Dimerization of norbornene on zeolite catalysts

Dimerization of norbornene on zeolite catalysts

The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established.The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium,with a selectivity of dimer formation of 88%-98%.Four stereo‐isomers of the bis‐2,2＇‐norbornylidene...

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Veröffentlicht in:Chinese journal of catalysis 2015-03, Vol.36 (3), p.268-273
Hauptverfasser: Grigor'eva, N.G., Bubennov, S.V., Khalilov, L.M., Kutepov, B.I.
Format: Artikel
Sprache:eng
Schlagworte:
Argon
Beta版
Bisnorbornylidenes
Catalysis
Chlorination
Conversion
Dimerization
Dimers
Norbornene
Selectivity
Zeolites
ZSM
二聚体
氯化石蜡
沸石催化剂
转化率
降冰片烯
高活性
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container_end_page 273
container_issue 3
container_start_page 268
container_title Chinese journal of catalysis
container_volume 36
creator Grigor'eva, N.G.
Bubennov, S.V.
Khalilov, L.M.
Kutepov, B.I.
description The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established.The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium,with a selectivity of dimer formation of 88%-98%.Four stereo‐isomers of the bis‐2,2＇‐norbornylidene structure were identified in the dimer fraction,with the（Z）‐anti‐bis‐2,2＇‐norbornylidene prevailing over the others.
doi_str_mv 10.1016/S1872-2067(14)60251-5
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1872-2067
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source ScienceDirect Journals (5 years ago - present)
subjects Argon
Beta版
Bisnorbornylidenes
Catalysis
Chlorination
Conversion
Dimerization
Dimers
Norbornene
Selectivity
Zeolites
ZSM
二聚体
氯化石蜡
沸石催化剂
转化率
降冰片烯
高活性
title Dimerization of norbornene on zeolite catalysts
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