Tetraphospholan-Bildung via Phosphaalken durch LiSnPh3-katalysierte PhP-Übertragung / Formation of a Tetraphospholane via Phosphaalkene by LiSnPh3-Catalyzed Transfer of PhP Units

Tetraphospholan-Bildung via Phosphaalken durch LiSnPh3-katalysierte PhP-Übertragung / Formation of a Tetraphospholane via Phosphaalkene by LiSnPh3-Catalyzed Transfer of PhP Units

Lithium triphenylsilyl-phenylphosphide (3), X = SiPh , reacts with ketones to give tetraphenyl-phospholanes (6). In an initial step a phosphaalkene 5 is formed, which then adds three more phenylphosphinidene units. This second step can be performed independently, and the PhP units can be furnished b...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1988-11, Vol.43 (11), p.1475-1477
Hauptverfasser: Zirzow, Karl-Heinz, Schmidpeter, Alfred
Format: Artikel
Sprache:eng
Schlagworte:
Phosphorus Heterocycles
Reversible Nucleophilic Degradation
Silyl-and Stannylphosphides Phosphaalkenes
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container_title Zeitschrift für Naturforschung. B, A journal of chemical sciences
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creator Zirzow, Karl-Heinz
Schmidpeter, Alfred
description Lithium triphenylsilyl-phenylphosphide (3), X = SiPh , reacts with ketones to give tetraphenyl-phospholanes (6). In an initial step a phosphaalkene 5 is formed, which then adds three more phenylphosphinidene units. This second step can be performed independently, and the PhP units can be furnished by pentaphenylcyclopentaphosphane (1) if the reaction is catalyzed by lithium triphenylstannide (2), X = SnPh
doi_str_mv 10.1515/znb-1988-1113
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This second step can be performed independently, and the PhP units can be furnished by pentaphenylcyclopentaphosphane (1) if the reaction is catalyzed by lithium triphenylstannide (2), X = SnPh</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1988-1113</doi><tpages>3</tpages><oa>free_for_read</oa></addata></record>
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1865-7117
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source Alma/SFX Local Collection
subjects Phosphorus Heterocycles
Reversible Nucleophilic Degradation
Silyl-and Stannylphosphides Phosphaalkenes
title Tetraphospholan-Bildung via Phosphaalken durch LiSnPh3-katalysierte PhP-Übertragung / Formation of a Tetraphospholane via Phosphaalkene by LiSnPh3-Catalyzed Transfer of PhP Units
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