links><search><creatorcontrib>WANG, Pengpeng</creatorcontrib><creatorcontrib>HU, Yuzhao</creatorcontrib><creatorcontrib>LIU, Lu</creatorcontrib><creatorcontrib>JIANG, Xiaojun</creatorcontrib><creatorcontrib>LI, Chao</creatorcontrib><creatorcontrib>Bartholomew, Chad Joseph</creatorcontrib><creatorcontrib>ZHANG, Guiquan</creatorcontrib><title>Re-Os Dating of Bitumen from Paleo-Oil Reservoir in the Qinglong Antimony Deposit, Guizhou Province, China and Its Geological Significance</title><title>Acta geologica Sinica (Beijing)</title><addtitle>Acta Geologica Sinica</addtitle><description>Abundant organic inclusions are present in the Qinglong antimony deposit. However, the source rocks of these organic matters have not been reliably identified. Recently, a paleo--oil reservoir was found in the Qinglong antimony deposit. In view of similar components of gaseous hydrocarbon, we propose that the organic matters observed in inclusions in Qinglong antimony deposit would come from this paleo-oil reservoir. We used the Re-Os dating method to determine the age of the bitumen from this paleo-oil reservoir, and obtained an isochron age of 254.3~2.8 Ma. The age indicates that the oil- generation from source rock occurred in the early Late Permian, earlier than the Sb mineralization age (-148~8.5 Ma) in the Qinglong antimony deposit area. After oil generation from Devonian source rock, first and secondary migration, the crude oil have probably entered into the fractures and pores of volcanic rocks and limestone and formed a paleo-oil reservoir in the western wing of Dachang anticline. As burial process deepened, the crude oil has turned into natural gas, migrates into the core of Dachang anticline and formed a paleo-gas reservoir. The hydrocarbons (including CH4) in the reservoirs can serve as reducing agent to provide the sulfur required for Sb mineralization through thermal chemical reduction of sulfates. Therefore, the formation of oil-gas in the area is a prerequisite for the Sb mineralization in the Qinglong antimony deposit.</description><subject>Age</subject><subject>Anticlines</subject><subject>Antimony</subject><subject>bitumen</subject><subject>Bitumens</subject><subject>Chemical reduction</subject><subject>Crude oil</subject><subject>Dating</subject><subject>Dating techniques</subject><subject>Devonian</subject><subject>Fractures</subject><subject>Hydrocarbons</subject><subject>Inclusions</subject><subject>Limestone</subject><subject>Migration</subject><subject>Mineralization</subject><subject>Natural gas</subject><subject>Oil reservoirs</subject><subject>paleo–oil reservoir</subject><subject>Permian</subject><subject>relationship between hydrocarbon accumulation and mineralization</subject><subject>Re–Os isotopic dating</subject><subject>Sulfur</subject><subject>Sulphur</subject><subject>the Qinglong antimony deposit</subject><subject>Volcanic rocks</subject><issn>1000-9515</issn><issn>1755-6724</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFkU9PHCEYhyemJlrtuVeih14chQHmz3G71tXEZK22ZwLMyy5mFlaYsa4fwU8t6656LBfekOfH-8KTZd8JPiVpnZGK87ysCnZKKON8J9v_OPmSaoxx3nDC97KvMd5jXPKS8P3s5RbyaUTnsrduhrxBP20_LMAhE_wC3cgOfD61HbqFCOHR24CsQ_0c0O_Edz5lRq63C-9W6ByWPtr-BE0G-zz3A7oJ_tE6DSdoPLdOIuladNVHNAHf-ZnVskN3duasSWXCDrNdI7sI37b7Qfb34tef8WV-PZ1cjUfXuWbpXTkxDS61ZkoaJYnShilet6phQLGsW9I2igOvKKU1o1BLUIWWqmZMc1xhBfQg-7G59590RrqZuPdDcKmjaJ-flIACkwqXmNBEHm_IZfAPA8T-EyVNTTAlhJNEnW0oHXyMAYxYBruQYSUIFms1Yi1CrEWINzUpUW4nsB2s_oeL0Xhy9x482raap69_SAo-wmXF0sh1UdBXClicMg</recordid><startdate>201712</startdate><enddate>201712</enddate><creator>WANG, Pengpeng</creator><creator>HU, Yuzhao</creator><creator>LIU, Lu</creator><creator>JIANG, Xiaojun</creator><creator>LI, Chao</creator><creator>Bartholomew, Chad Joseph</creator><creator>ZHANG, Guiquan</creator><general>Wiley Subscription Services, Inc</general><general>Faculty of Land and Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China</general><general>Yunnan Tin Vocation Technical College, Gejiu 661000, Yunnan, China%Faculty of Land and Resource Engineering, Kunming University of Science and Technology, Kunming 650093, Yunnan, China%National Research Center for Geoanalysis, Beijing 10003 7, China%Institute of Sinopec Exploration Southern Company, Chengdu 610041, Sichuan, China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>W94</scope><scope>~WA</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7UA</scope><scope>8FD</scope><scope>C1K</scope><scope>F1W</scope><scope>FR3</scope><scope>H96</scope><scope>KR7</scope><scope>L.G</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>201712</creationdate><title>Re-Os Dating of Bitumen from Paleo-Oil Reservoir in the Qinglong Antimony Deposit, Guizhou Province, China and Its Geological Significance</title><author>WANG, Pengpeng ; HU, Yuzhao ; LIU, Lu ; JIANG, Xiaojun ; LI, Chao ; Bartholomew, Chad Joseph ; ZHANG, Guiquan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c4455-1f906cc4bafba1bcf4b58db94e30a8d1d9b5e57333843e8aeb2cab844c5070be3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Age</topic><topic>Anticlines</topic><topic>Antimony</topic><topic>bitumen</topic><topic>Bitumens</topic><topic>Chemical reduction</topic><topic>Crude oil</topic><topic>Dating</topic><topic>Dating techniques</topic><topic>Devonian</topic><topic>Fractures</topic><topic>Hydrocarbons</topic><topic>Inclusions</topic><topic>Limestone</topic><topic>Migration</topic><topic>Mineralization</topic><topic>Natural gas</topic><topic>Oil reservoirs</topic><topic>paleo–oil reservoir</topic><topic>Permian</topic><topic>relationship between hydrocarbon accumulation and mineralization</topic><topic>Re–Os isotopic dating</topic><topic>Sulfur</topic><topic>Sulphur</topic><topic>the Qinglong antimony deposit</topic><topic>Volcanic rocks</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>WANG, Pengpeng</creatorcontrib><creatorcontrib>HU, Yuzhao</creatorcontrib><creatorcontrib>LIU, Lu</creatorcontrib><creatorcontrib>JIANG, Xiaojun</creatorcontrib><creatorcontrib>LI, Chao</creatorcontrib><creatorcontrib>Bartholomew, Chad Joseph</creatorcontrib><creatorcontrib>ZHANG, Guiquan</creatorcontrib><collection>中文科技期刊数据库</collection><collection>中文科技期刊数据库-CALIS站点</collection><collection>中文科技期刊数据库-7.0平台</collection><collection>中文科技期刊数据库-自然科学</collection><collection>中文科技期刊数据库- 镜像站点</collection><collection>CrossRef</collection><collection>Water Resources Abstracts</collection><collection>Technology Research Database</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ASFA: Aquatic Sciences and Fisheries Abstracts</collection><collection>Engineering Research Database</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) 2: Ocean Technology, Policy & Non-Living Resources</collection><collection>Civil Engineering Abstracts</collection><collection>Aquatic Science & Fisheries Abstracts (ASFA) Professional</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Acta geologica Sinica (Beijing)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>WANG, Pengpeng</au><au>HU, Yuzhao</au><au>LIU, Lu</au><au>JIANG, Xiaojun</au><au>LI, Chao</au><au>Bartholomew, Chad Joseph</au><au>ZHANG, Guiquan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Re-Os Dating of Bitumen from Paleo-Oil Reservoir in the Qinglong Antimony Deposit, Guizhou Province, China and Its Geological Significance</atitle><jtitle>Acta geologica Sinica (Beijing)</jtitle><addtitle>Acta Geologica Sinica</addtitle><date>2017-12</date><risdate>2017</risdate><volume>91</volume><issue>6</issue><spage>2153</spage><epage>2163</epage><pages>2153-2163</pages><issn>1000-9515</issn><eissn>1755-6724</eissn><abstract>Abundant organic inclusions are present in the Qinglong antimony deposit. However, the source rocks of these organic matters have not been reliably identified. Recently, a paleo--oil reservoir was found in the Qinglong antimony deposit. In view of similar components of gaseous hydrocarbon, we propose that the organic matters observed in inclusions in Qinglong antimony deposit would come from this paleo-oil reservoir. We used the Re-Os dating method to determine the age of the bitumen from this paleo-oil reservoir, and obtained an isochron age of 254.3~2.8 Ma. The age indicates that the oil- generation from source rock occurred in the early Late Permian, earlier than the Sb mineralization age (-148~8.5 Ma) in the Qinglong antimony deposit area. After oil generation from Devonian source rock, first and secondary migration, the crude oil have probably entered into the fractures and pores of volcanic rocks and limestone and formed a paleo-oil reservoir in the western wing of Dachang anticline. As burial process deepened, the crude oil has turned into natural gas, migrates into the core of Dachang anticline and formed a paleo-gas reservoir. The hydrocarbons (including CH4) in the reservoirs can serve as reducing agent to provide the sulfur required for Sb mineralization through thermal chemical reduction of sulfates. Therefore, the formation of oil-gas in the area is a prerequisite for the Sb mineralization in the Qinglong antimony deposit.</abstract><cop>Richmond</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1111/1755-6724.13455</doi><tpages>11</tpages><edition>English ed.</edition></addata></record> |
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subjects | Age Anticlines Antimony bitumen Bitumens Chemical reduction Crude oil Dating Dating techniques Devonian Fractures Hydrocarbons Inclusions Limestone Migration Mineralization Natural gas Oil reservoirs paleo–oil reservoir Permian relationship between hydrocarbon accumulation and mineralization Re–Os isotopic dating Sulfur Sulphur the Qinglong antimony deposit Volcanic rocks |
title | Re-Os Dating of Bitumen from Paleo-Oil Reservoir in the Qinglong Antimony Deposit, Guizhou Province, China and Its Geological Significance |
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