Inhibiting the formation of TCA in a Bayer causticisation process

Inhibiting the formation of TCA in a Bayer causticisation process

An improved process for the causticisation of Bayer liquors in an alumina refinery, the process including the steps of reacting lime with aluminate ions in a Bayer liquor within a primary reactor under controlled conditions of low to moderate temperature (between 70-80° C.) and agitation, to form su...

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Hauptverfasser: Rosenberg, Steven Philip, Wilson, Darrel James, Heath, Catherine Ann
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creator Rosenberg, Steven Philip
Wilson, Darrel James
Heath, Catherine Ann
description An improved process for the causticisation of Bayer liquors in an alumina refinery, the process including the steps of reacting lime with aluminate ions in a Bayer liquor within a primary reactor under controlled conditions of low to moderate temperature (between 70-80° C.) and agitation, to form substantially only a hydrocalumite species and hydroxyl ions; and a secondary reactor wherein the hydrocalumite species formed is subjected to heating in contact with a Bayer liquor under controlled conditions so as to cause the hydrocalumite species to react with the liquor to form calcium carbonate, aluminate ions and hydroxyl ions, whereby a causticised Bayer liquor is obtained and wherein the efficiency of lime utilization is substantially increased and/or alumina losses are minimized.
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and a secondary reactor wherein the hydrocalumite species formed is subjected to heating in contact with a Bayer liquor under controlled conditions so as to cause the hydrocalumite species to react with the liquor to form calcium carbonate, aluminate ions and hydroxyl ions, whereby a causticised Bayer liquor is obtained and wherein the efficiency of lime utilization is substantially increased and/or alumina losses are minimized.</description><language>eng</language><creationdate>2010</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7767190$$EPDF$$P50$$Guspatents$$Hfree_for_read</linktopdf><link.rule.ids>230,308,780,802,885,64038</link.rule.ids><linktorsrc>$$Uhttps://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/7767190$$EView_record_in_USPTO$$FView_record_in_$$GUSPTO$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Rosenberg, Steven Philip</creatorcontrib><creatorcontrib>Wilson, Darrel James</creatorcontrib><creatorcontrib>Heath, Catherine Ann</creatorcontrib><creatorcontrib>BHP Billiton Worsley Alumina PTY Ltd</creatorcontrib><title>Inhibiting the formation of TCA in a Bayer causticisation process</title><description>An improved process for the causticisation of Bayer liquors in an alumina refinery, the process including the steps of reacting lime with aluminate ions in a Bayer liquor within a primary reactor under controlled conditions of low to moderate temperature (between 70-80° C.) and agitation, to form substantially only a hydrocalumite species and hydroxyl ions; 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title Inhibiting the formation of TCA in a Bayer causticisation process
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