Formation of O-Allyl Oximes by Reaction of Allylzinc Reagents with α-Chloronitroso Compounds

ABSTRACT The reaction of α-chloronitrosocyclohexane with allyl­zinc reagents in THF selectively provides O-allylcyclohexanone oximes in very good yields in an ene type reaction followed by zinc halide elimination. N-Allyl hydroxylamines are formed as minor products via N-allyl nitrones when a nonpol...

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Veröffentlicht in:	Synthesis (Stuttgart) 2005-12, Vol.2005 (20), p.3565-3570
Hauptverfasser:	Filip, Sorin V., Sewald, Norbert
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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