A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate
A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu (L)(1,3-BDC)] ( ), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1 -imidazo[4,5- ][1,10]phenanthroline and 1,3-H BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X-ray...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2015-12, Vol.70 (12), p.857-861 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
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| creator | Kong, Zhi-Guo Guo, Sheng-Nan Sun, Bo Ng, Seik Weng |
| description | A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu
(L)(1,3-BDC)]
(
), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1
-imidazo[4,5-
][1,10]phenanthroline and 1,3-H
BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X-ray diffraction analysis and powder X-ray diffraction. The crystals are the monoclinic space group
with
= 10.686(4),
= 17.376(8),
= 11.759(4) Å,
= 92.072(14)°, C
Cu
FN
,
= 604.50,
= 2182.1(15) Å
,
= 4,
= 1.84 g cm
,
= 0.0588 and
= 0.1202 (all data). In complex
, the mixed-valence Cu(I)/Cu(II) atoms are linked by L and 1,3-BDC to give a rare 3D (3,3,4)-connected (4.7.9)(7.8.9)(4.7.8.9
) framework. The temperature-dependent magnetic susceptibility of
was investigated in the temperature range of 2–300 K. |
| doi_str_mv | 10.1515/znb-2015-0095 |
| format | Article |
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(L)(1,3-BDC)]
(
), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1
-imidazo[4,5-
][1,10]phenanthroline and 1,3-H
BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X-ray diffraction analysis and powder X-ray diffraction. The crystals are the monoclinic space group
with
= 10.686(4),
= 17.376(8),
= 11.759(4) Å,
= 92.072(14)°, C
Cu
FN
,
= 604.50,
= 2182.1(15) Å
,
= 4,
= 1.84 g cm
,
= 0.0588 and
= 0.1202 (all data). In complex
, the mixed-valence Cu(I)/Cu(II) atoms are linked by L and 1,3-BDC to give a rare 3D (3,3,4)-connected (4.7.9)(7.8.9)(4.7.8.9
) framework. The temperature-dependent magnetic susceptibility of
was investigated in the temperature range of 2–300 K.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-2015-0095</identifier><language>eng</language><publisher>De Gruyter</publisher><subject>coordination polymer ; copper ; crystal structure ; mixed-valence Cu(I)/Cu(II) ; molecular magnetism</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2015-12, Vol.70 (12), p.857-861</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Kong, Zhi-Guo</creatorcontrib><creatorcontrib>Guo, Sheng-Nan</creatorcontrib><creatorcontrib>Sun, Bo</creatorcontrib><creatorcontrib>Ng, Seik Weng</creatorcontrib><title>A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu
(L)(1,3-BDC)]
(
), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1
-imidazo[4,5-
][1,10]phenanthroline and 1,3-H
BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X-ray diffraction analysis and powder X-ray diffraction. The crystals are the monoclinic space group
with
= 10.686(4),
= 17.376(8),
= 11.759(4) Å,
= 92.072(14)°, C
Cu
FN
,
= 604.50,
= 2182.1(15) Å
,
= 4,
= 1.84 g cm
,
= 0.0588 and
= 0.1202 (all data). In complex
, the mixed-valence Cu(I)/Cu(II) atoms are linked by L and 1,3-BDC to give a rare 3D (3,3,4)-connected (4.7.9)(7.8.9)(4.7.8.9
) framework. The temperature-dependent magnetic susceptibility of
was investigated in the temperature range of 2–300 K.</description><subject>coordination polymer</subject><subject>copper</subject><subject>crystal structure</subject><subject>mixed-valence Cu(I)/Cu(II)</subject><subject>molecular magnetism</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2015</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNotkE9Lw0AUxBdRsFaP3vfYQtfuy2azCXiR-qeFghc9lRI22Zc2Jd0t20SbfhO_rQl6mRlm4D34EXIP_AEkyOnZZizgIBnnibwgA4gjyRSAuiQDnoiAcaWia3JzPO44hyQM-YD8PFHxTPflCQ370hXaHOmsGS3G014XY5o7501pdV06Sw-uavfou9Iea9_kNRqatTRgo4AVVeO8O2zRttWYwZyV-9Los1uFE8mK9QomwNf9rG299a4qLVJtDYWJYBnaM1o0Za595k5tpWu8JVeFro549-9D8vn68jGbs-X722L2tGSbIJQ1ixCLQsUy00YqSDALTGy6CmUWgggTXmhujIBIF1zEkAijRVKYMM8URjyMxZA8_t391lWN3uDGN20X0p1rvO0-p8DTnm_a8U17vmnPV3EIYqnELz4NcYM</recordid><startdate>20151201</startdate><enddate>20151201</enddate><creator>Kong, Zhi-Guo</creator><creator>Guo, Sheng-Nan</creator><creator>Sun, Bo</creator><creator>Ng, Seik Weng</creator><general>De Gruyter</general><scope/></search><sort><creationdate>20151201</creationdate><title>A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate</title><author>Kong, Zhi-Guo ; Guo, Sheng-Nan ; Sun, Bo ; Ng, Seik Weng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g245t-6eeff785bad5719eb2d8deffe5b413490fa0dd316af038193da39fd4cb7e60483</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2015</creationdate><topic>coordination polymer</topic><topic>copper</topic><topic>crystal structure</topic><topic>mixed-valence Cu(I)/Cu(II)</topic><topic>molecular magnetism</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Kong, Zhi-Guo</creatorcontrib><creatorcontrib>Guo, Sheng-Nan</creatorcontrib><creatorcontrib>Sun, Bo</creatorcontrib><creatorcontrib>Ng, Seik Weng</creatorcontrib><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Kong, Zhi-Guo</au><au>Guo, Sheng-Nan</au><au>Sun, Bo</au><au>Ng, Seik Weng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>2015-12-01</date><risdate>2015</risdate><volume>70</volume><issue>12</issue><spage>857</spage><epage>861</epage><pages>857-861</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>A mixed-valence Cu(I)/Cu(II) coordination polymer, namely, [Cu
(L)(1,3-BDC)]
(
), has been synthesized under hydrothermal conditions (HL = 2-(2-fluorophenyl)-1
-imidazo[4,5-
][1,10]phenanthroline and 1,3-H
BDC = 1,3-benzenedicarboxylic acid). Its structure has been determined by single crystal X-ray diffraction analysis and powder X-ray diffraction. The crystals are the monoclinic space group
with
= 10.686(4),
= 17.376(8),
= 11.759(4) Å,
= 92.072(14)°, C
Cu
FN
,
= 604.50,
= 2182.1(15) Å
,
= 4,
= 1.84 g cm
,
= 0.0588 and
= 0.1202 (all data). In complex
, the mixed-valence Cu(I)/Cu(II) atoms are linked by L and 1,3-BDC to give a rare 3D (3,3,4)-connected (4.7.9)(7.8.9)(4.7.8.9
) framework. The temperature-dependent magnetic susceptibility of
was investigated in the temperature range of 2–300 K.</abstract><pub>De Gruyter</pub><doi>10.1515/znb-2015-0095</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
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| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2015-12, Vol.70 (12), p.857-861 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_walterdegruyter_journals_10_1515_znb_2015_00957012857 |
| source | Alma/SFX Local Collection |
| subjects | coordination polymer copper crystal structure mixed-valence Cu(I)/Cu(II) molecular magnetism |
| title | A 3D mixed-valence Cu(I)/Cu(II) coordination polymer constructed by 2-(2-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,3-benzenedicarboxylate |
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