Poly (methacrylic) acid and $\gamma$ -methacryloxypropyltrimethoxy silane/clay nanocomposites prepared by in-situ polymerization
Poly(methacrylic acid) and poly(acrylic acid) nanocomposites were prepared by in-situ polymerization of $\gamma$-methacryloxypropyltrimethoxysilane (A174)/clay nanocomposites in which the macromonomer was generated by grafting A-174 onto activated clay samples via hydroxyl groups or via intercalatio...
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| Veröffentlicht in: | Turkish journal of chemistry 2002, Vol.26 (6), p.925-937 |
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| container_title | Turkish journal of chemistry |
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| creator | GÜLTEK, Ahmet İÇDUYGU, M. Galip SEÇKİN, Turgay ÖNAL, Yunus |
| description | Poly(methacrylic acid) and poly(acrylic acid) nanocomposites were prepared by in-situ polymerization of $\gamma$-methacryloxypropyltrimethoxysilane (A174)/clay nanocomposites in which the macromonomer was generated by grafting A-174 onto activated clay samples via hydroxyl groups or via intercalation. In- situ polymerization was carried out in the presence of an initiator. It was found that the structural affinity between the methacrylic or acrylic acid monomers and the amount of clay played an important role in the hybrid structure. The nanocomposites were quantified by both X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), and differential thermal analysis (DTA). |
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Galip</creatorcontrib><creatorcontrib>SEÇKİN, Turgay</creatorcontrib><creatorcontrib>ÖNAL, Yunus</creatorcontrib><title>Poly (methacrylic) acid and $\gamma$ -methacryloxypropyltrimethoxy silane/clay nanocomposites prepared by in-situ polymerization</title><title>Turkish journal of chemistry</title><description>Poly(methacrylic acid) and poly(acrylic acid) nanocomposites were prepared by in-situ polymerization of $\gamma$-methacryloxypropyltrimethoxysilane (A174)/clay nanocomposites in which the macromonomer was generated by grafting A-174 onto activated clay samples via hydroxyl groups or via intercalation. In- situ polymerization was carried out in the presence of an initiator. It was found that the structural affinity between the methacrylic or acrylic acid monomers and the amount of clay played an important role in the hybrid structure. The nanocomposites were quantified by both X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), and differential thermal analysis (DTA).</description><subject>Analitik Kimya, Ayırma Yöntemleri</subject><subject>Analytical Chemistry, Separation Methods</subject><subject>clay</subject><subject>Diferansiyel ısıl analiz</subject><subject>differential thermal analysis</subject><subject>Fizikokimya</subject><subject>FTIR spectroscopy</subject><subject>FTIR spektroskopisi</subject><subject>Kaolinit</subject><subject>kaolinite</subject><subject>Kil</subject><subject>Macromonomer</subject><subject>Makromonomer</subject><subject>Metalik Malzemeler</subject><subject>Metallic Materials</subject><subject>nanocomposites</subject><subject>Nanokompozitler</subject><subject>Physical Chemistry</subject><subject>Polimer Kimyası</subject><subject>Polimerizasyon</subject><subject>Polymer Chemistry</subject><subject>polymerization</subject><subject>scanning electron microscope</subject><subject>Structure of Condensed Matter and Radiation Physics</subject><subject>Taramalı elektron mikroskobu</subject><subject>Termogravimetrik analiz</subject><subject>thermogravimetric analysis</subject><subject>X-ışını kırınımı</subject><subject>X-ray diffraction</subject><subject>Yoğunlaşmış Madde Yapısı ve Radyasyon Fiziği</subject><issn>1300-0527</issn><issn>1303-6130</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2002</creationdate><recordtype>article</recordtype><sourceid/><recordid>eNo9T01LxDAQLaLguvoPPOSwBz0Ek502bY-y6Cos6EFvwjJppxpNm5B0wXjyp1s_EIZ5b96D95i9bCZBAFfT3v_hgotiWR5mRzG-CiHraWbZ572ziZ31NL5gE5I1zTnDxrQMh5Ytnp6x73HB-L_v3pMPzic7BvMtTjeLxuJAF43FxAYcXON676IZKTIfyGOglunEzMAnccf81NhTMB84GjccZwcd2kgnfzjPHq-vHlY3fHO3vl1dbniUZT7yvNGgpZJaIUKJkAMVulaSdFEpEFQp6sqKukKT7spOElSgRAl10UqsVAXz7PQ3d2fxTZt-66cHMKQtLOtawhf_m11G</recordid><startdate>2002</startdate><enddate>2002</enddate><creator>GÜLTEK, Ahmet</creator><creator>İÇDUYGU, M. 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Galip ; SEÇKİN, Turgay ; ÖNAL, Yunus</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-s174t-4cb3b161b6aa37a343e5b961eb58630e86ef78ef5bebf7f1e383607395d1a8683</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2002</creationdate><topic>Analitik Kimya, Ayırma Yöntemleri</topic><topic>Analytical Chemistry, Separation Methods</topic><topic>clay</topic><topic>Diferansiyel ısıl analiz</topic><topic>differential thermal analysis</topic><topic>Fizikokimya</topic><topic>FTIR spectroscopy</topic><topic>FTIR spektroskopisi</topic><topic>Kaolinit</topic><topic>kaolinite</topic><topic>Kil</topic><topic>Macromonomer</topic><topic>Makromonomer</topic><topic>Metalik Malzemeler</topic><topic>Metallic Materials</topic><topic>nanocomposites</topic><topic>Nanokompozitler</topic><topic>Physical Chemistry</topic><topic>Polimer Kimyası</topic><topic>Polimerizasyon</topic><topic>Polymer Chemistry</topic><topic>polymerization</topic><topic>scanning electron microscope</topic><topic>Structure of Condensed Matter and Radiation Physics</topic><topic>Taramalı elektron mikroskobu</topic><topic>Termogravimetrik analiz</topic><topic>thermogravimetric analysis</topic><topic>X-ışını kırınımı</topic><topic>X-ray diffraction</topic><topic>Yoğunlaşmış Madde Yapısı ve Radyasyon Fiziği</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>GÜLTEK, Ahmet</creatorcontrib><creatorcontrib>İÇDUYGU, M. Galip</creatorcontrib><creatorcontrib>SEÇKİN, Turgay</creatorcontrib><creatorcontrib>ÖNAL, Yunus</creatorcontrib><jtitle>Turkish journal of chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>GÜLTEK, Ahmet</au><au>İÇDUYGU, M. Galip</au><au>SEÇKİN, Turgay</au><au>ÖNAL, Yunus</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Poly (methacrylic) acid and $\gamma$ -methacryloxypropyltrimethoxy silane/clay nanocomposites prepared by in-situ polymerization</atitle><jtitle>Turkish journal of chemistry</jtitle><date>2002</date><risdate>2002</risdate><volume>26</volume><issue>6</issue><spage>925</spage><epage>937</epage><pages>925-937</pages><issn>1300-0527</issn><eissn>1303-6130</eissn><abstract>Poly(methacrylic acid) and poly(acrylic acid) nanocomposites were prepared by in-situ polymerization of $\gamma$-methacryloxypropyltrimethoxysilane (A174)/clay nanocomposites in which the macromonomer was generated by grafting A-174 onto activated clay samples via hydroxyl groups or via intercalation. In- situ polymerization was carried out in the presence of an initiator. It was found that the structural affinity between the methacrylic or acrylic acid monomers and the amount of clay played an important role in the hybrid structure. The nanocomposites were quantified by both X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), thermo-gravimetric analysis (TGA), and differential thermal analysis (DTA).</abstract><pub>TÜBİTAK</pub><tpages>13</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Turkish journal of chemistry, 2002, Vol.26 (6), p.925-937 |
| issn | 1300-0527 1303-6130 |
| language | eng |
| recordid | cdi_ulakbim_primary_32991 |
| source | Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; TÜBİTAK Scientific Journals |
| subjects | Analitik Kimya, Ayırma Yöntemleri Analytical Chemistry, Separation Methods clay Diferansiyel ısıl analiz differential thermal analysis Fizikokimya FTIR spectroscopy FTIR spektroskopisi Kaolinit kaolinite Kil Macromonomer Makromonomer Metalik Malzemeler Metallic Materials nanocomposites Nanokompozitler Physical Chemistry Polimer Kimyası Polimerizasyon Polymer Chemistry polymerization scanning electron microscope Structure of Condensed Matter and Radiation Physics Taramalı elektron mikroskobu Termogravimetrik analiz thermogravimetric analysis X-ışını kırınımı X-ray diffraction Yoğunlaşmış Madde Yapısı ve Radyasyon Fiziği |
| title | Poly (methacrylic) acid and $\gamma$ -methacryloxypropyltrimethoxy silane/clay nanocomposites prepared by in-situ polymerization |
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