Synthesis And Luminescence Of RhIII(phpy)2(S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate
Complexes of the general composition Rh (phpy) (S∪E) with phpy = 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E = diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature luminescen...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2005-03, Vol.60 (3), p.359-362 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
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| creator | Pawlowski, Valeri Kunkely, Horst Vogler, Arnd |
| description | Complexes of the general composition Rh
(phpy)
(S∪E) with phpy
= 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E
= diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature luminescence which originates from a phpy ππ
intraligand triplet. For the complex with S∪E
= 2-quinolinethiolate (or thiooxinate) the lowest-energy excited state is of the quinolinethiolate intraligand type. This complex displays a fluorescence as well as a phosphorescence under ambient conditions |
| doi_str_mv | 10.1515/znb-2005-0323 |
| format | Article |
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(phpy)
(S∪E) with phpy
= 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E
= diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature luminescence which originates from a phpy ππ
intraligand triplet. For the complex with S∪E
= 2-quinolinethiolate (or thiooxinate) the lowest-energy excited state is of the quinolinethiolate intraligand type. This complex displays a fluorescence as well as a phosphorescence under ambient conditions</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-2005-0323</identifier><language>eng</language><publisher>Verlag der Zeitschrift für Naturforschung</publisher><subject>Electronic Spectra ; Luminescence ; Rhodium Complexes ; Thiolate Complexes</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2005-03, Vol.60 (3), p.359-362</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Pawlowski, Valeri</creatorcontrib><creatorcontrib>Kunkely, Horst</creatorcontrib><creatorcontrib>Vogler, Arnd</creatorcontrib><title>Synthesis And Luminescence Of RhIII(phpy)2(S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>Complexes of the general composition Rh
(phpy)
(S∪E) with phpy
= 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E
= diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature luminescence which originates from a phpy ππ
intraligand triplet. For the complex with S∪E
= 2-quinolinethiolate (or thiooxinate) the lowest-energy excited state is of the quinolinethiolate intraligand type. This complex displays a fluorescence as well as a phosphorescence under ambient conditions</description><subject>Electronic Spectra</subject><subject>Luminescence</subject><subject>Rhodium Complexes</subject><subject>Thiolate Complexes</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2005</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNpNkL1OwzAUhS0EEqUwsntsJQz-SZxYiKEqBSJV4qeVGCPXdkmq1InyIwgTIztvwSPwOH0SnNKB6V6dc893pQPAKcHnxCf-xbtdIIqxjzCjbA_0SMh9FBAS7IMeFowiHAT8EBxV1QpjIjwP98DPrLV1Yqq0giOr4bRZp9ZUylhl4P0SPiVRFA2KpGiHdDDbfH5PhnCcr4vMvJkKPqd1Ajtz8_EFr-C1Kcq8zq2sjYYUPSTGtlnRlql2zC1-S9gdp6ZO2kw7RJorWS7k2uXOutwu0RmZ07ZJih6b1ObZP_0YHCxlVpmT3eyD-c1kPr5D0_vbaDyaokYQgTSWVGHBiSSKKxGaYBFKwo2iTvCYDqQIta9wKI0nxZIQLpgkIeNYL7DHOOuDyz_sq8xqU2rzUjatW-JV3pTWPY4Jjrv-Y9d_3PUfd_1zzJgv2C9p_YEB</recordid><startdate>20050301</startdate><enddate>20050301</enddate><creator>Pawlowski, Valeri</creator><creator>Kunkely, Horst</creator><creator>Vogler, Arnd</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope/></search><sort><creationdate>20050301</creationdate><title>Synthesis And Luminescence Of RhIII(phpy)2(S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate</title><author>Pawlowski, Valeri ; Kunkely, Horst ; Vogler, Arnd</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-u919-d0a2c0961a1c6c98e7b8a16ec2a1c43d7a98d5c08ae4a9f11693a18360db04363</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2005</creationdate><topic>Electronic Spectra</topic><topic>Luminescence</topic><topic>Rhodium Complexes</topic><topic>Thiolate Complexes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Pawlowski, Valeri</creatorcontrib><creatorcontrib>Kunkely, Horst</creatorcontrib><creatorcontrib>Vogler, Arnd</creatorcontrib><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Pawlowski, Valeri</au><au>Kunkely, Horst</au><au>Vogler, Arnd</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis And Luminescence Of RhIII(phpy)2(S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>2005-03-01</date><risdate>2005</risdate><volume>60</volume><issue>3</issue><spage>359</spage><epage>362</epage><pages>359-362</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>Complexes of the general composition Rh
(phpy)
(S∪E) with phpy
= 2-(2-pyridyl)phenyl and S∪E− = diethyldithiocarbamate, 2-pyridinethiolate and 2-quinolinethiolate were prepared and characterized. The complexes with S∪E
= diethyldithiocarbamate and 2-pyridinethiolate show a low-temperature luminescence which originates from a phpy ππ
intraligand triplet. For the complex with S∪E
= 2-quinolinethiolate (or thiooxinate) the lowest-energy excited state is of the quinolinethiolate intraligand type. This complex displays a fluorescence as well as a phosphorescence under ambient conditions</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-2005-0323</doi><tpages>4</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2005-03, Vol.60 (3), p.359-362 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_walterdegruyter_journals_10_1515_znb_2005_0323603359 |
| source | Alma/SFX Local Collection |
| subjects | Electronic Spectra Luminescence Rhodium Complexes Thiolate Complexes |
| title | Synthesis And Luminescence Of RhIII(phpy)2(S∪E) Complexes With phpy– = Deprotonated 2-Phenylpyridine And S∪E– = Diethyldithiocarbamate, 2-Pyridinethiolate And 2-Quinolinethiolate |
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