Investigation of the deterioration of passive films in H2S-containing solutions
The effect of H2S on the corrosion behavior of 316 L stainless steel was investigated using electrochemical methods by changing the gas condition from CO2 to H2S and then back to CO2. The presence of H2S showed an acceleration effect on the corrosion of 316 L stainless steel in comparison with CO2....
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| Veröffentlicht in: | International journal of minerals, metallurgy and materials metallurgy and materials, 2017-08, Vol.24 (8), p.943-953 |
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| container_title | International journal of minerals, metallurgy and materials |
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| creator | Wang, Zhu Zhang, Lei Tang, Xian Cui, Zhao-yang Xue, Jun-peng Lu, Min-xu |
| description | The effect of H2S on the corrosion behavior of 316 L stainless steel was investigated using electrochemical methods by changing the gas condition from CO2 to H2S and then back to CO2. The presence of H2S showed an acceleration effect on the corrosion of 316 L stainless steel in comparison with CO2. The acceleration effect remained even after the complete removal of H2S by CO2, indicating that the passive film was irreversibly damaged. X-ray photoelectron spectroscopy（XPS） analysis indicated that the passive film was composed of Cr2O3, Fe2O3, and FeS2 after being immersed in H2S-containing solutions. The semiconducting property of the passive film was then investigated by using the Mott–Schottky approach. The presence of sulfides resulted in higher acceptor and donor densities and thus was responsible for the deterioration of passive films. |
| doi_str_mv | 10.1007/s12613-017-1482-6 |
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The presence of H2S showed an acceleration effect on the corrosion of 316 L stainless steel in comparison with CO2. The acceleration effect remained even after the complete removal of H2S by CO2, indicating that the passive film was irreversibly damaged. X-ray photoelectron spectroscopy（XPS） analysis indicated that the passive film was composed of Cr2O3, Fe2O3, and FeS2 after being immersed in H2S-containing solutions. The semiconducting property of the passive film was then investigated by using the Mott–Schottky approach. The presence of sulfides resulted in higher acceptor and donor densities and thus was responsible for the deterioration of passive films.</description><identifier>ISSN: 1674-4799</identifier><identifier>EISSN: 1869-103X</identifier><identifier>DOI: 10.1007/s12613-017-1482-6</identifier><language>eng</language><publisher>Beijing: University of Science and Technology Beijing</publisher><subject>Austenitic stainless steels ; Carbon dioxide ; Ceramics ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Composites ; Corrosion ; Corrosion and Coatings ; Corrosion effects ; Corrosion resistance ; Electrochemistry ; Glass ; Hydrogen sulfide ; Investigations ; Materials Science ; Metallic Materials ; Natural Materials ; Photoelectrons ; Pyrite ; Spectrum analysis ; Stainless steel ; Surfaces and Interfaces ; Thin Films ; Tribology ; X ray photoelectron spectroscopy</subject><ispartof>International journal of minerals, metallurgy and materials, 2017-08, Vol.24 (8), p.943-953</ispartof><rights>The Author(s) 2016</rights><rights>The Author(s) 2016. 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All Rights Reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c439t-2fe754be671d8b0c06342d871afa529e54cfec39b8c217cb4d347e71585cdb793</citedby><cites>FETCH-LOGICAL-c439t-2fe754be671d8b0c06342d871afa529e54cfec39b8c217cb4d347e71585cdb793</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/85313A/85313A.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12613-017-1482-6$$EPDF$$P50$$Gspringer$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2919617900?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>314,776,780,21367,27901,27902,33721,41464,42533,43781,51294</link.rule.ids></links><search><creatorcontrib>Wang, Zhu</creatorcontrib><creatorcontrib>Zhang, Lei</creatorcontrib><creatorcontrib>Tang, Xian</creatorcontrib><creatorcontrib>Cui, Zhao-yang</creatorcontrib><creatorcontrib>Xue, Jun-peng</creatorcontrib><creatorcontrib>Lu, Min-xu</creatorcontrib><title>Investigation of the deterioration of passive films in H2S-containing solutions</title><title>International journal of minerals, metallurgy and materials</title><addtitle>Int J Miner Metall Mater</addtitle><addtitle>International Journal of Minerals Metallurgy and Materials</addtitle><description>The effect of H2S on the corrosion behavior of 316 L stainless steel was investigated using electrochemical methods by changing the gas condition from CO2 to H2S and then back to CO2. The presence of H2S showed an acceleration effect on the corrosion of 316 L stainless steel in comparison with CO2. The acceleration effect remained even after the complete removal of H2S by CO2, indicating that the passive film was irreversibly damaged. X-ray photoelectron spectroscopy（XPS） analysis indicated that the passive film was composed of Cr2O3, Fe2O3, and FeS2 after being immersed in H2S-containing solutions. The semiconducting property of the passive film was then investigated by using the Mott–Schottky approach. The presence of sulfides resulted in higher acceptor and donor densities and thus was responsible for the deterioration of passive films.</description><subject>Austenitic stainless steels</subject><subject>Carbon dioxide</subject><subject>Ceramics</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Composites</subject><subject>Corrosion</subject><subject>Corrosion and Coatings</subject><subject>Corrosion effects</subject><subject>Corrosion resistance</subject><subject>Electrochemistry</subject><subject>Glass</subject><subject>Hydrogen sulfide</subject><subject>Investigations</subject><subject>Materials Science</subject><subject>Metallic Materials</subject><subject>Natural Materials</subject><subject>Photoelectrons</subject><subject>Pyrite</subject><subject>Spectrum analysis</subject><subject>Stainless steel</subject><subject>Surfaces and Interfaces</subject><subject>Thin Films</subject><subject>Tribology</subject><subject>X ray photoelectron spectroscopy</subject><issn>1674-4799</issn><issn>1869-103X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>C6C</sourceid><sourceid>BENPR</sourceid><recordid>eNp9kc1qGzEUhYfSQtMkD5DdQJdFqa7-tSwmaQKBLJJAd0Kj0UzkOpItjVP37Stngr3r6l4u3zkHHTXNBeBLwFh-L0AEUIRBImCKIPGhOQElNAJMf32su5AMMan15-ZLKUuMhZRYnjT3t_HVlymMdgoptmlop2ff9n7yOaR8OK5tKeHVt0NYvZQ2xPaGPCCX4mRDDHFsS1pt92w5az4NdlX8-fs8bZ6urx4XN-ju_uft4scdcozqCZHBS846LyT0qsMOC8pIryTYwXKiPWdu8I7qTjkC0nWsp0x6CVxx13dS09Pm2-z7x8bBxtEs0zbHmmi65e9lv9t1xpPaBlYYaKW_zvQ6p822vveIEw1agNQYVwpmyuVUSvaDWefwYvNfA9jsWzZzy6b6mn3LRlQNmTWlsnH0-ej8PxF9D3pOcdxU3SFJ1H-SXGmOmWKac6a4eNuA_gMvNY6j</recordid><startdate>20170801</startdate><enddate>20170801</enddate><creator>Wang, Zhu</creator><creator>Zhang, Lei</creator><creator>Tang, Xian</creator><creator>Cui, Zhao-yang</creator><creator>Xue, Jun-peng</creator><creator>Lu, Min-xu</creator><general>University of Science and Technology Beijing</general><general>Springer Nature B.V</general><general>Safetech Research Institute, Beijing 100083, China</general><general>Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China%Institute of Advanced Materials and Technology, University of Science and Technology Beijing, Beijing 100083, China</general><scope>2RA</scope><scope>92L</scope><scope>CQIGP</scope><scope>~WA</scope><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>KB.</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20170801</creationdate><title>Investigation of the deterioration of passive films in H2S-containing solutions</title><author>Wang, Zhu ; 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The presence of H2S showed an acceleration effect on the corrosion of 316 L stainless steel in comparison with CO2. The acceleration effect remained even after the complete removal of H2S by CO2, indicating that the passive film was irreversibly damaged. X-ray photoelectron spectroscopy（XPS） analysis indicated that the passive film was composed of Cr2O3, Fe2O3, and FeS2 after being immersed in H2S-containing solutions. The semiconducting property of the passive film was then investigated by using the Mott–Schottky approach. The presence of sulfides resulted in higher acceptor and donor densities and thus was responsible for the deterioration of passive films.</abstract><cop>Beijing</cop><pub>University of Science and Technology Beijing</pub><doi>10.1007/s12613-017-1482-6</doi><tpages>11</tpages><oa>free_for_read</oa></addata></record> |
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| subjects | Austenitic stainless steels Carbon dioxide Ceramics Characterization and Evaluation of Materials Chemistry and Materials Science Composites Corrosion Corrosion and Coatings Corrosion effects Corrosion resistance Electrochemistry Glass Hydrogen sulfide Investigations Materials Science Metallic Materials Natural Materials Photoelectrons Pyrite Spectrum analysis Stainless steel Surfaces and Interfaces Thin Films Tribology X ray photoelectron spectroscopy |
| title | Investigation of the deterioration of passive films in H2S-containing solutions |
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