Process for preparing a Ziegler-Natta catalyst
This invention relates to a new process for preparing a Ziegler-Natta catalyst and in particular to a simple solution phase process which can be carried out in one reaction vessel. Especially homogeneous supported Ziegler-Natta catalysts may be prepared in a simple one reaction vessel process from a...
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creator | Garoff, Thomas Johansson, Solveig Waldvogel, Paivi |
description | This invention relates to a new process for preparing a Ziegler-Natta catalyst and in particular to a simple solution phase process which can be carried out in one reaction vessel.
Especially homogeneous supported Ziegler-Natta catalysts may be prepared in a simple one reaction vessel process from a magnesium hydrocarbyloxy starting material which is soluble in a hydrocarbon solvent. The process comprises: (I) reacting a magnesium hydrocarbyloxy compound with a chlorine-containing compound in a non-polar hydrocarbon solvent in which said magnesium hydrocarbyloxy compound is soluble whereby to produce a solution (A); and then either: (II) contacting the solution (A) with a chlorine containing tetravalent titanium compound to produce a solution (B); (III) impregnating solution (B) into a porous particulate support; or (II) impregnating solution (A) into a porous particulate support; and (III) contacting the solid support with a chlorine containing tetravalent titanium compound; or (II) impregnating solution (A) into a porous particulate support pretreated with a chlorine containing tetravalent titanium compound. |
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Especially homogeneous supported Ziegler-Natta catalysts may be prepared in a simple one reaction vessel process from a magnesium hydrocarbyloxy starting material which is soluble in a hydrocarbon solvent. The process comprises: (I) reacting a magnesium hydrocarbyloxy compound with a chlorine-containing compound in a non-polar hydrocarbon solvent in which said magnesium hydrocarbyloxy compound is soluble whereby to produce a solution (A); and then either: (II) contacting the solution (A) with a chlorine containing tetravalent titanium compound to produce a solution (B); (III) impregnating solution (B) into a porous particulate support; or (II) impregnating solution (A) into a porous particulate support; and (III) contacting the solid support with a chlorine containing tetravalent titanium compound; or (II) impregnating solution (A) into a porous particulate support pretreated with a chlorine containing tetravalent titanium compound.</description><language>eng</language><creationdate>2004</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6818584$$EPDF$$P50$$Guspatents$$Hfree_for_read</linktopdf><link.rule.ids>230,308,777,799,882,64018</link.rule.ids><linktorsrc>$$Uhttps://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/6818584$$EView_record_in_USPTO$$FView_record_in_$$GUSPTO$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Garoff, Thomas</creatorcontrib><creatorcontrib>Johansson, Solveig</creatorcontrib><creatorcontrib>Waldvogel, Paivi</creatorcontrib><creatorcontrib>Borealis Technology OY</creatorcontrib><title>Process for preparing a Ziegler-Natta catalyst</title><description>This invention relates to a new process for preparing a Ziegler-Natta catalyst and in particular to a simple solution phase process which can be carried out in one reaction vessel.
Especially homogeneous supported Ziegler-Natta catalysts may be prepared in a simple one reaction vessel process from a magnesium hydrocarbyloxy starting material which is soluble in a hydrocarbon solvent. The process comprises: (I) reacting a magnesium hydrocarbyloxy compound with a chlorine-containing compound in a non-polar hydrocarbon solvent in which said magnesium hydrocarbyloxy compound is soluble whereby to produce a solution (A); and then either: (II) contacting the solution (A) with a chlorine containing tetravalent titanium compound to produce a solution (B); (III) impregnating solution (B) into a porous particulate support; or (II) impregnating solution (A) into a porous particulate support; and (III) contacting the solid support with a chlorine containing tetravalent titanium compound; or (II) impregnating solution (A) into a porous particulate support pretreated with a chlorine containing tetravalent titanium compound.</description><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2004</creationdate><recordtype>patent</recordtype><sourceid>EFH</sourceid><recordid>eNrjZNALKMpPTi0uVkjLL1IoKEotSCzKzEtXSFSIykxNz0kt0vVLLClJVEhOLEnMqSwu4WFgTUvMKU7lhdLcDApuriHOHrqlxQWJJal5JcXx6UWJIMrAzMLQwtTCxJgIJQDBUSte</recordid><startdate>20041116</startdate><enddate>20041116</enddate><creator>Garoff, Thomas</creator><creator>Johansson, Solveig</creator><creator>Waldvogel, Paivi</creator><scope>EFH</scope></search><sort><creationdate>20041116</creationdate><title>Process for preparing a Ziegler-Natta catalyst</title><author>Garoff, Thomas ; Johansson, Solveig ; Waldvogel, Paivi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-uspatents_grants_068185843</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2004</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Garoff, Thomas</creatorcontrib><creatorcontrib>Johansson, Solveig</creatorcontrib><creatorcontrib>Waldvogel, Paivi</creatorcontrib><creatorcontrib>Borealis Technology OY</creatorcontrib><collection>USPTO Issued Patents</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Garoff, Thomas</au><au>Johansson, Solveig</au><au>Waldvogel, Paivi</au><aucorp>Borealis Technology OY</aucorp><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Process for preparing a Ziegler-Natta catalyst</title><date>2004-11-16</date><risdate>2004</risdate><abstract>This invention relates to a new process for preparing a Ziegler-Natta catalyst and in particular to a simple solution phase process which can be carried out in one reaction vessel.
Especially homogeneous supported Ziegler-Natta catalysts may be prepared in a simple one reaction vessel process from a magnesium hydrocarbyloxy starting material which is soluble in a hydrocarbon solvent. The process comprises: (I) reacting a magnesium hydrocarbyloxy compound with a chlorine-containing compound in a non-polar hydrocarbon solvent in which said magnesium hydrocarbyloxy compound is soluble whereby to produce a solution (A); and then either: (II) contacting the solution (A) with a chlorine containing tetravalent titanium compound to produce a solution (B); (III) impregnating solution (B) into a porous particulate support; or (II) impregnating solution (A) into a porous particulate support; and (III) contacting the solid support with a chlorine containing tetravalent titanium compound; or (II) impregnating solution (A) into a porous particulate support pretreated with a chlorine containing tetravalent titanium compound.</abstract><oa>free_for_read</oa></addata></record> |
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title | Process for preparing a Ziegler-Natta catalyst |
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