A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-Bu4NOCN

A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-Bu4NOCN

Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile. This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcoh...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Turkish journal of chemistry 2007, Vol.31 (1), p.35-43
Hauptverfasser: SAMIEI, Sima, AKHLAGHINIA, Batool
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 43
container_issue 1
container_start_page 35
container_title Turkish journal of chemistry
container_volume 31
creator SAMIEI, Sima
AKHLAGHINIA, Batool
description Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile. This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.
format Article
fullrecord <record><control><sourceid>ulakbim</sourceid><recordid>TN_cdi_ulakbim_primary_74390</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>74390</sourcerecordid><originalsourceid>FETCH-LOGICAL-s176t-a905f3e21b3bc80f6732baf6e6fb901e2d25d2a5811661a140e9fbdd2b6965e93</originalsourceid><addsrcrecordid>eNotj91KAzEQhRdRsFbfwIs8wAbzs5vtXtbiH5T2Rq9ESrI76camiWxSZX0ZX9VsFYY5h2HOB-ckm1BOOBZpnx49waRk1Xl2EcI7IbROM8l-5sjBF5KuRY13n-AMuIj2EDvfIq_RFhz0Mhq3RdLuBotM8M0gnYwQkO79Pp0b33kbchQ7c9QRFnszQgYbjE2pZKEP6BCOIMTyIhc4_TSd9b1HrzTnefk2puS3cXDj8O2hWK0Xq8vsTEsb4Opfp9nL_d3z4hEv1w9Pi_kSB1qJiGVNSs2BUcVVMyNaVJwpqQUIrVJRYC0rWybLGaVCUEkLArVWbcuUqEUJNZ9m13_cg5U7Zfabj1RA9sOmKnhN-C9NC2VN</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype></control><display><type>article</type><title>A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-Bu4NOCN</title><source>EZB-FREE-00999 freely available EZB journals</source><source>TÜBİTAK Scientific Journals</source><creator>SAMIEI, Sima ; AKHLAGHINIA, Batool</creator><creatorcontrib>SAMIEI, Sima ; AKHLAGHINIA, Batool</creatorcontrib><description>Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile. This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.</description><identifier>ISSN: 1300-0527</identifier><identifier>EISSN: 1303-6130</identifier><language>eng</language><publisher>TÜBİTAK</publisher><ispartof>Turkish journal of chemistry, 2007, Vol.31 (1), p.35-43</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,4024</link.rule.ids></links><search><creatorcontrib>SAMIEI, Sima</creatorcontrib><creatorcontrib>AKHLAGHINIA, Batool</creatorcontrib><title>A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-Bu4NOCN</title><title>Turkish journal of chemistry</title><description>Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile. This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.</description><issn>1300-0527</issn><issn>1303-6130</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2007</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNotj91KAzEQhRdRsFbfwIs8wAbzs5vtXtbiH5T2Rq9ESrI76camiWxSZX0ZX9VsFYY5h2HOB-ckm1BOOBZpnx49waRk1Xl2EcI7IbROM8l-5sjBF5KuRY13n-AMuIj2EDvfIq_RFhz0Mhq3RdLuBotM8M0gnYwQkO79Pp0b33kbchQ7c9QRFnszQgYbjE2pZKEP6BCOIMTyIhc4_TSd9b1HrzTnefk2puS3cXDj8O2hWK0Xq8vsTEsb4Opfp9nL_d3z4hEv1w9Pi_kSB1qJiGVNSs2BUcVVMyNaVJwpqQUIrVJRYC0rWybLGaVCUEkLArVWbcuUqEUJNZ9m13_cg5U7Zfabj1RA9sOmKnhN-C9NC2VN</recordid><startdate>2007</startdate><enddate>2007</enddate><creator>SAMIEI, Sima</creator><creator>AKHLAGHINIA, Batool</creator><general>TÜBİTAK</general><scope/></search><sort><creationdate>2007</creationdate><title>A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-Bu4NOCN</title><author>SAMIEI, Sima ; AKHLAGHINIA, Batool</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-s176t-a905f3e21b3bc80f6732baf6e6fb901e2d25d2a5811661a140e9fbdd2b6965e93</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2007</creationdate><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>SAMIEI, Sima</creatorcontrib><creatorcontrib>AKHLAGHINIA, Batool</creatorcontrib><jtitle>Turkish journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>SAMIEI, Sima</au><au>AKHLAGHINIA, Batool</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-Bu4NOCN</atitle><jtitle>Turkish journal of chemistry</jtitle><date>2007</date><risdate>2007</risdate><volume>31</volume><issue>1</issue><spage>35</spage><epage>43</epage><pages>35-43</pages><issn>1300-0527</issn><eissn>1303-6130</eissn><abstract>Alkyl isocyanates are prepared in good to excellent yields by treatment of alcohols, thiols, and trimethylsilyl ethers with 2,4,6-trichloro[l,3,5] triazine/n-Bu4NOCN in acetonitrile. This method is highly selective for conversion of 1° alcohols to alkyl isocyanates in the presence of 2° and 3° alcohols, thiols, and trimethylsilyl ethers.</abstract><pub>TÜBİTAK</pub><tpages>9</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1300-0527
ispartof Turkish journal of chemistry, 2007, Vol.31 (1), p.35-43
issn 1300-0527
1303-6130
language eng
recordid cdi_ulakbim_primary_74390
source EZB-FREE-00999 freely available EZB journals; TÜBİTAK Scientific Journals
title A new and convenient method of generating alkyl isocyanates from alcohols, thiols, and trimethylsilyl ethers using a 2,4,6-trichloro [1,3,5] triazine/n-Bu4NOCN
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-29T14%3A25%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-ulakbim&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=A%20new%20and%20convenient%20method%20of%20generating%20alkyl%20isocyanates%20from%20alcohols,%20thiols,%20and%20trimethylsilyl%20ethers%20using%20a%202,4,6-trichloro%20%5B1,3,5%5D%20triazine/n-Bu4NOCN&rft.jtitle=Turkish%20journal%20of%20chemistry&rft.au=SAMIEI,%20Sima&rft.date=2007&rft.volume=31&rft.issue=1&rft.spage=35&rft.epage=43&rft.pages=35-43&rft.issn=1300-0527&rft.eissn=1303-6130&rft_id=info:doi/&rft_dat=%3Culakbim%3E74390%3C/ulakbim%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_id=info:pmid/&rfr_iscdi=true