Dimere und polymere Pnictidostannat(IV)-Anionen -Darstellung und Kristallstrukturen von Na2K3[SnP3], Na2Cs3[SnP3] und Na2K3[SnBi3] / Dimeric and Polymeric Pnictidostannate(IV) Anions -Preparation and Crystal Structures of Na2K3[SnP3], Na2Cs3[SnP3] and Na2K3[SnBi3]
The metallic lustrous compounds Na [SnP ], Na Cs [SnP ], and Na [SnBi ] were prepared from melts of mixtures of the elements. The isotypic compounds Na [SnP ] and Na Cs [SnP ] crystallize in the orthorhombic system, space group Cmca (No 64), Z = 8, with lattice constants a = 1996.1 (4)/2047.9(4) pm,...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1998-04, Vol.53 (4), p.405-410 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
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| creator | Asbrand, Matthias Eisenmann, Brigitte Engelhardt, Holger Rößler, Ute |
| description | The metallic lustrous compounds Na
[SnP
], Na
Cs
[SnP
], and Na
[SnBi
] were prepared from melts of mixtures of the elements. The isotypic compounds Na
[SnP
] and Na
Cs
[SnP
] crystallize in the orthorhombic system, space group Cmca (No 64), Z = 8, with lattice constants a = 1996.1 (4)/2047.9(4) pm, b = 669.5(1)/686.5(2) pm, c = 1494.5(2)/1617.8(3) pm. The structure is characterized by dimeric units [Sn
]
of edge-sharing [SnP
] tetrahedra, which are coordinated by the alkali cations. Na
[SnBi
] crystallizes in the orthorhombic system, space group Ibca (No 73), Z = 8, with lattice constants a = 718.2(1) pm , b -1692.6(2) pm, c = 2159.5(2) pm. In the anionic partial structure [SnBi
] tetrahedra are connected via common corners to infinite
[SnBi
Zweier single chains. The sodium and potassium cat ions separate the chains from each other. Neglecting the distortions caused by covalent bonding and different radii both structure types can be classified as superstructure defect variants of the Li
Bi structure. Different orderings in the occupation of the tetrahedral voids lead to the variants in the anionic assemblies. |
| doi_str_mv | 10.1515/znb-1998-0402 |
| format | Article |
| fullrecord | <record><control><sourceid>walterdegruyter</sourceid><recordid>TN_cdi_walterdegruyter_journals_10_1515_znb_1998_0402534405</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>10_1515_znb_1998_0402534405</sourcerecordid><originalsourceid>FETCH-LOGICAL-j1185-e58c75aab36fcff0a7b5bcd9772bb23758322bd9131ca62b88a4ec1b6ff1fc253</originalsourceid><addsrcrecordid>eNp9kb1PwzAQxQMCqaUwsnsECVN_1HEiptLyUbWCSgUWhCLbcaqU4FR2Aip_PU4oSwemu-e7d_5JLwhOMbrEDLP-t5EQx3EE0QCR_aCLo5BBjjE_CLoopgQizsNOcOTcCiEcDwaou9cZ5x_aalCbFKzLYtOKuclVlaelq4QxojqbvJzDoclLow2AY2FdpYuiNsvWNbW53ysKV9n6vaqt3_ksDXgQZEpfF2ZO3y4aMXJb1Zr-pte5f-iDFiJXQPjR_JfCqx0M3XCAlsMBOLd6LayovGptI7tpMMDCY6gGw4Ey-4dC7FAcB4eZKJw-2dZe8Hx78zS6h7PHu8loOIMrjCMGNYsUZ0JIGmYqy5DgkkmVxpwTKQnlLKKEyDTGFCsREhlFYqAVlmGW4UwRRnvB1e_dL1FU2qZ6aeuNb5JVWVvjf04wSpo4Ex9n0sSZNHEy6uNi9AeppJa-</addsrcrecordid><sourcetype>Publisher</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>Dimere und polymere Pnictidostannat(IV)-Anionen -Darstellung und Kristallstrukturen von Na2K3[SnP3], Na2Cs3[SnP3] und Na2K3[SnBi3] / Dimeric and Polymeric Pnictidostannate(IV) Anions -Preparation and Crystal Structures of Na2K3[SnP3], Na2Cs3[SnP3] and Na2K3[SnBi3]</title><source>Alma/SFX Local Collection</source><creator>Asbrand, Matthias ; Eisenmann, Brigitte ; Engelhardt, Holger ; Rößler, Ute</creator><creatorcontrib>Asbrand, Matthias ; Eisenmann, Brigitte ; Engelhardt, Holger ; Rößler, Ute</creatorcontrib><description>The metallic lustrous compounds Na
[SnP
], Na
Cs
[SnP
], and Na
[SnBi
] were prepared from melts of mixtures of the elements. The isotypic compounds Na
[SnP
] and Na
Cs
[SnP
] crystallize in the orthorhombic system, space group Cmca (No 64), Z = 8, with lattice constants a = 1996.1 (4)/2047.9(4) pm, b = 669.5(1)/686.5(2) pm, c = 1494.5(2)/1617.8(3) pm. The structure is characterized by dimeric units [Sn
]
of edge-sharing [SnP
] tetrahedra, which are coordinated by the alkali cations. Na
[SnBi
] crystallizes in the orthorhombic system, space group Ibca (No 73), Z = 8, with lattice constants a = 718.2(1) pm , b -1692.6(2) pm, c = 2159.5(2) pm. In the anionic partial structure [SnBi
] tetrahedra are connected via common corners to infinite
[SnBi
Zweier single chains. The sodium and potassium cat ions separate the chains from each other. Neglecting the distortions caused by covalent bonding and different radii both structure types can be classified as superstructure defect variants of the Li
Bi structure. Different orderings in the occupation of the tetrahedral voids lead to the variants in the anionic assemblies.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-1998-0402</identifier><language>eng ; jpn</language><publisher>Verlag der Zeitschrift für Naturforschung</publisher><subject>Dimeric Tetrahedral Anions ; Disodium Tricesium Triphosphidostannate( IV) ; Disodium Tripotassium Tribismutidostannate(IV) ; Disodium Tripotassium Triphosphidostannate(IV) ; Zweier Single Chains</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1998-04, Vol.53 (4), p.405-410</ispartof><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27901,27902</link.rule.ids></links><search><creatorcontrib>Asbrand, Matthias</creatorcontrib><creatorcontrib>Eisenmann, Brigitte</creatorcontrib><creatorcontrib>Engelhardt, Holger</creatorcontrib><creatorcontrib>Rößler, Ute</creatorcontrib><title>Dimere und polymere Pnictidostannat(IV)-Anionen -Darstellung und Kristallstrukturen von Na2K3[SnP3], Na2Cs3[SnP3] und Na2K3[SnBi3] / Dimeric and Polymeric Pnictidostannate(IV) Anions -Preparation and Crystal Structures of Na2K3[SnP3], Na2Cs3[SnP3] and Na2K3[SnBi3]</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>The metallic lustrous compounds Na
[SnP
], Na
Cs
[SnP
], and Na
[SnBi
] were prepared from melts of mixtures of the elements. The isotypic compounds Na
[SnP
] and Na
Cs
[SnP
] crystallize in the orthorhombic system, space group Cmca (No 64), Z = 8, with lattice constants a = 1996.1 (4)/2047.9(4) pm, b = 669.5(1)/686.5(2) pm, c = 1494.5(2)/1617.8(3) pm. The structure is characterized by dimeric units [Sn
]
of edge-sharing [SnP
] tetrahedra, which are coordinated by the alkali cations. Na
[SnBi
] crystallizes in the orthorhombic system, space group Ibca (No 73), Z = 8, with lattice constants a = 718.2(1) pm , b -1692.6(2) pm, c = 2159.5(2) pm. In the anionic partial structure [SnBi
] tetrahedra are connected via common corners to infinite
[SnBi
Zweier single chains. The sodium and potassium cat ions separate the chains from each other. Neglecting the distortions caused by covalent bonding and different radii both structure types can be classified as superstructure defect variants of the Li
Bi structure. Different orderings in the occupation of the tetrahedral voids lead to the variants in the anionic assemblies.</description><subject>Dimeric Tetrahedral Anions</subject><subject>Disodium Tricesium Triphosphidostannate( IV)</subject><subject>Disodium Tripotassium Tribismutidostannate(IV)</subject><subject>Disodium Tripotassium Triphosphidostannate(IV)</subject><subject>Zweier Single Chains</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1998</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNp9kb1PwzAQxQMCqaUwsnsECVN_1HEiptLyUbWCSgUWhCLbcaqU4FR2Aip_PU4oSwemu-e7d_5JLwhOMbrEDLP-t5EQx3EE0QCR_aCLo5BBjjE_CLoopgQizsNOcOTcCiEcDwaou9cZ5x_aalCbFKzLYtOKuclVlaelq4QxojqbvJzDoclLow2AY2FdpYuiNsvWNbW53ysKV9n6vaqt3_ksDXgQZEpfF2ZO3y4aMXJb1Zr-pte5f-iDFiJXQPjR_JfCqx0M3XCAlsMBOLd6LayovGptI7tpMMDCY6gGw4Ey-4dC7FAcB4eZKJw-2dZe8Hx78zS6h7PHu8loOIMrjCMGNYsUZ0JIGmYqy5DgkkmVxpwTKQnlLKKEyDTGFCsREhlFYqAVlmGW4UwRRnvB1e_dL1FU2qZ6aeuNb5JVWVvjf04wSpo4Ex9n0sSZNHEy6uNi9AeppJa-</recordid><startdate>19980401</startdate><enddate>19980401</enddate><creator>Asbrand, Matthias</creator><creator>Eisenmann, Brigitte</creator><creator>Engelhardt, Holger</creator><creator>Rößler, Ute</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope/></search><sort><creationdate>19980401</creationdate><title>Dimere und polymere Pnictidostannat(IV)-Anionen -Darstellung und Kristallstrukturen von Na2K3[SnP3], Na2Cs3[SnP3] und Na2K3[SnBi3] / Dimeric and Polymeric Pnictidostannate(IV) Anions -Preparation and Crystal Structures of Na2K3[SnP3], Na2Cs3[SnP3] and Na2K3[SnBi3]</title><author>Asbrand, Matthias ; Eisenmann, Brigitte ; Engelhardt, Holger ; Rößler, Ute</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j1185-e58c75aab36fcff0a7b5bcd9772bb23758322bd9131ca62b88a4ec1b6ff1fc253</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>1998</creationdate><topic>Dimeric Tetrahedral Anions</topic><topic>Disodium Tricesium Triphosphidostannate( IV)</topic><topic>Disodium Tripotassium Tribismutidostannate(IV)</topic><topic>Disodium Tripotassium Triphosphidostannate(IV)</topic><topic>Zweier Single Chains</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Asbrand, Matthias</creatorcontrib><creatorcontrib>Eisenmann, Brigitte</creatorcontrib><creatorcontrib>Engelhardt, Holger</creatorcontrib><creatorcontrib>Rößler, Ute</creatorcontrib><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Asbrand, Matthias</au><au>Eisenmann, Brigitte</au><au>Engelhardt, Holger</au><au>Rößler, Ute</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dimere und polymere Pnictidostannat(IV)-Anionen -Darstellung und Kristallstrukturen von Na2K3[SnP3], Na2Cs3[SnP3] und Na2K3[SnBi3] / Dimeric and Polymeric Pnictidostannate(IV) Anions -Preparation and Crystal Structures of Na2K3[SnP3], Na2Cs3[SnP3] and Na2K3[SnBi3]</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1998-04-01</date><risdate>1998</risdate><volume>53</volume><issue>4</issue><spage>405</spage><epage>410</epage><pages>405-410</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>The metallic lustrous compounds Na
[SnP
], Na
Cs
[SnP
], and Na
[SnBi
] were prepared from melts of mixtures of the elements. The isotypic compounds Na
[SnP
] and Na
Cs
[SnP
] crystallize in the orthorhombic system, space group Cmca (No 64), Z = 8, with lattice constants a = 1996.1 (4)/2047.9(4) pm, b = 669.5(1)/686.5(2) pm, c = 1494.5(2)/1617.8(3) pm. The structure is characterized by dimeric units [Sn
]
of edge-sharing [SnP
] tetrahedra, which are coordinated by the alkali cations. Na
[SnBi
] crystallizes in the orthorhombic system, space group Ibca (No 73), Z = 8, with lattice constants a = 718.2(1) pm , b -1692.6(2) pm, c = 2159.5(2) pm. In the anionic partial structure [SnBi
] tetrahedra are connected via common corners to infinite
[SnBi
Zweier single chains. The sodium and potassium cat ions separate the chains from each other. Neglecting the distortions caused by covalent bonding and different radii both structure types can be classified as superstructure defect variants of the Li
Bi structure. Different orderings in the occupation of the tetrahedral voids lead to the variants in the anionic assemblies.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1998-0402</doi><tpages>6</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1998-04, Vol.53 (4), p.405-410 |
| issn | 0932-0776 1865-7117 |
| language | eng ; jpn |
| recordid | cdi_walterdegruyter_journals_10_1515_znb_1998_0402534405 |
| source | Alma/SFX Local Collection |
| subjects | Dimeric Tetrahedral Anions Disodium Tricesium Triphosphidostannate( IV) Disodium Tripotassium Tribismutidostannate(IV) Disodium Tripotassium Triphosphidostannate(IV) Zweier Single Chains |
| title | Dimere und polymere Pnictidostannat(IV)-Anionen -Darstellung und Kristallstrukturen von Na2K3[SnP3], Na2Cs3[SnP3] und Na2K3[SnBi3] / Dimeric and Polymeric Pnictidostannate(IV) Anions -Preparation and Crystal Structures of Na2K3[SnP3], Na2Cs3[SnP3] and Na2K3[SnBi3] |
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