Darstellung, Charakterisierung und Röntgenstrukturanalyse von η5 -Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, CpRe(CO)(SMe)2 / Preparation, Characterization and X-Ray Structure Analysis of η5-Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, CpRe(CO)(SMe)2
Reaction of the tetrahydrofuran-stabilized 16-electron complex fragment [Cp*Re(CO) ] with dimethyl disulfide, MeSSMe, leads to the diamagnetic title compound, Cp*Re(CO)(SMe) , which was characterized by mass, IR and NMR spectra and by an X-ray crystal structure analysis**. The two methylsulfido liga...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1987-06, Vol.42 (6), p.739-745 |
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| container_end_page | 745 |
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| container_issue | 6 |
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| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 42 |
| creator | Herberhold, Max Schmidkonz, Bertram Ziegler, Manfred L. Serhadle, Orhan |
| description | Reaction of the tetrahydrofuran-stabilized 16-electron complex fragment [Cp*Re(CO)
] with dimethyl disulfide, MeSSMe, leads to the diamagnetic title compound, Cp*Re(CO)(SMe)
, which was characterized by mass, IR and NMR spectra and by an X-ray crystal structure analysis**. The two methylsulfido ligands are bent (angles Re-S-CH
114.1(3)°) and turned away from the Cp* ring. The Re - S-bond distances are 227.0(2) pm. |
| doi_str_mv | 10.1515/znb-1987-0616 |
| format | Article |
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114.1(3)°) and turned away from the Cp* ring. The Re - S-bond distances are 227.0(2) pm.</description><subject>Cleavage of Dimethyl Disulfide</subject><subject>Methylsulfido Complexes</subject><subject>Pentamethylcyclopentadienyl Rhenium Complexes</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1987</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNqt0c1O4zAQB_CAQKIUjtwtcWklDHY-7FqcUGHZlboCFQ7cIseetAHjVHYMCg_GPgD3faZ1gEfYk8czkv0b_ZPkiJJTWtDi7M1WmIoZx4RRtp2M6IwVmFPKd5IREVmKCedsL9n3_pEQKvKcjLaOL6XzHRgT7OoEzdfSyacOXOMbcLGFgtVo-fFuuxVY37nw1AUnrTS9B_TSWvT3T4HwLdhOPkO37o3qlWk3w103YHuDq8ZPvkY-mLrR7VRJV7Vx5NZgm_Acf90sYTK_mU7ufsM0RWfo1sEmQrqmtd8mNZjePjtIRtIDXsoe3UWQiiBAF5-kxqO2Hkj_V3SQ7NbSeDj8PsfJ_Y-r-_lPvLi5_jW_WOAgqMCsJmrGcgFAUqF4pqCiUqdM8FowJUABVTmrVcYKTfKMEs1TXRdFWslC50xn4-T869lXaeK6GlYu9LEoH9vg4n6-pKQcgi5j0OUQdDkEnaeMZyL7B3k-qVk</recordid><startdate>19870601</startdate><enddate>19870601</enddate><creator>Herberhold, Max</creator><creator>Schmidkonz, Bertram</creator><creator>Ziegler, Manfred L.</creator><creator>Serhadle, Orhan</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope/></search><sort><creationdate>19870601</creationdate><title>Darstellung, Charakterisierung und Röntgenstrukturanalyse von η5 -Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, CpRe(CO)(SMe)2 / Preparation, Characterization and X-Ray Structure Analysis of η5-Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, CpRe(CO)(SMe)2</title><author>Herberhold, Max ; Schmidkonz, Bertram ; Ziegler, Manfred L. ; Serhadle, Orhan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-u919-6f0c8649ee029c73ceb1ad2697f96c9ece1c46fc365d04310d72df552ba5d46d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>1987</creationdate><topic>Cleavage of Dimethyl Disulfide</topic><topic>Methylsulfido Complexes</topic><topic>Pentamethylcyclopentadienyl Rhenium Complexes</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Herberhold, Max</creatorcontrib><creatorcontrib>Schmidkonz, Bertram</creatorcontrib><creatorcontrib>Ziegler, Manfred L.</creatorcontrib><creatorcontrib>Serhadle, Orhan</creatorcontrib><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Herberhold, Max</au><au>Schmidkonz, Bertram</au><au>Ziegler, Manfred L.</au><au>Serhadle, Orhan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Darstellung, Charakterisierung und Röntgenstrukturanalyse von η5 -Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, CpRe(CO)(SMe)2 / Preparation, Characterization and X-Ray Structure Analysis of η5-Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, CpRe(CO)(SMe)2</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1987-06-01</date><risdate>1987</risdate><volume>42</volume><issue>6</issue><spage>739</spage><epage>745</epage><pages>739-745</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>Reaction of the tetrahydrofuran-stabilized 16-electron complex fragment [Cp*Re(CO)
] with dimethyl disulfide, MeSSMe, leads to the diamagnetic title compound, Cp*Re(CO)(SMe)
, which was characterized by mass, IR and NMR spectra and by an X-ray crystal structure analysis**. The two methylsulfido ligands are bent (angles Re-S-CH
114.1(3)°) and turned away from the Cp* ring. The Re - S-bond distances are 227.0(2) pm.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1987-0616</doi><tpages>7</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1987-06, Vol.42 (6), p.739-745 |
| issn | 0932-0776 1865-7117 |
| language | eng |
| recordid | cdi_walterdegruyter_journals_10_1515_znb_1987_0616426739 |
| source | Alma/SFX Local Collection |
| subjects | Cleavage of Dimethyl Disulfide Methylsulfido Complexes Pentamethylcyclopentadienyl Rhenium Complexes |
| title | Darstellung, Charakterisierung und Röntgenstrukturanalyse von η5 -Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, CpRe(CO)(SMe)2 / Preparation, Characterization and X-Ray Structure Analysis of η5-Pentamethylcyclopentadienyl-bis(methylsulfido)carbonylrhenium, CpRe(CO)(SMe)2 |
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