Determining the valence state of manganese ions in complex oxides La1–xCaxMnO3 (x = 0.5, 0.7, 0.85, and 0.9) based on Mn2p and Mn3s X-ray photoelectron spectra

The valence state of manganese ions in complex oxides La 1– x Ca x MnO 3 ( x = 0.5, 0.7, 0.85, and 0.9) is studied on the basis of Mn2 p and Mn3 s X-ray photoelectron spectra. It is shown that manganese ions have the valence of Mn 3+ and Mn 4+ in the studied compounds. The relative Mn 3+ /Mn 4+ cont...

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Veröffentlicht in:Bulletin of the Russian Academy of Sciences. Physics 2016-06, Vol.80 (6), p.638-640
Hauptverfasser: Googlev, K. A., Kozakov, A. T., Kochur, A. G., Nikolskii, A. V., Torgashev, V. I., Zvolenskaya, A. A.
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container_title Bulletin of the Russian Academy of Sciences. Physics
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creator Googlev, K. A.
Kozakov, A. T.
Kochur, A. G.
Nikolskii, A. V.
Torgashev, V. I.
Zvolenskaya, A. A.
description The valence state of manganese ions in complex oxides La 1– x Ca x MnO 3 ( x = 0.5, 0.7, 0.85, and 0.9) is studied on the basis of Mn2 p and Mn3 s X-ray photoelectron spectra. It is shown that manganese ions have the valence of Mn 3+ and Mn 4+ in the studied compounds. The relative Mn 3+ /Mn 4+ content is determined.
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subjects Disorder
Hadrons
Heavy Ions
Nuclear Physics
Physics
Physics and Astronomy
Proceedings of the Interdisciplinary Symposium “Ordering in Minerals and Alloys” OMA-18 and Proceedings of the International Interdisciplinary Symposium “Order
Properties of Oxides” ODPO-18
title Determining the valence state of manganese ions in complex oxides La1–xCaxMnO3 (x = 0.5, 0.7, 0.85, and 0.9) based on Mn2p and Mn3s X-ray photoelectron spectra
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