Process for preparing boronic and borinic acids

A process for preparing boronic acids of the formula (I) and borinic acids of the formula (II), 1 by reaction of chloroaromatics of the formula (III) with lithium metal and boron compounds BW′W′W′″, where W′, W′ and W′″ are each, independently of one another, C 1 -C 6 -alkoxy, fluorine, chlorine, br...

Ausführliche Beschreibung

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Bibliographische Detailangaben
Hauptverfasser: Meudt, Andreas, Erbes, Michael, Forstinger, Klaus
Format: Patent
Sprache:eng
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Zusammenfassung:A process for preparing boronic acids of the formula (I) and borinic acids of the formula (II), 1 by reaction of chloroaromatics of the formula (III) with lithium metal and boron compounds BW′W′W′″, where W′, W′ and W′″ are each, independently of one another, C 1 -C 6 -alkoxy, fluorine, chlorine, bromine, iodine, N(C 1 -C 6 -alkyl) 2 or S(C 1 -C 5 -alkyl), in a solvent at temperatures in the range from −100 to 80° C. 2