氟催化废弃硅基还原剂与CO2还原转化反应
CO2是最重要的可再生碳源之一.为了将CO2转化为有用的有机化合物,我们研究了二种模型硅基"废"材料—乙硅烷和硅粉的反应活性.在这些反应中,氟盐的催化活性最高,在常压、在质子源水和硅基还原剂的存在下,CO2可转化为甲酸.原位NMR和动力学分析表明,含氢硅烷和五配位的硅物种分别是反应中间物和活性物种....
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| Veröffentlicht in: | 催化学报 2017, Vol.38 (3), p.434-439 |
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| container_title | 催化学报 |
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| creator | Ken Motokura Masaki Naijo Sho Yamaguchi Akimitsu Miyaji Toshihide Baba |
| description | CO2是最重要的可再生碳源之一.为了将CO2转化为有用的有机化合物,我们研究了二种模型硅基"废"材料—乙硅烷和硅粉的反应活性.在这些反应中,氟盐的催化活性最高,在常压、在质子源水和硅基还原剂的存在下,CO2可转化为甲酸.原位NMR和动力学分析表明,含氢硅烷和五配位的硅物种分别是反应中间物和活性物种. |
| doi_str_mv | 10.1016/S1872-2067(17)62800-6 |
| format | Article |
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| ispartof | 催化学报, 2017, Vol.38 (3), p.434-439 |
| issn | 0253-9837 |
| language | chi |
| recordid | cdi_wanfang_journals_cuihuaxb201703003 |
| source | Elsevier ScienceDirect Journals Complete |
| title | 氟催化废弃硅基还原剂与CO2还原转化反应 |
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