Reactions of Polyfluoroaromatic Organozinc Compounds with Oxalyl Chloride in DMF. Synthesis of Polyfluoroaromatic Aldehydes

The reaction of polyfluoroaromatic organozinc compounds with oxalyl chloride in DMF proceeds involving the Vilsmeier–Haack reagent with the formation of polyfluoroaromatic aldehydes as the major products. The use of CuI makes it possible to increase the yield of the target aldehydes.

Bibliographische Detailangaben

Veröffentlicht in:	Russian journal of general chemistry 2020-12, Vol.90 (12), p.2264-2272
Hauptverfasser:	Vinogradov, A. S., Platonov, V. E.
Format:	Artikel
Sprache:	eng
Schlagworte:	Aldehydes Chemical tests and reagents Chemistry Chemistry and Materials Science Chemistry/Food Science Chlorides Reagents
Online-Zugang:	Volltext
Tags:	Tag hinzufügen Keine Tags, Fügen Sie den ersten Tag hinzu!