Dimerization of norbornene on zeolite catalysts

The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established.The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium,with a selectivity of dimer formation of 88%-98%.Four stereo‐isomers of the bis‐2,2'‐norbornylidene...

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Veröffentlicht in:Chinese journal of catalysis 2015-03, Vol.36 (3), p.268-273
Hauptverfasser: Grigor'eva, N.G., Bubennov, S.V., Khalilov, L.M., Kutepov, B.I.
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Sprache:eng
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Zusammenfassung:The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established.The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium,with a selectivity of dimer formation of 88%-98%.Four stereo‐isomers of the bis‐2,2'‐norbornylidene structure were identified in the dimer fraction,with the(Z)‐anti‐bis‐2,2'‐norbornylidene prevailing over the others.
ISSN:0253-9837
1872-2067
1872-2067
DOI:10.1016/S1872-2067(14)60251-5