Sintering of monoclinic SrAl2Si2O8 ceramics and their Sr immobilization

Monoclinic SrAl 2 Si 2 O 8 ceramics for Sr immobilization were prepared by a liquid-phase sintering method. The sintering temperature, mineral phase composition, microstructure, flexural strength, bulk density, and Sr ion leaching characteristics of the SrAl 2 Si 2 O 8 ceramics were investigated. A...

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Veröffentlicht in:International journal of minerals, metallurgy and materials metallurgy and materials, 2021-06, Vol.28 (6), p.1057-1062
Hauptverfasser: Luo, Jie, Li, Xin, Zhang, Fu-jie, Chen, Song, Ren, Ding
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creator Luo, Jie
Li, Xin
Zhang, Fu-jie
Chen, Song
Ren, Ding
description Monoclinic SrAl 2 Si 2 O 8 ceramics for Sr immobilization were prepared by a liquid-phase sintering method. The sintering temperature, mineral phase composition, microstructure, flexural strength, bulk density, and Sr ion leaching characteristics of the SrAl 2 Si 2 O 8 ceramics were investigated. A crystalline monoclinic SrAl 2 Si 2 O 8 phase formed through liquid-phase sintering at 1223 K. The introduction of four flux agents (B 2 O 3 , CaO·2B 2 O 3 , SrO·2B 2 O 3 , and BaO·2B 2 O 3 ) to the SrAl 2 Si 2 O 8 ceramics not only reduced the densification temperature and decreased the volatilization of Sr during high-temperature sintering but also impacted the mechanical properties of the ceramics. Product consistency tests showed that the leaching concentration of Sr ions in the sample with flux agent B 2 O 3 was the lowest, whereas that of Sr ions in the sample with flux agent BaO·2B 2 O 3 was the highest. These results show that the leaching concentration of Sr ions depends largely on the amorphous phase in the ceramics. Meanwhile, the formation of mineral analog ceramics containing Sr is an important factor to improve Sr immobilization.
doi_str_mv 10.1007/s12613-020-2056-6
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The sintering temperature, mineral phase composition, microstructure, flexural strength, bulk density, and Sr ion leaching characteristics of the SrAl 2 Si 2 O 8 ceramics were investigated. A crystalline monoclinic SrAl 2 Si 2 O 8 phase formed through liquid-phase sintering at 1223 K. The introduction of four flux agents (B 2 O 3 , CaO·2B 2 O 3 , SrO·2B 2 O 3 , and BaO·2B 2 O 3 ) to the SrAl 2 Si 2 O 8 ceramics not only reduced the densification temperature and decreased the volatilization of Sr during high-temperature sintering but also impacted the mechanical properties of the ceramics. Product consistency tests showed that the leaching concentration of Sr ions in the sample with flux agent B 2 O 3 was the lowest, whereas that of Sr ions in the sample with flux agent BaO·2B 2 O 3 was the highest. These results show that the leaching concentration of Sr ions depends largely on the amorphous phase in the ceramics. Meanwhile, the formation of mineral analog ceramics containing Sr is an important factor to improve Sr immobilization.</description><identifier>ISSN: 1674-4799</identifier><identifier>EISSN: 1869-103X</identifier><identifier>DOI: 10.1007/s12613-020-2056-6</identifier><language>eng</language><publisher>Beijing: University of Science and Technology Beijing</publisher><subject>Barium oxides ; Boron oxides ; Bulk density ; Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composites ; Consistency tests ; Corrosion and Coatings ; Densification ; Flexural strength ; Fluctuations ; Glass ; High temperature ; Immobilization ; Ions ; Leaching ; Liquid phase sintering ; Liquid phases ; Materials Science ; Mechanical properties ; Metallic Materials ; Monoclinic lattice ; Natural Materials ; Phase composition ; Sintering ; Surfaces and Interfaces ; Thin Films ; Tribology</subject><ispartof>International journal of minerals, metallurgy and materials, 2021-06, Vol.28 (6), p.1057-1062</ispartof><rights>University of Science and Technology Beijing 2021</rights><rights>University of Science and Technology Beijing 2021.</rights><rights>Copyright © Wanfang Data Co. 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The sintering temperature, mineral phase composition, microstructure, flexural strength, bulk density, and Sr ion leaching characteristics of the SrAl 2 Si 2 O 8 ceramics were investigated. A crystalline monoclinic SrAl 2 Si 2 O 8 phase formed through liquid-phase sintering at 1223 K. The introduction of four flux agents (B 2 O 3 , CaO·2B 2 O 3 , SrO·2B 2 O 3 , and BaO·2B 2 O 3 ) to the SrAl 2 Si 2 O 8 ceramics not only reduced the densification temperature and decreased the volatilization of Sr during high-temperature sintering but also impacted the mechanical properties of the ceramics. Product consistency tests showed that the leaching concentration of Sr ions in the sample with flux agent B 2 O 3 was the lowest, whereas that of Sr ions in the sample with flux agent BaO·2B 2 O 3 was the highest. These results show that the leaching concentration of Sr ions depends largely on the amorphous phase in the ceramics. 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The sintering temperature, mineral phase composition, microstructure, flexural strength, bulk density, and Sr ion leaching characteristics of the SrAl 2 Si 2 O 8 ceramics were investigated. A crystalline monoclinic SrAl 2 Si 2 O 8 phase formed through liquid-phase sintering at 1223 K. The introduction of four flux agents (B 2 O 3 , CaO·2B 2 O 3 , SrO·2B 2 O 3 , and BaO·2B 2 O 3 ) to the SrAl 2 Si 2 O 8 ceramics not only reduced the densification temperature and decreased the volatilization of Sr during high-temperature sintering but also impacted the mechanical properties of the ceramics. Product consistency tests showed that the leaching concentration of Sr ions in the sample with flux agent B 2 O 3 was the lowest, whereas that of Sr ions in the sample with flux agent BaO·2B 2 O 3 was the highest. These results show that the leaching concentration of Sr ions depends largely on the amorphous phase in the ceramics. Meanwhile, the formation of mineral analog ceramics containing Sr is an important factor to improve Sr immobilization.</abstract><cop>Beijing</cop><pub>University of Science and Technology Beijing</pub><doi>10.1007/s12613-020-2056-6</doi><tpages>6</tpages></addata></record>
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subjects Barium oxides
Boron oxides
Bulk density
Ceramics
Characterization and Evaluation of Materials
Chemistry and Materials Science
Composites
Consistency tests
Corrosion and Coatings
Densification
Flexural strength
Fluctuations
Glass
High temperature
Immobilization
Ions
Leaching
Liquid phase sintering
Liquid phases
Materials Science
Mechanical properties
Metallic Materials
Monoclinic lattice
Natural Materials
Phase composition
Sintering
Surfaces and Interfaces
Thin Films
Tribology
title Sintering of monoclinic SrAl2Si2O8 ceramics and their Sr immobilization
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