A thermodynamic study on the Ti-bearing inclusions in the 17Cr stainless steel
In order to utilize the advantage of oxides in stainless steel, the formation of titanium nitride (TiN) and oxide (Ti sub( x)O sub( y)) in the 17Cr steel was investigated by the calculation of the free energy of reaction and thermodynamic calculation with Thermo-calc software. The result indicates t...
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description | In order to utilize the advantage of oxides in stainless steel, the formation of titanium nitride (TiN) and oxide (Ti sub( x)O sub( y)) in the 17Cr steel was investigated by the calculation of the free energy of reaction and thermodynamic calculation with Thermo-calc software. The result indicates that the competitive reaction between the dissolved (O) and the dissolved (N) with the dissolved (Ti) in molten steel results in different precipitation sequences of TiN and Ti sub( x)O sub( y). The increase of (Ti) causes a higher precipitation temperature of TiN and Ti sub( x)O sub( y) in both Ti-N and Ti-O alloy systems. Equilibrium relations of (Ti) vs (N) and (Ti) vs (O) show that the solubility products fall with the decrease of the temperature, and then the precipitation of the inclusions becomes easier. In the Ti-O alloy system, a high (O) and a low (Ti) are favorable to the precipitation of Ti sub( 3)O sub(5), and a high (Ti) content and a low (O) favorable to the Ti sub( 2)O sub( 3) precipitation. |
doi_str_mv | 10.3969/j.issn.1674-3458.2010.04.008 |
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The result indicates that the competitive reaction between the dissolved (O) and the dissolved (N) with the dissolved (Ti) in molten steel results in different precipitation sequences of TiN and Ti sub( x)O sub( y). The increase of (Ti) causes a higher precipitation temperature of TiN and Ti sub( x)O sub( y) in both Ti-N and Ti-O alloy systems. Equilibrium relations of (Ti) vs (N) and (Ti) vs (O) show that the solubility products fall with the decrease of the temperature, and then the precipitation of the inclusions becomes easier. In the Ti-O alloy system, a high (O) and a low (Ti) are favorable to the precipitation of Ti sub( 3)O sub(5), and a high (Ti) content and a low (O) favorable to the Ti sub( 2)O sub( 3) precipitation.</description><identifier>ISSN: 1674-3458</identifier><identifier>DOI: 10.3969/j.issn.1674-3458.2010.04.008</identifier><language>eng</language><publisher>School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China%Stainless Steel Technology Center,Research Institute, Baoshan Iron & Steel Co. , Ltd. , Shanghai 200431, China</publisher><subject>Chromium steels ; Dissolution ; Ferritic stainless steels ; Mathematical analysis ; Oxides ; Precipitation ; Titanium ; Titanium base alloys ; Titanium nitride</subject><ispartof>Baosteel Technical Research, 2010-12, Vol.4 (4), p.37-37</ispartof><rights>Copyright © Wanfang Data Co. Ltd. All Rights Reserved.</rights><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://www.wanfangdata.com.cn/images/PeriodicalImages/bgjsyj/bgjsyj.jpg</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Jianping, Liang</creatorcontrib><creatorcontrib>Laizhu, Jiang</creatorcontrib><creatorcontrib>Ruiyin, Zhai</creatorcontrib><creatorcontrib>Haifeng, Yu</creatorcontrib><creatorcontrib>Chang, E</creatorcontrib><title>A thermodynamic study on the Ti-bearing inclusions in the 17Cr stainless steel</title><title>Baosteel Technical Research</title><description>In order to utilize the advantage of oxides in stainless steel, the formation of titanium nitride (TiN) and oxide (Ti sub( x)O sub( y)) in the 17Cr steel was investigated by the calculation of the free energy of reaction and thermodynamic calculation with Thermo-calc software. The result indicates that the competitive reaction between the dissolved (O) and the dissolved (N) with the dissolved (Ti) in molten steel results in different precipitation sequences of TiN and Ti sub( x)O sub( y). The increase of (Ti) causes a higher precipitation temperature of TiN and Ti sub( x)O sub( y) in both Ti-N and Ti-O alloy systems. Equilibrium relations of (Ti) vs (N) and (Ti) vs (O) show that the solubility products fall with the decrease of the temperature, and then the precipitation of the inclusions becomes easier. In the Ti-O alloy system, a high (O) and a low (Ti) are favorable to the precipitation of Ti sub( 3)O sub(5), and a high (Ti) content and a low (O) favorable to the Ti sub( 2)O sub( 3) precipitation.</description><subject>Chromium steels</subject><subject>Dissolution</subject><subject>Ferritic stainless steels</subject><subject>Mathematical analysis</subject><subject>Oxides</subject><subject>Precipitation</subject><subject>Titanium</subject><subject>Titanium base alloys</subject><subject>Titanium nitride</subject><issn>1674-3458</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><recordid>eNo9kM1OwzAQhH0Aiar0HXJAgkvC2nEc-1hV_EkVXHKPnHhTHKVOyTZCfXtcijjtp5nRrmYZu-OQ5UaZxz7zRCHjqpRpLgudCYgWyAxAX7HFv37DVkQ9AAijJFdywd7XyfETp_3oTsHufZvQcXanZAxnOal82qCdfNglPrTDTH4MFPHX5OVminHrw4BEkRCHW3bd2YFw9TeXrHp-qjav6fbj5W2z3qYHVZi0wK7R4DprnYbOce06FCrnoiuEbbBUJYAyEbDVXBspJYJB4AVo53KL-ZLdX9Z-29DZsKv7cZ5CPFg3u55O_bk-SAATkw-X5GEav2akY7331OIw2IDjTHV8ghBCF1zmP1xSYYE</recordid><startdate>20101201</startdate><enddate>20101201</enddate><creator>Jianping, Liang</creator><creator>Laizhu, Jiang</creator><creator>Ruiyin, Zhai</creator><creator>Haifeng, Yu</creator><creator>Chang, E</creator><general>School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China%Stainless Steel Technology Center,Research Institute, Baoshan Iron & Steel Co. , Ltd. , Shanghai 200431, China</general><general>Stainless Steel Technology Center,Research Institute, Baoshan Iron & Steel Co. , Ltd. , Shanghai 200431, China</general><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>2B.</scope><scope>4A8</scope><scope>92I</scope><scope>93N</scope><scope>PSX</scope><scope>TCJ</scope></search><sort><creationdate>20101201</creationdate><title>A thermodynamic study on the Ti-bearing inclusions in the 17Cr stainless steel</title><author>Jianping, Liang ; Laizhu, Jiang ; Ruiyin, Zhai ; Haifeng, Yu ; Chang, E</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p659-5efb80dfaad80fd18dfe26312f52abe7670069be7ec8189444e09e01508dd3ae3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Chromium steels</topic><topic>Dissolution</topic><topic>Ferritic stainless steels</topic><topic>Mathematical analysis</topic><topic>Oxides</topic><topic>Precipitation</topic><topic>Titanium</topic><topic>Titanium base alloys</topic><topic>Titanium nitride</topic><toplevel>online_resources</toplevel><creatorcontrib>Jianping, Liang</creatorcontrib><creatorcontrib>Laizhu, Jiang</creatorcontrib><creatorcontrib>Ruiyin, Zhai</creatorcontrib><creatorcontrib>Haifeng, Yu</creatorcontrib><creatorcontrib>Chang, E</creatorcontrib><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>Wanfang Data Journals - Hong Kong</collection><collection>WANFANG Data Centre</collection><collection>Wanfang Data Journals</collection><collection>万方数据期刊 - 香港版</collection><collection>China Online Journals (COJ)</collection><collection>China Online Journals (COJ)</collection><jtitle>Baosteel Technical Research</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Jianping, Liang</au><au>Laizhu, Jiang</au><au>Ruiyin, Zhai</au><au>Haifeng, Yu</au><au>Chang, E</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A thermodynamic study on the Ti-bearing inclusions in the 17Cr stainless steel</atitle><jtitle>Baosteel Technical Research</jtitle><date>2010-12-01</date><risdate>2010</risdate><volume>4</volume><issue>4</issue><spage>37</spage><epage>37</epage><pages>37-37</pages><issn>1674-3458</issn><abstract>In order to utilize the advantage of oxides in stainless steel, the formation of titanium nitride (TiN) and oxide (Ti sub( x)O sub( y)) in the 17Cr steel was investigated by the calculation of the free energy of reaction and thermodynamic calculation with Thermo-calc software. The result indicates that the competitive reaction between the dissolved (O) and the dissolved (N) with the dissolved (Ti) in molten steel results in different precipitation sequences of TiN and Ti sub( x)O sub( y). The increase of (Ti) causes a higher precipitation temperature of TiN and Ti sub( x)O sub( y) in both Ti-N and Ti-O alloy systems. Equilibrium relations of (Ti) vs (N) and (Ti) vs (O) show that the solubility products fall with the decrease of the temperature, and then the precipitation of the inclusions becomes easier. In the Ti-O alloy system, a high (O) and a low (Ti) are favorable to the precipitation of Ti sub( 3)O sub(5), and a high (Ti) content and a low (O) favorable to the Ti sub( 2)O sub( 3) precipitation.</abstract><pub>School of Materials Science and Engineering, Shanghai University, Shanghai 200072, China%Stainless Steel Technology Center,Research Institute, Baoshan Iron & Steel Co. , Ltd. , Shanghai 200431, China</pub><doi>10.3969/j.issn.1674-3458.2010.04.008</doi><tpages>1</tpages></addata></record> |
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subjects | Chromium steels Dissolution Ferritic stainless steels Mathematical analysis Oxides Precipitation Titanium Titanium base alloys Titanium nitride |
title | A thermodynamic study on the Ti-bearing inclusions in the 17Cr stainless steel |
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