Funktionalisierte 1,1-Ethendithiolate als Liganden, II / Functionalized 1,1-Ethene Dithiolates as Ligands, II

Funktionalisierte 1,1-Ethendithiolate als Liganden, II / Functionalized 1,1-Ethene Dithiolates as Ligands, II

para-Substituted β-ketodithiocinnamic acid dianions react with L MCl [M = Ni, L = PBu ; M = Pd, L = PPh ; M = Pt, L = PEt , PBu , PPh Tol, 1/2 dppe, 1/2 2,9-dimethyl-1,10-phenanthroline (dmphen)] to give the 1,1-ethene dithiolate complexes L M[S C=CH-C(O)-C p-OC ] (3: M = Ni, L = PBu , n = 12; 4a, b...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1993-08, Vol.48 (8), p.1080-1088
Hauptverfasser: Weigand, Wolfgang, Saumweber, Rupert, Schulz, Peter
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container_end_page 1088
container_issue 8
container_start_page 1080
container_title Zeitschrift für Naturforschung. B, A journal of chemical sciences
container_volume 48
creator Weigand, Wolfgang
Saumweber, Rupert
Schulz, Peter
description para-Substituted β-ketodithiocinnamic acid dianions react with L MCl [M = Ni, L = PBu ; M = Pd, L = PPh ; M = Pt, L = PEt , PBu , PPh Tol, 1/2 dppe, 1/2 2,9-dimethyl-1,10-phenanthroline (dmphen)] to give the 1,1-ethene dithiolate complexes L M[S C=CH-C(O)-C p-OC ] (3: M = Ni, L = PBu , n = 12; 4a, b: M = Pd, L = PPh , n = 1,8; 5a: M = Pt, L = PEt , n = 1; 5b, 5e-g; 5i: M = Pt, L = PPh , n = 1,8,10,12,14; 5c, h: M = Pt, L = 1/2 dppe, n = 1,12; 5j: M = Pt, L = PPh Tol, n = 12; 6 a-c M = Pt, L = 1/2 dmphen, n = 8, 12, 16); L Pt[S C=CH-C(O)-C -p-C ] (7 a, b: L = PPh , 1/2 dmphen), (Ph P) Pt[S C=CH-C(O)-C -p-C ] (8) and L M[S C=CH-C(O)-C S] (9a: M = Pd, L = PPh ; 9b: M = Pt, L = PEt ; 9c: M = Pt, L = PPh , 9d: M = Pt, L = 1/2 dppe). These compounds have been characterized by their UV, IR, H, C and P NMR spectra.
doi_str_mv 10.1515/znb-1993-0809
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B, A journal of chemical sciences</title><description>para-Substituted β-ketodithiocinnamic acid dianions react with L MCl [M = Ni, L = PBu ; M = Pd, L = PPh ; M = Pt, L = PEt , PBu , PPh Tol, 1/2 dppe, 1/2 2,9-dimethyl-1,10-phenanthroline (dmphen)] to give the 1,1-ethene dithiolate complexes L M[S C=CH-C(O)-C p-OC ] (3: M = Ni, L = PBu , n = 12; 4a, b: M = Pd, L = PPh , n = 1,8; 5a: M = Pt, L = PEt , n = 1; 5b, 5e-g; 5i: M = Pt, L = PPh , n = 1,8,10,12,14; 5c, h: M = Pt, L = 1/2 dppe, n = 1,12; 5j: M = Pt, L = PPh Tol, n = 12; 6 a-c M = Pt, L = 1/2 dmphen, n = 8, 12, 16); L Pt[S C=CH-C(O)-C -p-C ] (7 a, b: L = PPh , 1/2 dmphen), (Ph P) Pt[S C=CH-C(O)-C -p-C ] (8) and L M[S C=CH-C(O)-C S] (9a: M = Pd, L = PPh ; 9b: M = Pt, L = PEt ; 9c: M = Pt, L = PPh , 9d: M = Pt, L = 1/2 dppe). 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B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Weigand, Wolfgang</au><au>Saumweber, Rupert</au><au>Schulz, Peter</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Funktionalisierte 1,1-Ethendithiolate als Liganden, II / Functionalized 1,1-Ethene Dithiolates as Ligands, II</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1993-08-01</date><risdate>1993</risdate><volume>48</volume><issue>8</issue><spage>1080</spage><epage>1088</epage><pages>1080-1088</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>para-Substituted β-ketodithiocinnamic acid dianions react with L MCl [M = Ni, L = PBu ; M = Pd, L = PPh ; M = Pt, L = PEt , PBu , PPh Tol, 1/2 dppe, 1/2 2,9-dimethyl-1,10-phenanthroline (dmphen)] to give the 1,1-ethene dithiolate complexes L M[S C=CH-C(O)-C p-OC ] (3: M = Ni, L = PBu , n = 12; 4a, b: M = Pd, L = PPh , n = 1,8; 5a: M = Pt, L = PEt , n = 1; 5b, 5e-g; 5i: M = Pt, L = PPh , n = 1,8,10,12,14; 5c, h: M = Pt, L = 1/2 dppe, n = 1,12; 5j: M = Pt, L = PPh Tol, n = 12; 6 a-c M = Pt, L = 1/2 dmphen, n = 8, 12, 16); L Pt[S C=CH-C(O)-C -p-C ] (7 a, b: L = PPh , 1/2 dmphen), (Ph P) Pt[S C=CH-C(O)-C -p-C ] (8) and L M[S C=CH-C(O)-C S] (9a: M = Pd, L = PPh ; 9b: M = Pt, L = PEt ; 9c: M = Pt, L = PPh , 9d: M = Pt, L = 1/2 dppe). These compounds have been characterized by their UV, IR, H, C and P NMR spectra.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1993-0809</doi><tpages>9</tpages><oa>free_for_read</oa></addata></record>
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title Funktionalisierte 1,1-Ethendithiolate als Liganden, II / Functionalized 1,1-Ethene Dithiolates as Ligands, II
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