Erstmalige Charakterisierung der Ammoniak-Proton-Komplexe [(NH3)3H]+ und [(NH3)4H]+ in den Kristallstrukturen von (NH4)3AsS4 · 5 NH3 und (NH4)3SbS4 · 8 NH3 / First Characterization of the Ammonia-Proton-Complexes [(NH3)3H]+ and [(NH3)4H]+ in the Crystal Structures of (NH4)3AsS4 · 5 NH3 and (NH4)3SbS4 · 8 NH3
The compounds (NH AsS · 5 NH (1) and (NH SbS · 8 NH (2) were prepared by the reaction of Na AsS and Na SbS with a proton-charged ion exchange material in liquid ammonia and characterized by low temperature single crystal X-ray structure analysis. The ammonium-ammoniates show H N-H···N-hydrogen bonds...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2003-07, Vol.58 (7), p.672-677 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 58 |
| creator | Roßmeier, Thomas Korber, Nikolaus |
| description | The compounds (NH
AsS
· 5 NH
(1) and (NH
SbS
· 8 NH
(2) were prepared by the reaction of Na
AsS
and Na
SbS
with a proton-charged ion exchange material in liquid ammonia and characterized by low temperature single crystal X-ray structure analysis. The ammonium-ammoniates show H
N-H···N-hydrogen bonds between the ammonium ion and ammonia molecules ranging from 1.86 to 2.55 Å (DHA-angles: 145 - 173°) and H3N-H···S-bonds to the thioanions between 2.36 and 2.97 Å (DHA-angles: 130 - 176°). The former of the interactions are responsible for the formation of [(NH
H]
, [(NH
H]
and [(NH
H]
-complexes, the last two of which were characterized by X-ray analysis for the first time. |
| doi_str_mv | 10.1515/znb-2003-0711 |
| format | Article |
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AsS
· 5 NH
(1) and (NH
SbS
· 8 NH
(2) were prepared by the reaction of Na
AsS
and Na
SbS
with a proton-charged ion exchange material in liquid ammonia and characterized by low temperature single crystal X-ray structure analysis. The ammonium-ammoniates show H
N-H···N-hydrogen bonds between the ammonium ion and ammonia molecules ranging from 1.86 to 2.55 Å (DHA-angles: 145 - 173°) and H3N-H···S-bonds to the thioanions between 2.36 and 2.97 Å (DHA-angles: 130 - 176°). The former of the interactions are responsible for the formation of [(NH
H]
, [(NH
H]
and [(NH
H]
-complexes, the last two of which were characterized by X-ray analysis for the first time.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-2003-0711</identifier><language>eng</language><publisher>Verlag der Zeitschrift für Naturforschung</publisher><subject>Ammonium Ion ; Hydrogen Bonding ; Liquid Ammonia ; Low-Temperature Crystal Structure Analysis ; Solvate Crystal</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2003-07, Vol.58 (7), p.672-677</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Roßmeier, Thomas</creatorcontrib><creatorcontrib>Korber, Nikolaus</creatorcontrib><title>Erstmalige Charakterisierung der Ammoniak-Proton-Komplexe [(NH3)3H]+ und [(NH3)4H]+ in den Kristallstrukturen von (NH4)3AsS4 · 5 NH3 und (NH4)3SbS4 · 8 NH3 / First Characterization of the Ammonia-Proton-Complexes [(NH3)3H]+ and [(NH3)4H]+ in the Crystal Structures of (NH4)3AsS4 · 5 NH3 and (NH4)3SbS4 · 8 NH3</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>The compounds (NH
AsS
· 5 NH
(1) and (NH
SbS
· 8 NH
(2) were prepared by the reaction of Na
AsS
and Na
SbS
with a proton-charged ion exchange material in liquid ammonia and characterized by low temperature single crystal X-ray structure analysis. The ammonium-ammoniates show H
N-H···N-hydrogen bonds between the ammonium ion and ammonia molecules ranging from 1.86 to 2.55 Å (DHA-angles: 145 - 173°) and H3N-H···S-bonds to the thioanions between 2.36 and 2.97 Å (DHA-angles: 130 - 176°). The former of the interactions are responsible for the formation of [(NH
H]
, [(NH
H]
and [(NH
H]
-complexes, the last two of which were characterized by X-ray analysis for the first time.</description><subject>Ammonium Ion</subject><subject>Hydrogen Bonding</subject><subject>Liquid Ammonia</subject><subject>Low-Temperature Crystal Structure Analysis</subject><subject>Solvate Crystal</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2003</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqlkc1LAzEQxaMoWD-O3udokbVJd7fb4qksLQsFEepNZEnbtE27m0iSrbb_mHf_Mif9AMHePM3MY97jB4-QW0YfWMzixkaNgialYUATxk5JjbVbcYBrckZqtBM2UU9aF-TS2gWlrBNFtHbS6RnrSl7ImYB0zg1fOmGklcJUagYTYaBbllpJvgyejXZaBQNdvhfiU8Dr3VMW1sPs7R4qNdmfkT-lQqeCAQY5XhTWmWrpKoPSSivAv6gedu0wgu8viAFt24CdPhzt9PZWb0BfIuAObezRNtxJDNFTcHNxgDuwpXs2-xuO_4HzztSsPRwMEW7s4azPPMbGj7Ndk_MpL6y42c8r8tjvvaRZ8MELBJ2ImanWuOQLXRmFHzmjue8px55y31Pue4rbSStphv9z_wBECZ2U</recordid><startdate>20030701</startdate><enddate>20030701</enddate><creator>Roßmeier, Thomas</creator><creator>Korber, Nikolaus</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope/></search><sort><creationdate>20030701</creationdate><title>Erstmalige Charakterisierung der Ammoniak-Proton-Komplexe [(NH3)3H]+ und [(NH3)4H]+ in den Kristallstrukturen von (NH4)3AsS4 · 5 NH3 und (NH4)3SbS4 · 8 NH3 / First Characterization of the Ammonia-Proton-Complexes [(NH3)3H]+ and [(NH3)4H]+ in the Crystal Structures of (NH4)3AsS4 · 5 NH3 and (NH4)3SbS4 · 8 NH3</title><author>Roßmeier, Thomas ; Korber, Nikolaus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-walterdegruyter_journals_10_1515_znb_2003_07115876723</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2003</creationdate><topic>Ammonium Ion</topic><topic>Hydrogen Bonding</topic><topic>Liquid Ammonia</topic><topic>Low-Temperature Crystal Structure Analysis</topic><topic>Solvate Crystal</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Roßmeier, Thomas</creatorcontrib><creatorcontrib>Korber, Nikolaus</creatorcontrib><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Roßmeier, Thomas</au><au>Korber, Nikolaus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Erstmalige Charakterisierung der Ammoniak-Proton-Komplexe [(NH3)3H]+ und [(NH3)4H]+ in den Kristallstrukturen von (NH4)3AsS4 · 5 NH3 und (NH4)3SbS4 · 8 NH3 / First Characterization of the Ammonia-Proton-Complexes [(NH3)3H]+ and [(NH3)4H]+ in the Crystal Structures of (NH4)3AsS4 · 5 NH3 and (NH4)3SbS4 · 8 NH3</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>2003-07-01</date><risdate>2003</risdate><volume>58</volume><issue>7</issue><spage>672</spage><epage>677</epage><pages>672-677</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>The compounds (NH
AsS
· 5 NH
(1) and (NH
SbS
· 8 NH
(2) were prepared by the reaction of Na
AsS
and Na
SbS
with a proton-charged ion exchange material in liquid ammonia and characterized by low temperature single crystal X-ray structure analysis. The ammonium-ammoniates show H
N-H···N-hydrogen bonds between the ammonium ion and ammonia molecules ranging from 1.86 to 2.55 Å (DHA-angles: 145 - 173°) and H3N-H···S-bonds to the thioanions between 2.36 and 2.97 Å (DHA-angles: 130 - 176°). The former of the interactions are responsible for the formation of [(NH
H]
, [(NH
H]
and [(NH
H]
-complexes, the last two of which were characterized by X-ray analysis for the first time.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-2003-0711</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 2003-07, Vol.58 (7), p.672-677 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_walterdegruyter_journals_10_1515_znb_2003_0711587672 |
| source | Alma/SFX Local Collection |
| subjects | Ammonium Ion Hydrogen Bonding Liquid Ammonia Low-Temperature Crystal Structure Analysis Solvate Crystal |
| title | Erstmalige Charakterisierung der Ammoniak-Proton-Komplexe [(NH3)3H]+ und [(NH3)4H]+ in den Kristallstrukturen von (NH4)3AsS4 · 5 NH3 und (NH4)3SbS4 · 8 NH3 / First Characterization of the Ammonia-Proton-Complexes [(NH3)3H]+ and [(NH3)4H]+ in the Crystal Structures of (NH4)3AsS4 · 5 NH3 and (NH4)3SbS4 · 8 NH3 |
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