Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant
The hydrometallurgical strategy of extracting Mn from low-grade Mn ores has attracted attention for the production of electrolytic manganese metal (EMM). In this work, the reductive dissolution of low-grade MnO 2 ores using toxic nitrocellulose acidic wastewater (NAW) as a reductant was investigated...
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| Veröffentlicht in: | International journal of minerals, metallurgy and materials metallurgy and materials, 2018-09, Vol.25 (9), p.990-999 |
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| container_title | International journal of minerals, metallurgy and materials |
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| creator | Zhang, Yong-tao Dan, Zhi-gang Duan, Ning Xin, Bao-ping |
| description | The hydrometallurgical strategy of extracting Mn from low-grade Mn ores has attracted attention for the production of electrolytic manganese metal (EMM). In this work, the reductive dissolution of low-grade MnO
2
ores using toxic nitrocellulose acidic wastewater (NAW) as a reductant was investigated for the first time. Under the optimized conditions of an MnO
2
ore dosage of 100 g·L
−1
, an ore particle size of −200 mesh, concentrated H
2
SO
4
-to-NAW volume ratio of 0.12, reaction temperature of 90°C, stirring speed at 160 r·min
−1
, and a contact time of 120 min, the reductive leaching efficiency of Mn and the total organic carbon (TOC) removal efficiency of NAW reached 97.4% and 98.5%, respectively. The residual TOC of 31.6 mg·L
−1
did not adversely affect the preparation of EMM. The current process offers a feasible route for the concurrent realization of the reductive leaching of Mn and the treatment of toxic wastewater via a simple one-step process. |
| doi_str_mv | 10.1007/s12613-018-1649-9 |
| format | Article |
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2
ores using toxic nitrocellulose acidic wastewater (NAW) as a reductant was investigated for the first time. Under the optimized conditions of an MnO
2
ore dosage of 100 g·L
−1
, an ore particle size of −200 mesh, concentrated H
2
SO
4
-to-NAW volume ratio of 0.12, reaction temperature of 90°C, stirring speed at 160 r·min
−1
, and a contact time of 120 min, the reductive leaching efficiency of Mn and the total organic carbon (TOC) removal efficiency of NAW reached 97.4% and 98.5%, respectively. The residual TOC of 31.6 mg·L
−1
did not adversely affect the preparation of EMM. The current process offers a feasible route for the concurrent realization of the reductive leaching of Mn and the treatment of toxic wastewater via a simple one-step process.</description><identifier>ISSN: 1674-4799</identifier><identifier>EISSN: 1869-103X</identifier><identifier>DOI: 10.1007/s12613-018-1649-9</identifier><language>eng</language><publisher>Beijing: University of Science and Technology Beijing</publisher><subject>Cellulose ; Cellulose esters ; Cellulose nitrate ; Ceramics ; Characterization and Evaluation of Materials ; Chemical oxygen demand ; Chemistry and Materials Science ; Composites ; Corrosion and Coatings ; Efficiency ; Explosives ; Glass ; Leaching ; Manganese ; Manganese dioxide ; Manganese ores ; Manufacturing ; Materials Science ; Metallic Materials ; Natural Materials ; Organic carbon ; Particle size ; Reducing agents ; Sulfuric acid ; Surfaces and Interfaces ; Syrups & sweeteners ; Thin Films ; Toxicity ; Tribology ; Wastewater treatment</subject><ispartof>International journal of minerals, metallurgy and materials, 2018-09, Vol.25 (9), p.990-999</ispartof><rights>University of Science and Technology Beijing and Springer-Verlag GmbH Germany, part of Springer Nature 2018</rights><rights>University of Science and Technology Beijing and Springer-Verlag GmbH Germany, part of Springer Nature 2018.</rights><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c352t-6354c3345fd2597e4460bcb0c6d9ab06c6188753c7a861ec5798e8365aae7c03</citedby><cites>FETCH-LOGICAL-c352t-6354c3345fd2597e4460bcb0c6d9ab06c6188753c7a861ec5798e8365aae7c03</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://www.wanfangdata.com.cn/images/PeriodicalImages/bjkjdxxb-e/bjkjdxxb-e.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12613-018-1649-9$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2919655117?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,780,784,21388,27924,27925,33744,41488,42557,43805,51319,64385,64389,72469</link.rule.ids></links><search><creatorcontrib>Zhang, Yong-tao</creatorcontrib><creatorcontrib>Dan, Zhi-gang</creatorcontrib><creatorcontrib>Duan, Ning</creatorcontrib><creatorcontrib>Xin, Bao-ping</creatorcontrib><title>Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant</title><title>International journal of minerals, metallurgy and materials</title><addtitle>Int J Miner Metall Mater</addtitle><description>The hydrometallurgical strategy of extracting Mn from low-grade Mn ores has attracted attention for the production of electrolytic manganese metal (EMM). In this work, the reductive dissolution of low-grade MnO
2
ores using toxic nitrocellulose acidic wastewater (NAW) as a reductant was investigated for the first time. Under the optimized conditions of an MnO
2
ore dosage of 100 g·L
−1
, an ore particle size of −200 mesh, concentrated H
2
SO
4
-to-NAW volume ratio of 0.12, reaction temperature of 90°C, stirring speed at 160 r·min
−1
, and a contact time of 120 min, the reductive leaching efficiency of Mn and the total organic carbon (TOC) removal efficiency of NAW reached 97.4% and 98.5%, respectively. The residual TOC of 31.6 mg·L
−1
did not adversely affect the preparation of EMM. The current process offers a feasible route for the concurrent realization of the reductive leaching of Mn and the treatment of toxic wastewater via a simple one-step process.</description><subject>Cellulose</subject><subject>Cellulose esters</subject><subject>Cellulose nitrate</subject><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemical oxygen demand</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Corrosion and Coatings</subject><subject>Efficiency</subject><subject>Explosives</subject><subject>Glass</subject><subject>Leaching</subject><subject>Manganese</subject><subject>Manganese dioxide</subject><subject>Manganese ores</subject><subject>Manufacturing</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Natural Materials</subject><subject>Organic carbon</subject><subject>Particle size</subject><subject>Reducing agents</subject><subject>Sulfuric acid</subject><subject>Surfaces and Interfaces</subject><subject>Syrups & sweeteners</subject><subject>Thin Films</subject><subject>Toxicity</subject><subject>Tribology</subject><subject>Wastewater treatment</subject><issn>1674-4799</issn><issn>1869-103X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>AFKRA</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><recordid>eNp1kV9LwzAUxYsoOKcfwLeAjxJNmiZpHmX4DwaC7MG3kKa3o7NrZtKuG_jhzagwX3xKuPmdcy45SXJNyR0lRN4HmgrKMKE5piJTWJ0kE5oLhSlhH6fxLmSGM6nUeXIRwooQISWRk-T7HcredvUWkAfrtuD3yFVobdqlaSEAqrxbo8YNeOlNCX8eytrt6jhxHlAf6naJujiwqK077yw0Td-4iBlbl2gwoYPBdOCRCTHoEGna7jI5q0wT4Or3nCaLp8fF7AXP355fZw9zbBlPOywYzyxjGa_KlCsJWSZIYQtiRalMQYQVNM8lZ1aaXFCwXKoccia4MSAtYdPkdrQdTFvF_fXK9b6NgbpYfa7K3a7QkMafI4qQNNI3I73x7quH0B3xVFElOKdURoqOlPUuBA-V3vh6bfxeU6IPjeixER199aERraImHTUhsu0S_NH5f9EPhzmQWA</recordid><startdate>20180901</startdate><enddate>20180901</enddate><creator>Zhang, Yong-tao</creator><creator>Dan, Zhi-gang</creator><creator>Duan, Ning</creator><creator>Xin, Bao-ping</creator><general>University of Science and Technology Beijing</general><general>Springer Nature B.V</general><general>School of Petroleum and Environment Engineering, Yan'an University, Yan'an 716000, China</general><general>School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China%Technology Center for Heavy Metal Cleaner Production Engineering, Chinese Research Academy of Environmental Sciences, Beijing 100012, China%School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China</general><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20180901</creationdate><title>Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant</title><author>Zhang, Yong-tao ; Dan, Zhi-gang ; Duan, Ning ; Xin, Bao-ping</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c352t-6354c3345fd2597e4460bcb0c6d9ab06c6188753c7a861ec5798e8365aae7c03</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>Cellulose</topic><topic>Cellulose esters</topic><topic>Cellulose nitrate</topic><topic>Ceramics</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemical oxygen demand</topic><topic>Chemistry and Materials Science</topic><topic>Composites</topic><topic>Corrosion and Coatings</topic><topic>Efficiency</topic><topic>Explosives</topic><topic>Glass</topic><topic>Leaching</topic><topic>Manganese</topic><topic>Manganese dioxide</topic><topic>Manganese ores</topic><topic>Manufacturing</topic><topic>Materials Science</topic><topic>Metallic Materials</topic><topic>Natural Materials</topic><topic>Organic carbon</topic><topic>Particle size</topic><topic>Reducing agents</topic><topic>Sulfuric acid</topic><topic>Surfaces and Interfaces</topic><topic>Syrups & sweeteners</topic><topic>Thin Films</topic><topic>Toxicity</topic><topic>Tribology</topic><topic>Wastewater treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Yong-tao</creatorcontrib><creatorcontrib>Dan, Zhi-gang</creatorcontrib><creatorcontrib>Duan, Ning</creatorcontrib><creatorcontrib>Xin, Bao-ping</creatorcontrib><collection>CrossRef</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central UK/Ireland</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>International journal of minerals, metallurgy and materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Yong-tao</au><au>Dan, Zhi-gang</au><au>Duan, Ning</au><au>Xin, Bao-ping</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant</atitle><jtitle>International journal of minerals, metallurgy and materials</jtitle><stitle>Int J Miner Metall Mater</stitle><date>2018-09-01</date><risdate>2018</risdate><volume>25</volume><issue>9</issue><spage>990</spage><epage>999</epage><pages>990-999</pages><issn>1674-4799</issn><eissn>1869-103X</eissn><abstract>The hydrometallurgical strategy of extracting Mn from low-grade Mn ores has attracted attention for the production of electrolytic manganese metal (EMM). In this work, the reductive dissolution of low-grade MnO
2
ores using toxic nitrocellulose acidic wastewater (NAW) as a reductant was investigated for the first time. Under the optimized conditions of an MnO
2
ore dosage of 100 g·L
−1
, an ore particle size of −200 mesh, concentrated H
2
SO
4
-to-NAW volume ratio of 0.12, reaction temperature of 90°C, stirring speed at 160 r·min
−1
, and a contact time of 120 min, the reductive leaching efficiency of Mn and the total organic carbon (TOC) removal efficiency of NAW reached 97.4% and 98.5%, respectively. The residual TOC of 31.6 mg·L
−1
did not adversely affect the preparation of EMM. The current process offers a feasible route for the concurrent realization of the reductive leaching of Mn and the treatment of toxic wastewater via a simple one-step process.</abstract><cop>Beijing</cop><pub>University of Science and Technology Beijing</pub><doi>10.1007/s12613-018-1649-9</doi><tpages>10</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1674-4799 |
| ispartof | International journal of minerals, metallurgy and materials, 2018-09, Vol.25 (9), p.990-999 |
| issn | 1674-4799 1869-103X |
| language | eng |
| recordid | cdi_wanfang_journals_bjkjdxxb_e201809002 |
| source | SpringerNature Journals; ProQuest Central UK/Ireland; Alma/SFX Local Collection; ProQuest Central |
| subjects | Cellulose Cellulose esters Cellulose nitrate Ceramics Characterization and Evaluation of Materials Chemical oxygen demand Chemistry and Materials Science Composites Corrosion and Coatings Efficiency Explosives Glass Leaching Manganese Manganese dioxide Manganese ores Manufacturing Materials Science Metallic Materials Natural Materials Organic carbon Particle size Reducing agents Sulfuric acid Surfaces and Interfaces Syrups & sweeteners Thin Films Toxicity Tribology Wastewater treatment |
| title | Reductive recovery of manganese from low-grade manganese dioxide ore using toxic nitrocellulose acid wastewater as reductant |
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