Quantification of chemical sulphur species in bulk soil and organic sulphur fractions by S K-edge XANES spectroscopy
A new data treatment method for fitting spectra obtained by sulphur (S) K‐edge X‐ray absorption near‐edge structure (XANES) spectroscopy was used to quantify the chemical S speciation at three experimental sites with arable soils receiving the same long‐term field treatments. Two treatments, crop re...
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| Veröffentlicht in: | European journal of soil science 2011-12, Vol.62 (6), p.874-881 |
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| container_title | European journal of soil science |
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| creator | Boye, K. Almkvist, G. Nilsson, S. I. Eriksen, J. Persson, I. |
| description | A new data treatment method for fitting spectra obtained by sulphur (S) K‐edge X‐ray absorption near‐edge structure (XANES) spectroscopy was used to quantify the chemical S speciation at three experimental sites with arable soils receiving the same long‐term field treatments. Two treatments, crop residue (CR) incorporation and farmyard manure (FYM) application, with equal applications of mineral nutrients were included in the study. In the new data treatment method, internally calibrated spectra of dilute solutions (30 mm) of model compounds were used to fit the sample spectra. This greatly enhanced the reliability of quantitative determination of contributing S species in soil samples and soil extracts. The results indicated that long‐term FYM application shifted S species composition from highly oxidized towards intermediate oxidization in two of the soils, but in the third soil the opposite trend was observed. Sulphur XANES spectroscopy of acetylacetone extracts of physically protected and unprotected organic S in two of the soils revealed that physical protection was not related to S speciation; however, intermediate forms of oxidized S species appeared to accumulate in the residual S pool (not extractable by acetylacetone). |
| doi_str_mv | 10.1111/j.1365-2389.2011.01391.x |
| format | Article |
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I. ; Eriksen, J. ; Persson, I.</creator><creatorcontrib>Boye, K. ; Almkvist, G. ; Nilsson, S. I. ; Eriksen, J. ; Persson, I. ; Sveriges lantbruksuniversitet</creatorcontrib><description>A new data treatment method for fitting spectra obtained by sulphur (S) K‐edge X‐ray absorption near‐edge structure (XANES) spectroscopy was used to quantify the chemical S speciation at three experimental sites with arable soils receiving the same long‐term field treatments. Two treatments, crop residue (CR) incorporation and farmyard manure (FYM) application, with equal applications of mineral nutrients were included in the study. In the new data treatment method, internally calibrated spectra of dilute solutions (30 mm) of model compounds were used to fit the sample spectra. This greatly enhanced the reliability of quantitative determination of contributing S species in soil samples and soil extracts. The results indicated that long‐term FYM application shifted S species composition from highly oxidized towards intermediate oxidization in two of the soils, but in the third soil the opposite trend was observed. Sulphur XANES spectroscopy of acetylacetone extracts of physically protected and unprotected organic S in two of the soils revealed that physical protection was not related to S speciation; however, intermediate forms of oxidized S species appeared to accumulate in the residual S pool (not extractable by acetylacetone).</description><identifier>ISSN: 1351-0754</identifier><identifier>ISSN: 1365-2389</identifier><identifier>EISSN: 1365-2389</identifier><identifier>DOI: 10.1111/j.1365-2389.2011.01391.x</identifier><language>eng</language><publisher>Oxford, UK: Blackwell Publishing Ltd</publisher><subject>Acetylacetone ; Agricultural Science ; Agronomy. 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I.</creatorcontrib><creatorcontrib>Eriksen, J.</creatorcontrib><creatorcontrib>Persson, I.</creatorcontrib><creatorcontrib>Sveriges lantbruksuniversitet</creatorcontrib><title>Quantification of chemical sulphur species in bulk soil and organic sulphur fractions by S K-edge XANES spectroscopy</title><title>European journal of soil science</title><description>A new data treatment method for fitting spectra obtained by sulphur (S) K‐edge X‐ray absorption near‐edge structure (XANES) spectroscopy was used to quantify the chemical S speciation at three experimental sites with arable soils receiving the same long‐term field treatments. Two treatments, crop residue (CR) incorporation and farmyard manure (FYM) application, with equal applications of mineral nutrients were included in the study. In the new data treatment method, internally calibrated spectra of dilute solutions (30 mm) of model compounds were used to fit the sample spectra. This greatly enhanced the reliability of quantitative determination of contributing S species in soil samples and soil extracts. The results indicated that long‐term FYM application shifted S species composition from highly oxidized towards intermediate oxidization in two of the soils, but in the third soil the opposite trend was observed. Sulphur XANES spectroscopy of acetylacetone extracts of physically protected and unprotected organic S in two of the soils revealed that physical protection was not related to S speciation; however, intermediate forms of oxidized S species appeared to accumulate in the residual S pool (not extractable by acetylacetone).</description><subject>Acetylacetone</subject><subject>Agricultural Science</subject><subject>Agronomy. Soil science and plant productions</subject><subject>Biological and medical sciences</subject><subject>Chemical, physicochemical, biochemical and biological properties</subject><subject>Earth sciences</subject><subject>Earth, ocean, space</subject><subject>Environmental Sciences related to Agriculture and Land-use</subject><subject>Exact sciences and technology</subject><subject>Fundamental and applied biological sciences. Psychology</subject><subject>Jordbruksvetenskap</subject><subject>Miljö- och naturvårdsvetenskap</subject><subject>Organic matter</subject><subject>Physics, chemistry, biochemistry and biology of agricultural and forest soils</subject><subject>Receiving</subject><subject>Soil (material)</subject><subject>Soil science</subject><subject>Soils</subject><subject>Speciation</subject><subject>Spectra</subject><subject>Spectroscopy</subject><subject>Sulfur</subject><subject>Sulphur</subject><subject>Surficial geology</subject><issn>1351-0754</issn><issn>1365-2389</issn><issn>1365-2389</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNqNkU1v1DAQhiMEEqXwH3xBcElqxx-JL0hVtezSL4QWBDfLcezW22ySehJ199_X6VbhVtWXGcvPvOOZN0kQwRmJ52STESp4mtNSZjkmJMOESpLt3iRH88PbKeckxQVn75MPABscKSLlUTL8GnU7eOeNHnzXos4hc2u38dogGJv-dgwIemu8BeRbVI3NHYLON0i3NerCjW69mUEXtJlUAFV7tEYXqa1vLPp3er1YP4kMoQPT9fuPyTunG7CfnuNx8uf74vfZKr38ufxxdnqZao5LktpKUiYILrkThrNCmJxxQy3DrpZ1xQ2TQjBZyVLXjImyco5ggjmhOA5X5vQ4SQ-68GD7sVJ98Fsd9qrTXkEzVjpMQYFVVNBCRv7Lge9Ddz9aGNTWg7FNo1vbjaAkKTHnOS4j-fVFkoiC8JzSfELLA2ri9BCsm79BsJosVBs1OaUmp9RkoXqyUO1i6efnLhqiIXG9rfEw1-dxJZwyGrlvB-7BN3b_an21OF-vp_T_ojwMdjcL6HCnREELrv5eLxW_upArvlxFtUcmv75S</recordid><startdate>201112</startdate><enddate>201112</enddate><creator>Boye, K.</creator><creator>Almkvist, G.</creator><creator>Nilsson, S. 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I. ; Eriksen, J. ; Persson, I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a5081-eb93461085f6c5476c245c3e40fd9db5c496649b98ad4468bff10105130319823</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Acetylacetone</topic><topic>Agricultural Science</topic><topic>Agronomy. Soil science and plant productions</topic><topic>Biological and medical sciences</topic><topic>Chemical, physicochemical, biochemical and biological properties</topic><topic>Earth sciences</topic><topic>Earth, ocean, space</topic><topic>Environmental Sciences related to Agriculture and Land-use</topic><topic>Exact sciences and technology</topic><topic>Fundamental and applied biological sciences. 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In the new data treatment method, internally calibrated spectra of dilute solutions (30 mm) of model compounds were used to fit the sample spectra. This greatly enhanced the reliability of quantitative determination of contributing S species in soil samples and soil extracts. The results indicated that long‐term FYM application shifted S species composition from highly oxidized towards intermediate oxidization in two of the soils, but in the third soil the opposite trend was observed. Sulphur XANES spectroscopy of acetylacetone extracts of physically protected and unprotected organic S in two of the soils revealed that physical protection was not related to S speciation; however, intermediate forms of oxidized S species appeared to accumulate in the residual S pool (not extractable by acetylacetone).</abstract><cop>Oxford, UK</cop><pub>Blackwell Publishing Ltd</pub><doi>10.1111/j.1365-2389.2011.01391.x</doi><tpages>8</tpages></addata></record> |
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| source | Wiley Online Library Journals Frontfile Complete |
| subjects | Acetylacetone Agricultural Science Agronomy. Soil science and plant productions Biological and medical sciences Chemical, physicochemical, biochemical and biological properties Earth sciences Earth, ocean, space Environmental Sciences related to Agriculture and Land-use Exact sciences and technology Fundamental and applied biological sciences. Psychology Jordbruksvetenskap Miljö- och naturvårdsvetenskap Organic matter Physics, chemistry, biochemistry and biology of agricultural and forest soils Receiving Soil (material) Soil science Soils Speciation Spectra Spectroscopy Sulfur Sulphur Surficial geology |
| title | Quantification of chemical sulphur species in bulk soil and organic sulphur fractions by S K-edge XANES spectroscopy |
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