Influencing factors and mechanism of iodine-induced stress corrosion cracking of zirconium alloy cladding: A review

Failure of the zirconium alloy claddings due to iodine-induced stress corrosion cracking (I-SCC) will increase the risk of fission product leakage. The progress of I-SCC has been comprehensively investigated in a massive amount of published literature. For a comprehensive understanding of I-SCC, thi...

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Veröffentlicht in:International journal of minerals, metallurgy and materials metallurgy and materials, 2022-04, Vol.29 (4), p.586-598
Hauptverfasser: Li, Yusha, Ge, Changchun, Liu, Yanhong, Li, Guangbin, Dong, Xiaoxu, Gu, Zongxing, Zhang, Yingchun
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container_title International journal of minerals, metallurgy and materials
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Ge, Changchun
Liu, Yanhong
Li, Guangbin
Dong, Xiaoxu
Gu, Zongxing
Zhang, Yingchun
description Failure of the zirconium alloy claddings due to iodine-induced stress corrosion cracking (I-SCC) will increase the risk of fission product leakage. The progress of I-SCC has been comprehensively investigated in a massive amount of published literature. For a comprehensive understanding of I-SCC, this review focuses on summarizing the mechanisms and influencing factors of I-SCC. Results show that micropits are formed on the surface of zirconium alloys due to the reaction between iodine and zirconium, and then small pits gradually gather to form pit clusters. Cracks are easily generated in pit clusters and propagate along the grain boundary. After reaching a particular condition, the crack will transform into transgranular direction propagation. As the crack develops, it finally becomes a ductile fracture. We also summarize various factors that may affect I-SCC. The specific cracking conditions are linked to elements, such as iodine concentration, temperature, microstructure, and alloying elements. Nonetheless, the improvement of the I-SCC resistance of zirconium alloys needs to be further explored. More attention can be paid to material properties, such as alloying elements, microstructure, and surface treatment, to improve the I-SCC resistance of zirconium alloys.
doi_str_mv 10.1007/s12613-022-2431-6
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The progress of I-SCC has been comprehensively investigated in a massive amount of published literature. For a comprehensive understanding of I-SCC, this review focuses on summarizing the mechanisms and influencing factors of I-SCC. Results show that micropits are formed on the surface of zirconium alloys due to the reaction between iodine and zirconium, and then small pits gradually gather to form pit clusters. Cracks are easily generated in pit clusters and propagate along the grain boundary. After reaching a particular condition, the crack will transform into transgranular direction propagation. As the crack develops, it finally becomes a ductile fracture. We also summarize various factors that may affect I-SCC. The specific cracking conditions are linked to elements, such as iodine concentration, temperature, microstructure, and alloying elements. Nonetheless, the improvement of the I-SCC resistance of zirconium alloys needs to be further explored. 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More attention can be paid to material properties, such as alloying elements, microstructure, and surface treatment, to improve the I-SCC resistance of zirconium alloys.</abstract><cop>Beijing</cop><pub>University of Science and Technology Beijing</pub><doi>10.1007/s12613-022-2431-6</doi><tpages>13</tpages></addata></record>
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subjects Alloying elements
Alloys
Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Claddings
Clusters
Composites
Corrosion
Corrosion and Coatings
Corrosion mechanisms
Corrosion products
Ductile fracture
Fission products
Glass
Grain boundaries
Invited Review
Iodine
Material properties
Materials Science
Metallic Materials
Microstructure
Natural Materials
Stress corrosion
Stress corrosion cracking
Surface treatment
Surfaces and Interfaces
Thin Films
Tribology
Zirconium
Zirconium alloys
Zirconium base alloys
title Influencing factors and mechanism of iodine-induced stress corrosion cracking of zirconium alloy cladding: A review
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