Die Alkoholyse von 3.5-Difluor-1.1.3.5-tetraoxo-2-alkyl-1λ6.3λ6.5λ6.2.4.6- trithiatriazin / The Alcoholysis Reaction of 3,5-Difluoro-l,l,3,5-tetraoxo-2-alkyl-1λ6,3λ6,5λ6,2,4,6-trithiatriazin
(NSOF) (CH NSO ) 2a reacts with methanol to give sulfuric acid, aminosulfuric acid and SO (NHCH as final products. The primary reaction was studied by H and F NMR spectroscopy. A 1:1 adduct 2a · CH OH (=3) and a monosubstituted product which has the formula (NSOF)(NSOOCH )(CH NSO were detected to be...
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| Veröffentlicht in: | Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1978-03, Vol.33 (3), p.300-304 |
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| Sprache: | eng ; jpn |
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| container_issue | 3 |
| container_start_page | 300 |
| container_title | Zeitschrift für Naturforschung. B, A journal of chemical sciences |
| container_volume | 33 |
| creator | Wagner, Diec-Lang Wagner, Hartmut Glemser, Oskar |
| description | (NSOF)
(CH
NSO
) 2a reacts with methanol to give sulfuric acid, aminosulfuric acid and SO
(NHCH
as final products. The primary reaction was studied by
H and
F NMR spectroscopy. A 1:1 adduct 2a · CH
OH (=3) and a monosubstituted product which has the formula (NSOF)(NSOOCH
)(CH
NSO
were detected to be intermediates.
As 2 a is chiral, the reaction with racemic butanol-2 proceeds via diastereomeric inter-mediates which were identified by their
F NMR spectrum.
The reaction pattern of 2a is explained. |
| doi_str_mv | 10.1515/znb-1978-0310 |
| format | Article |
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(CH
NSO
) 2a reacts with methanol to give sulfuric acid, aminosulfuric acid and SO
(NHCH
as final products. The primary reaction was studied by
H and
F NMR spectroscopy. A 1:1 adduct 2a · CH
OH (=3) and a monosubstituted product which has the formula (NSOF)(NSOOCH
)(CH
NSO
were detected to be intermediates.
As 2 a is chiral, the reaction with racemic butanol-2 proceeds via diastereomeric inter-mediates which were identified by their
F NMR spectrum.
The reaction pattern of 2a is explained.</description><identifier>ISSN: 0932-0776</identifier><identifier>EISSN: 1865-7117</identifier><identifier>DOI: 10.1515/znb-1978-0310</identifier><language>eng ; jpn</language><publisher>Verlag der Zeitschrift für Naturforschung</publisher><subject>19F NMR ; Alcoholysis ; Reaction Mechanism ; Trithiatriazine</subject><ispartof>Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1978-03, Vol.33 (3), p.300-304</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,776,780,27903,27904</link.rule.ids></links><search><creatorcontrib>Wagner, Diec-Lang</creatorcontrib><creatorcontrib>Wagner, Hartmut</creatorcontrib><creatorcontrib>Glemser, Oskar</creatorcontrib><title>Die Alkoholyse von 3.5-Difluor-1.1.3.5-tetraoxo-2-alkyl-1λ6.3λ6.5λ6.2.4.6- trithiatriazin / The Alcoholysis Reaction of 3,5-Difluoro-l,l,3,5-tetraoxo-2-alkyl-1λ6,3λ6,5λ6,2,4,6-trithiatriazin</title><title>Zeitschrift für Naturforschung. B, A journal of chemical sciences</title><description>(NSOF)
(CH
NSO
) 2a reacts with methanol to give sulfuric acid, aminosulfuric acid and SO
(NHCH
as final products. The primary reaction was studied by
H and
F NMR spectroscopy. A 1:1 adduct 2a · CH
OH (=3) and a monosubstituted product which has the formula (NSOF)(NSOOCH
)(CH
NSO
were detected to be intermediates.
As 2 a is chiral, the reaction with racemic butanol-2 proceeds via diastereomeric inter-mediates which were identified by their
F NMR spectrum.
The reaction pattern of 2a is explained.</description><subject>19F NMR</subject><subject>Alcoholysis</subject><subject>Reaction Mechanism</subject><subject>Trithiatriazine</subject><issn>0932-0776</issn><issn>1865-7117</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>1978</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNptkctKAzEUhoMoWKtL93mAZHrOZJJMcFVabyAIUtfDXDJ22tDAzFRtX82ta5_JCRVB8Cz-c1n8H5yfkEuECCXKyX5TcDQ65SAQjsgIUyW5RtTHZARGxBy0VqfkrOtWAGiSBEbkc95YOnVrv_Ru11n66jdURJLPm9ptfcsxwijsve3b3L97HvPcrXeO49eHikQQGSSOkkhx2rdNv2zyoeX7ZkMndLEM9uXBvunok83LvhkgvqaC_XI8d8yxcPgXxAKIBRCLWcIU_8s5Jyd17jp78dPH5PnmejG74w-Pt_ez6QNfodTAqyIFUFKnsSrqWFkpoYwtQmWHxxQGpBAGraqwUqooSyNVbUxhtaqTWKs0F2NydfB9y11v28q-tNvdMGQrv203AzlDyEIU2RBFFqLIQhRiKADxDZHNfxc</recordid><startdate>19780301</startdate><enddate>19780301</enddate><creator>Wagner, Diec-Lang</creator><creator>Wagner, Hartmut</creator><creator>Glemser, Oskar</creator><general>Verlag der Zeitschrift für Naturforschung</general><scope/></search><sort><creationdate>19780301</creationdate><title>Die Alkoholyse von 3.5-Difluor-1.1.3.5-tetraoxo-2-alkyl-1λ6.3λ6.5λ6.2.4.6- trithiatriazin / The Alcoholysis Reaction of 3,5-Difluoro-l,l,3,5-tetraoxo-2-alkyl-1λ6,3λ6,5λ6,2,4,6-trithiatriazin</title><author>Wagner, Diec-Lang ; Wagner, Hartmut ; Glemser, Oskar</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-j1570-db800657826bf26e550c2e10de077b9053391e6d1d66bcc956f99be76f42768a3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng ; jpn</language><creationdate>1978</creationdate><topic>19F NMR</topic><topic>Alcoholysis</topic><topic>Reaction Mechanism</topic><topic>Trithiatriazine</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wagner, Diec-Lang</creatorcontrib><creatorcontrib>Wagner, Hartmut</creatorcontrib><creatorcontrib>Glemser, Oskar</creatorcontrib><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wagner, Diec-Lang</au><au>Wagner, Hartmut</au><au>Glemser, Oskar</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Die Alkoholyse von 3.5-Difluor-1.1.3.5-tetraoxo-2-alkyl-1λ6.3λ6.5λ6.2.4.6- trithiatriazin / The Alcoholysis Reaction of 3,5-Difluoro-l,l,3,5-tetraoxo-2-alkyl-1λ6,3λ6,5λ6,2,4,6-trithiatriazin</atitle><jtitle>Zeitschrift für Naturforschung. B, A journal of chemical sciences</jtitle><date>1978-03-01</date><risdate>1978</risdate><volume>33</volume><issue>3</issue><spage>300</spage><epage>304</epage><pages>300-304</pages><issn>0932-0776</issn><eissn>1865-7117</eissn><abstract>(NSOF)
(CH
NSO
) 2a reacts with methanol to give sulfuric acid, aminosulfuric acid and SO
(NHCH
as final products. The primary reaction was studied by
H and
F NMR spectroscopy. A 1:1 adduct 2a · CH
OH (=3) and a monosubstituted product which has the formula (NSOF)(NSOOCH
)(CH
NSO
were detected to be intermediates.
As 2 a is chiral, the reaction with racemic butanol-2 proceeds via diastereomeric inter-mediates which were identified by their
F NMR spectrum.
The reaction pattern of 2a is explained.</abstract><pub>Verlag der Zeitschrift für Naturforschung</pub><doi>10.1515/znb-1978-0310</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0932-0776 |
| ispartof | Zeitschrift für Naturforschung. B, A journal of chemical sciences, 1978-03, Vol.33 (3), p.300-304 |
| issn | 0932-0776 1865-7117 |
| language | eng ; jpn |
| recordid | cdi_walterdegruyter_journals_10_1515_znb_1978_0310333300 |
| source | Alma/SFX Local Collection |
| subjects | 19F NMR Alcoholysis Reaction Mechanism Trithiatriazine |
| title | Die Alkoholyse von 3.5-Difluor-1.1.3.5-tetraoxo-2-alkyl-1λ6.3λ6.5λ6.2.4.6- trithiatriazin / The Alcoholysis Reaction of 3,5-Difluoro-l,l,3,5-tetraoxo-2-alkyl-1λ6,3λ6,5λ6,2,4,6-trithiatriazin |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-26T03%3A12%3A58IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-walterdegruyter&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Die%20Alkoholyse%20von%203.5-Difluor-1.1.3.5-tetraoxo-2-alkyl-1%CE%BB6.3%CE%BB6.5%CE%BB6.2.4.6-%20trithiatriazin%20/%20The%20Alcoholysis%20Reaction%20of%203,5-Difluoro-l,l,3,5-tetraoxo-2-alkyl-1%CE%BB6,3%CE%BB6,5%CE%BB6,2,4,6-trithiatriazin&rft.jtitle=Zeitschrift%20f%C3%BCr%20Naturforschung.%20B,%20A%20journal%20of%20chemical%20sciences&rft.au=Wagner,%20Diec-Lang&rft.date=1978-03-01&rft.volume=33&rft.issue=3&rft.spage=300&rft.epage=304&rft.pages=300-304&rft.issn=0932-0776&rft.eissn=1865-7117&rft_id=info:doi/10.1515/znb-1978-0310&rft_dat=%3Cwalterdegruyter%3E10_1515_znb_1978_0310333300%3C/walterdegruyter%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true |