Imidazolium-based ionic liquids as an anticorrosive agent for completion fluid design
Most of the onshore and offshore oil and gas reservoirs are facing operational challenges due to high temperature and high salinity, thus requiring advanced techniques for realizing the expected oil recovery with the use of specially designed chemicals. During oil and gas well development, completio...
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| Veröffentlicht in: | Journal of earth science (Wuhan, China) China), 2017-10, Vol.28 (5), p.949-961 |
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| creator | Velusamy, Sugirtha Sakthivel, Sivabalan Neelakantan, Lakshman Sangwai, Jitendra S. |
| description | Most of the onshore and offshore oil and gas reservoirs are facing operational challenges due to high temperature and high salinity, thus requiring advanced techniques for realizing the expected oil recovery with the use of specially designed chemicals. During oil and gas well development, completion fluids, which are solids-free liquids, are used to complete an oil or gas well. Completion fluids consisting of brines are primarily used for oil and gas well stabilization and are corrosive in nature. There is a need to develop additives to be added with completion fluids to address the corrosive nature. The present investigation involved the usage of two imidazolium ionic liquids (ILs) as corrosion inhibitors for mild steel in various completion brine (CaCl
2
, HCOOCs and ZnBr
2
) fluids. The study was performed using various techniques, such as, potentiodynamic polarization, weight loss measurements and exposure studies. All the above techniques showed promising results which indicated that the ILs as corrosion inhibitors used were of the mixed-type following both physisorption and chemisorption over the mild steel surface. Among the two inhibitors studied here, 1-octyl-3-methyl imidazolium chloride ([OMIM]
+
[Cl]
-
) with longer alkyl chain exhibited better inhibition efficiency and much lesser corrosion rate than 1-butyl-3-methyl imidazolium chloride ([BMIM]
+
[Cl]
-
) with a shorter alkyl chain. The results obtained from various methodologies indicate that ionic liquids can be explored to develop anti-corrosive completion fluids suitable for oil and gas reservoirs. |
| doi_str_mv | 10.1007/s12583-017-0780-2 |
| format | Article |
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2
, HCOOCs and ZnBr
2
) fluids. The study was performed using various techniques, such as, potentiodynamic polarization, weight loss measurements and exposure studies. All the above techniques showed promising results which indicated that the ILs as corrosion inhibitors used were of the mixed-type following both physisorption and chemisorption over the mild steel surface. Among the two inhibitors studied here, 1-octyl-3-methyl imidazolium chloride ([OMIM]
+
[Cl]
-
) with longer alkyl chain exhibited better inhibition efficiency and much lesser corrosion rate than 1-butyl-3-methyl imidazolium chloride ([BMIM]
+
[Cl]
-
) with a shorter alkyl chain. The results obtained from various methodologies indicate that ionic liquids can be explored to develop anti-corrosive completion fluids suitable for oil and gas reservoirs.</description><identifier>ISSN: 1674-487X</identifier><identifier>EISSN: 1867-111X</identifier><identifier>DOI: 10.1007/s12583-017-0780-2</identifier><language>eng</language><publisher>Wuhan: China University of Geosciences</publisher><subject>Additives ; Biogeosciences ; Brines ; Calcium chloride ; Chains ; Chemisorption ; Chlorides ; Corrosion ; Corrosion inhibitors ; Corrosion prevention ; Corrosion rate ; Earth and Environmental Science ; Earth Sciences ; Fluids ; Gas wells ; Geochemistry ; Geology ; Geotechnical Engineering & Applied Earth Sciences ; High temperature ; Inhibitors ; Ionic liquids ; Ions ; Liquids ; Low carbon steels ; Natural gas ; Offshore ; Offshore drilling rigs ; Offshore engineering ; Oil ; Oil recovery ; Oil reservoirs ; Petroleum ; Reservoirs ; Saline water ; Solvents ; Steel ; Temperature requirements ; Weight loss measurement ; Well development</subject><ispartof>Journal of earth science (Wuhan, China), 2017-10, Vol.28 (5), p.949-961</ispartof><rights>China University of Geosciences and Springer-Verlag GmbH Germany 2017</rights><rights>Journal of Earth Science is a copyright of Springer, 2017.</rights><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c348t-7cf9a123f858f60267eeccc657316a2e7e529e83fd2b0a9c88851d4c2d524f013</citedby><cites>FETCH-LOGICAL-c348t-7cf9a123f858f60267eeccc657316a2e7e529e83fd2b0a9c88851d4c2d524f013</cites><orcidid>0000-0003-1862-5722</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://www.wanfangdata.com.cn/images/PeriodicalImages/dqkx-e/dqkx-e.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12583-017-0780-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12583-017-0780-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Velusamy, Sugirtha</creatorcontrib><creatorcontrib>Sakthivel, Sivabalan</creatorcontrib><creatorcontrib>Neelakantan, Lakshman</creatorcontrib><creatorcontrib>Sangwai, Jitendra S.</creatorcontrib><title>Imidazolium-based ionic liquids as an anticorrosive agent for completion fluid design</title><title>Journal of earth science (Wuhan, China)</title><addtitle>J. Earth Sci</addtitle><description>Most of the onshore and offshore oil and gas reservoirs are facing operational challenges due to high temperature and high salinity, thus requiring advanced techniques for realizing the expected oil recovery with the use of specially designed chemicals. During oil and gas well development, completion fluids, which are solids-free liquids, are used to complete an oil or gas well. Completion fluids consisting of brines are primarily used for oil and gas well stabilization and are corrosive in nature. There is a need to develop additives to be added with completion fluids to address the corrosive nature. The present investigation involved the usage of two imidazolium ionic liquids (ILs) as corrosion inhibitors for mild steel in various completion brine (CaCl
2
, HCOOCs and ZnBr
2
) fluids. The study was performed using various techniques, such as, potentiodynamic polarization, weight loss measurements and exposure studies. All the above techniques showed promising results which indicated that the ILs as corrosion inhibitors used were of the mixed-type following both physisorption and chemisorption over the mild steel surface. Among the two inhibitors studied here, 1-octyl-3-methyl imidazolium chloride ([OMIM]
+
[Cl]
-
) with longer alkyl chain exhibited better inhibition efficiency and much lesser corrosion rate than 1-butyl-3-methyl imidazolium chloride ([BMIM]
+
[Cl]
-
) with a shorter alkyl chain. The results obtained from various methodologies indicate that ionic liquids can be explored to develop anti-corrosive completion fluids suitable for oil and gas reservoirs.</description><subject>Additives</subject><subject>Biogeosciences</subject><subject>Brines</subject><subject>Calcium chloride</subject><subject>Chains</subject><subject>Chemisorption</subject><subject>Chlorides</subject><subject>Corrosion</subject><subject>Corrosion inhibitors</subject><subject>Corrosion prevention</subject><subject>Corrosion rate</subject><subject>Earth and Environmental Science</subject><subject>Earth Sciences</subject><subject>Fluids</subject><subject>Gas wells</subject><subject>Geochemistry</subject><subject>Geology</subject><subject>Geotechnical Engineering & Applied Earth Sciences</subject><subject>High temperature</subject><subject>Inhibitors</subject><subject>Ionic liquids</subject><subject>Ions</subject><subject>Liquids</subject><subject>Low carbon steels</subject><subject>Natural gas</subject><subject>Offshore</subject><subject>Offshore drilling rigs</subject><subject>Offshore engineering</subject><subject>Oil</subject><subject>Oil recovery</subject><subject>Oil reservoirs</subject><subject>Petroleum</subject><subject>Reservoirs</subject><subject>Saline water</subject><subject>Solvents</subject><subject>Steel</subject><subject>Temperature requirements</subject><subject>Weight loss measurement</subject><subject>Well 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Sivabalan</au><au>Neelakantan, Lakshman</au><au>Sangwai, Jitendra S.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Imidazolium-based ionic liquids as an anticorrosive agent for completion fluid design</atitle><jtitle>Journal of earth science (Wuhan, China)</jtitle><stitle>J. Earth Sci</stitle><date>2017-10-01</date><risdate>2017</risdate><volume>28</volume><issue>5</issue><spage>949</spage><epage>961</epage><pages>949-961</pages><issn>1674-487X</issn><eissn>1867-111X</eissn><abstract>Most of the onshore and offshore oil and gas reservoirs are facing operational challenges due to high temperature and high salinity, thus requiring advanced techniques for realizing the expected oil recovery with the use of specially designed chemicals. During oil and gas well development, completion fluids, which are solids-free liquids, are used to complete an oil or gas well. Completion fluids consisting of brines are primarily used for oil and gas well stabilization and are corrosive in nature. There is a need to develop additives to be added with completion fluids to address the corrosive nature. The present investigation involved the usage of two imidazolium ionic liquids (ILs) as corrosion inhibitors for mild steel in various completion brine (CaCl
2
, HCOOCs and ZnBr
2
) fluids. The study was performed using various techniques, such as, potentiodynamic polarization, weight loss measurements and exposure studies. All the above techniques showed promising results which indicated that the ILs as corrosion inhibitors used were of the mixed-type following both physisorption and chemisorption over the mild steel surface. Among the two inhibitors studied here, 1-octyl-3-methyl imidazolium chloride ([OMIM]
+
[Cl]
-
) with longer alkyl chain exhibited better inhibition efficiency and much lesser corrosion rate than 1-butyl-3-methyl imidazolium chloride ([BMIM]
+
[Cl]
-
) with a shorter alkyl chain. The results obtained from various methodologies indicate that ionic liquids can be explored to develop anti-corrosive completion fluids suitable for oil and gas reservoirs.</abstract><cop>Wuhan</cop><pub>China University of Geosciences</pub><doi>10.1007/s12583-017-0780-2</doi><tpages>13</tpages><orcidid>https://orcid.org/0000-0003-1862-5722</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1674-487X |
| ispartof | Journal of earth science (Wuhan, China), 2017-10, Vol.28 (5), p.949-961 |
| issn | 1674-487X 1867-111X |
| language | eng |
| recordid | cdi_wanfang_journals_dqkx_e201705016 |
| source | Springer Nature - Complete Springer Journals; Alma/SFX Local Collection |
| subjects | Additives Biogeosciences Brines Calcium chloride Chains Chemisorption Chlorides Corrosion Corrosion inhibitors Corrosion prevention Corrosion rate Earth and Environmental Science Earth Sciences Fluids Gas wells Geochemistry Geology Geotechnical Engineering & Applied Earth Sciences High temperature Inhibitors Ionic liquids Ions Liquids Low carbon steels Natural gas Offshore Offshore drilling rigs Offshore engineering Oil Oil recovery Oil reservoirs Petroleum Reservoirs Saline water Solvents Steel Temperature requirements Weight loss measurement Well development |
| title | Imidazolium-based ionic liquids as an anticorrosive agent for completion fluid design |
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