Dimerization of norbornene on zeolite catalysts
The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established.The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium,with a selectivity of dimer formation of 88%-98%.Four stereo‐isomers of the bis‐2,2'‐norbornylidene...
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Veröffentlicht in: | Chinese journal of catalysis 2015-03, Vol.36 (3), p.268-273 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The high activity and selectivity of H‐Beta and H‐ZSM‐12 zeolites in the dimerization of norbornene was established.The norbornene conversion reached 100% in chlorinated paraffin and argon gas medium,with a selectivity of dimer formation of 88%-98%.Four stereo‐isomers of the bis‐2,2'‐norbornylidene structure were identified in the dimer fraction,with the(Z)‐anti‐bis‐2,2'‐norbornylidene prevailing over the others. |
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ISSN: | 0253-9837 1872-2067 1872-2067 |
DOI: | 10.1016/S1872-2067(14)60251-5 |