TWO NEW SELF-ASSEMBLED CADMIUM(II) METAL-ORGANIC FRAMEWORKS CONSTRUCTED OF A FLEXIBLE TRIPODAL LIGAND: SYNTHESIS, STRUCTURE, AND THERMAL STABILITY
Two novel complexes, namely [Cd(L)(NO 3 ) 2 ] n ( 1 ) and {[Cd(L)(NO 3 ) 2 ](CH 3 CH 2 OH)} n ( 2 ) (L = 1,3,5-tris[1-(4-oxidroxypyridinium-methylene)]benzene) are synthesized solvothermally in different solvents. Single crystal and powder X-ray diffraction, infrared spectroscopy, thermogravimetry,...
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| Veröffentlicht in: | Journal of structural chemistry 2021-11, Vol.62 (11), p.1703-1714 |
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| creator | Yang, Q. -L. Zhang, X. -Y. Xiong, D. -Q. Zhu, Y. -Y. Yun, M. Jia, M. -M. Fu, P. -K. Liu, J. -C. Dong, X. -Y. |
| description | Two novel complexes, namely [Cd(L)(NO
3
)
2
]
n
(
1
) and {[Cd(L)(NO
3
)
2
](CH
3
CH
2
OH)}
n
(
2
) (L = 1,3,5-tris[1-(4-oxidroxypyridinium-methylene)]benzene) are synthesized solvothermally in different solvents. Single crystal and powder X-ray diffraction, infrared spectroscopy, thermogravimetry, 2D fingerprint plots, and Hirshfeld surface analyses are carried out for these complexes and their topology and thermal stability are also analyzed. Two complexes exhibit the same 2D interpenetrating structure formed by the ligand coordinated with Cd(II) ions. Due to the presence of ethanol molecules in complex
2
, part of π⋯π stacking in complex
1
is blocked, resulting in new C–H⋯π and hydrogen bonding. This change makes the weak force stronger and forms a more stable framework. The result is that the thermal stability of
2
is higher than that of
1
. |
| doi_str_mv | 10.1134/S0022476621110068 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_sprin</sourceid><recordid>TN_cdi_springer_journals_10_1134_S0022476621110068</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2610488412</sourcerecordid><originalsourceid>FETCH-LOGICAL-c316t-b40bfb35389892d426578503c3fdc00d16c1528f5eda6fa030bcbd558d892cea3</originalsourceid><addsrcrecordid>eNqNkMtu1DAYRi1EJYbCA7CzxAbUBnyJHQ-7NOO0FskExR4NXUWJ46CpIGmTjBCvwRPjUSpYICRWtvyd4_8CwCuM3mFMw_caIULCiHOCMUaIiydghVlEAxFF66dgdYqDU_4MPJ-mO4TQWqz5Cvw0-wJu5R5qmaVBrLXMrzK5gUm8ydUuf6PUW5hLE2dBUV7HW5XAtIxzuS_KjxomxVabcpcYLxQpjGGayc_K-9CU6lOxiTOYKW9tPkB9uzU3Uit9CRdlV8pL6CPon8vck9rEVypT5vYFOOvqr5N7-Xieg10qTXITZMW1SnwnlmI-B02Imq6hjAo_CWlDwlkkGKKWdq1FqMXcYkZEx1xb865GFDW2aRkTrcetq-k5eL38ez8OD0c3zdXdcBx7X7IiHKNQiBATT-GFsuMwTaPrqvvx8K0ef1QYVafVV3-t3jsXi_PdNUM32YPrrfvt-d1HFLE1Dv0NcU-L_6eTw1zPh6FPhmM_e5Us6uTx_osb_4zw7-5-Ad0vmZE</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2610488412</pqid></control><display><type>article</type><title>TWO NEW SELF-ASSEMBLED CADMIUM(II) METAL-ORGANIC FRAMEWORKS CONSTRUCTED OF A FLEXIBLE TRIPODAL LIGAND: SYNTHESIS, STRUCTURE, AND THERMAL STABILITY</title><source>Springer Online Journals</source><source>Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /></source><creator>Yang, Q. -L. ; Zhang, X. -Y. ; Xiong, D. -Q. ; Zhu, Y. -Y. ; Yun, M. ; Jia, M. -M. ; Fu, P. -K. ; Liu, J. -C. ; Dong, X. -Y.</creator><creatorcontrib>Yang, Q. -L. ; Zhang, X. -Y. ; Xiong, D. -Q. ; Zhu, Y. -Y. ; Yun, M. ; Jia, M. -M. ; Fu, P. -K. ; Liu, J. -C. ; Dong, X. -Y.</creatorcontrib><description>Two novel complexes, namely [Cd(L)(NO
3
)
2
]
n
(
1
) and {[Cd(L)(NO
3
)
2
](CH
3
CH
2
OH)}
n
(
2
) (L = 1,3,5-tris[1-(4-oxidroxypyridinium-methylene)]benzene) are synthesized solvothermally in different solvents. Single crystal and powder X-ray diffraction, infrared spectroscopy, thermogravimetry, 2D fingerprint plots, and Hirshfeld surface analyses are carried out for these complexes and their topology and thermal stability are also analyzed. Two complexes exhibit the same 2D interpenetrating structure formed by the ligand coordinated with Cd(II) ions. Due to the presence of ethanol molecules in complex
2
, part of π⋯π stacking in complex
1
is blocked, resulting in new C–H⋯π and hydrogen bonding. This change makes the weak force stronger and forms a more stable framework. The result is that the thermal stability of
2
is higher than that of
1
.</description><identifier>ISSN: 0022-4766</identifier><identifier>EISSN: 1573-8779</identifier><identifier>DOI: 10.1134/S0022476621110068</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Atomic ; Atomic/Molecular Structure and Spectra ; Benzene ; Bonding strength ; Chemistry ; Chemistry and Materials Science ; Chemistry, Inorganic & Nuclear ; Chemistry, Physical ; Ethanol ; Hydrogen bonding ; Infrared analysis ; Inorganic Chemistry ; Ligands ; Metal-organic frameworks ; Molecular ; Optical and Plasma Physics ; Physical Chemistry ; Physical Sciences ; Science & Technology ; Self-assembly ; Single crystals ; Solid State Physics ; Stability analysis ; Structural stability ; Thermal stability ; Thermogravimetry ; Topology ; Two dimensional analysis ; X ray powder diffraction</subject><ispartof>Journal of structural chemistry, 2021-11, Vol.62 (11), p.1703-1714</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>true</woscitedreferencessubscribed><woscitedreferencescount>6</woscitedreferencescount><woscitedreferencesoriginalsourcerecordid>wos000730591400006</woscitedreferencesoriginalsourcerecordid><citedby>FETCH-LOGICAL-c316t-b40bfb35389892d426578503c3fdc00d16c1528f5eda6fa030bcbd558d892cea3</citedby><cites>FETCH-LOGICAL-c316t-b40bfb35389892d426578503c3fdc00d16c1528f5eda6fa030bcbd558d892cea3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S0022476621110068$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S0022476621110068$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>315,782,786,27933,27934,39267,41497,42566,51328</link.rule.ids></links><search><creatorcontrib>Yang, Q. -L.</creatorcontrib><creatorcontrib>Zhang, X. -Y.</creatorcontrib><creatorcontrib>Xiong, D. -Q.</creatorcontrib><creatorcontrib>Zhu, Y. -Y.</creatorcontrib><creatorcontrib>Yun, M.</creatorcontrib><creatorcontrib>Jia, M. -M.</creatorcontrib><creatorcontrib>Fu, P. -K.</creatorcontrib><creatorcontrib>Liu, J. -C.</creatorcontrib><creatorcontrib>Dong, X. -Y.</creatorcontrib><title>TWO NEW SELF-ASSEMBLED CADMIUM(II) METAL-ORGANIC FRAMEWORKS CONSTRUCTED OF A FLEXIBLE TRIPODAL LIGAND: SYNTHESIS, STRUCTURE, AND THERMAL STABILITY</title><title>Journal of structural chemistry</title><addtitle>J Struct Chem</addtitle><addtitle>J STRUCT CHEM</addtitle><description>Two novel complexes, namely [Cd(L)(NO
3
)
2
]
n
(
1
) and {[Cd(L)(NO
3
)
2
](CH
3
CH
2
OH)}
n
(
2
) (L = 1,3,5-tris[1-(4-oxidroxypyridinium-methylene)]benzene) are synthesized solvothermally in different solvents. Single crystal and powder X-ray diffraction, infrared spectroscopy, thermogravimetry, 2D fingerprint plots, and Hirshfeld surface analyses are carried out for these complexes and their topology and thermal stability are also analyzed. Two complexes exhibit the same 2D interpenetrating structure formed by the ligand coordinated with Cd(II) ions. Due to the presence of ethanol molecules in complex
2
, part of π⋯π stacking in complex
1
is blocked, resulting in new C–H⋯π and hydrogen bonding. This change makes the weak force stronger and forms a more stable framework. The result is that the thermal stability of
2
is higher than that of
1
.</description><subject>Atomic</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Benzene</subject><subject>Bonding strength</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry, Inorganic & Nuclear</subject><subject>Chemistry, Physical</subject><subject>Ethanol</subject><subject>Hydrogen bonding</subject><subject>Infrared analysis</subject><subject>Inorganic Chemistry</subject><subject>Ligands</subject><subject>Metal-organic frameworks</subject><subject>Molecular</subject><subject>Optical and Plasma Physics</subject><subject>Physical Chemistry</subject><subject>Physical Sciences</subject><subject>Science & Technology</subject><subject>Self-assembly</subject><subject>Single crystals</subject><subject>Solid State Physics</subject><subject>Stability analysis</subject><subject>Structural stability</subject><subject>Thermal stability</subject><subject>Thermogravimetry</subject><subject>Topology</subject><subject>Two dimensional analysis</subject><subject>X ray powder diffraction</subject><issn>0022-4766</issn><issn>1573-8779</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>HGBXW</sourceid><recordid>eNqNkMtu1DAYRi1EJYbCA7CzxAbUBnyJHQ-7NOO0FskExR4NXUWJ46CpIGmTjBCvwRPjUSpYICRWtvyd4_8CwCuM3mFMw_caIULCiHOCMUaIiydghVlEAxFF66dgdYqDU_4MPJ-mO4TQWqz5Cvw0-wJu5R5qmaVBrLXMrzK5gUm8ydUuf6PUW5hLE2dBUV7HW5XAtIxzuS_KjxomxVabcpcYLxQpjGGayc_K-9CU6lOxiTOYKW9tPkB9uzU3Uit9CRdlV8pL6CPon8vck9rEVypT5vYFOOvqr5N7-Xieg10qTXITZMW1SnwnlmI-B02Imq6hjAo_CWlDwlkkGKKWdq1FqMXcYkZEx1xb865GFDW2aRkTrcetq-k5eL38ez8OD0c3zdXdcBx7X7IiHKNQiBATT-GFsuMwTaPrqvvx8K0ef1QYVafVV3-t3jsXi_PdNUM32YPrrfvt-d1HFLE1Dv0NcU-L_6eTw1zPh6FPhmM_e5Us6uTx_osb_4zw7-5-Ad0vmZE</recordid><startdate>20211101</startdate><enddate>20211101</enddate><creator>Yang, Q. -L.</creator><creator>Zhang, X. -Y.</creator><creator>Xiong, D. -Q.</creator><creator>Zhu, Y. -Y.</creator><creator>Yun, M.</creator><creator>Jia, M. -M.</creator><creator>Fu, P. -K.</creator><creator>Liu, J. -C.</creator><creator>Dong, X. -Y.</creator><general>Pleiades Publishing</general><general>Pleiades Publishing Inc</general><general>Springer Nature B.V</general><scope>BLEPL</scope><scope>DTL</scope><scope>HGBXW</scope><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20211101</creationdate><title>TWO NEW SELF-ASSEMBLED CADMIUM(II) METAL-ORGANIC FRAMEWORKS CONSTRUCTED OF A FLEXIBLE TRIPODAL LIGAND: SYNTHESIS, STRUCTURE, AND THERMAL STABILITY</title><author>Yang, Q. -L. ; Zhang, X. -Y. ; Xiong, D. -Q. ; Zhu, Y. -Y. ; Yun, M. ; Jia, M. -M. ; Fu, P. -K. ; Liu, J. -C. ; Dong, X. -Y.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-b40bfb35389892d426578503c3fdc00d16c1528f5eda6fa030bcbd558d892cea3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Atomic</topic><topic>Atomic/Molecular Structure and Spectra</topic><topic>Benzene</topic><topic>Bonding strength</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry, Inorganic & Nuclear</topic><topic>Chemistry, Physical</topic><topic>Ethanol</topic><topic>Hydrogen bonding</topic><topic>Infrared analysis</topic><topic>Inorganic Chemistry</topic><topic>Ligands</topic><topic>Metal-organic frameworks</topic><topic>Molecular</topic><topic>Optical and Plasma Physics</topic><topic>Physical Chemistry</topic><topic>Physical Sciences</topic><topic>Science & Technology</topic><topic>Self-assembly</topic><topic>Single crystals</topic><topic>Solid State Physics</topic><topic>Stability analysis</topic><topic>Structural stability</topic><topic>Thermal stability</topic><topic>Thermogravimetry</topic><topic>Topology</topic><topic>Two dimensional analysis</topic><topic>X ray powder diffraction</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Q. -L.</creatorcontrib><creatorcontrib>Zhang, X. -Y.</creatorcontrib><creatorcontrib>Xiong, D. -Q.</creatorcontrib><creatorcontrib>Zhu, Y. -Y.</creatorcontrib><creatorcontrib>Yun, M.</creatorcontrib><creatorcontrib>Jia, M. -M.</creatorcontrib><creatorcontrib>Fu, P. -K.</creatorcontrib><creatorcontrib>Liu, J. -C.</creatorcontrib><creatorcontrib>Dong, X. -Y.</creatorcontrib><collection>Web of Science Core Collection</collection><collection>Science Citation Index Expanded</collection><collection>Web of Science - Science Citation Index Expanded - 2021</collection><collection>CrossRef</collection><jtitle>Journal of structural chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Q. -L.</au><au>Zhang, X. -Y.</au><au>Xiong, D. -Q.</au><au>Zhu, Y. -Y.</au><au>Yun, M.</au><au>Jia, M. -M.</au><au>Fu, P. -K.</au><au>Liu, J. -C.</au><au>Dong, X. -Y.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>TWO NEW SELF-ASSEMBLED CADMIUM(II) METAL-ORGANIC FRAMEWORKS CONSTRUCTED OF A FLEXIBLE TRIPODAL LIGAND: SYNTHESIS, STRUCTURE, AND THERMAL STABILITY</atitle><jtitle>Journal of structural chemistry</jtitle><stitle>J Struct Chem</stitle><stitle>J STRUCT CHEM</stitle><date>2021-11-01</date><risdate>2021</risdate><volume>62</volume><issue>11</issue><spage>1703</spage><epage>1714</epage><pages>1703-1714</pages><issn>0022-4766</issn><eissn>1573-8779</eissn><abstract>Two novel complexes, namely [Cd(L)(NO
3
)
2
]
n
(
1
) and {[Cd(L)(NO
3
)
2
](CH
3
CH
2
OH)}
n
(
2
) (L = 1,3,5-tris[1-(4-oxidroxypyridinium-methylene)]benzene) are synthesized solvothermally in different solvents. Single crystal and powder X-ray diffraction, infrared spectroscopy, thermogravimetry, 2D fingerprint plots, and Hirshfeld surface analyses are carried out for these complexes and their topology and thermal stability are also analyzed. Two complexes exhibit the same 2D interpenetrating structure formed by the ligand coordinated with Cd(II) ions. Due to the presence of ethanol molecules in complex
2
, part of π⋯π stacking in complex
1
is blocked, resulting in new C–H⋯π and hydrogen bonding. This change makes the weak force stronger and forms a more stable framework. The result is that the thermal stability of
2
is higher than that of
1
.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S0022476621110068</doi><tpages>12</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0022-4766 |
| ispartof | Journal of structural chemistry, 2021-11, Vol.62 (11), p.1703-1714 |
| issn | 0022-4766 1573-8779 |
| language | eng |
| recordid | cdi_springer_journals_10_1134_S0022476621110068 |
| source | Springer Online Journals; Web of Science - Science Citation Index Expanded - 2021<img src="https://exlibris-pub.s3.amazonaws.com/fromwos-v2.jpg" /> |
| subjects | Atomic Atomic/Molecular Structure and Spectra Benzene Bonding strength Chemistry Chemistry and Materials Science Chemistry, Inorganic & Nuclear Chemistry, Physical Ethanol Hydrogen bonding Infrared analysis Inorganic Chemistry Ligands Metal-organic frameworks Molecular Optical and Plasma Physics Physical Chemistry Physical Sciences Science & Technology Self-assembly Single crystals Solid State Physics Stability analysis Structural stability Thermal stability Thermogravimetry Topology Two dimensional analysis X ray powder diffraction |
| title | TWO NEW SELF-ASSEMBLED CADMIUM(II) METAL-ORGANIC FRAMEWORKS CONSTRUCTED OF A FLEXIBLE TRIPODAL LIGAND: SYNTHESIS, STRUCTURE, AND THERMAL STABILITY |
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